The first 3-connected SrSi2-type 3D chiral framework constructed from {Ni6PW9} building units

Xin Xiong Li; Wei Hui Fang; Jun Wei Zhao; Guo Yu Yang

doi:10.1002/chem.201405290

The first 3-connected SrSi2-type 3D chiral framework constructed from {Ni6PW9} building units

Xin Xiong Li
, Wei Hui Fang
, Jun Wei Zhao^*
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

A novel 3-connected SrSi₂-type 3D chiral framework constructed from hexa-Ni^II-cluster-substituted polyoxometalate (POM) units [Ni(enMe)₂]₃[WO₄]₃- [Ni₆(enMe)₃(OH)₃PW₉O₃₄]2·9H2O (1) (enMe=1,2-diaminopropane) has been made from a hydrothermal synthetic method. This POM represents the first 3D framework based on {Ni₆PW₉} units and {WO₄} connectors.

Original language	English
Pages (from-to)	2315-2318
Number of pages	4
Journal	Chemistry - A European Journal
Volume	21
Issue number	6
DOIs	https://doi.org/10.1002/chem.201405290
Publication status	Published - 2 Feb 2015

Keywords

Chiral framework •
Cluster compounds •
Nickel •
Polyoxometalate

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10.1002/chem.201405290

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title = "The first 3-connected SrSi2-type 3D chiral framework constructed from \{Ni6PW9\} building units",

abstract = "A novel 3-connected SrSi2-type 3D chiral framework constructed from hexa-NiII-cluster-substituted polyoxometalate (POM) units [Ni(enMe)2]3[WO4]3- [Ni6(enMe)3(OH)3PW9O34]2·9H2O (1) (enMe=1,2-diaminopropane) has been made from a hydrothermal synthetic method. This POM represents the first 3D framework based on \{Ni6PW9\} units and \{WO4\} connectors.",

keywords = "Chiral framework •, Cluster compounds •, Nickel •, Polyoxometalate",

author = "Li, \{Xin Xiong\} and Fang, \{Wei Hui\} and Zhao, \{Jun Wei\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2015 Wiley-VCH Verlag GmbH \& Co. KGaA.",

year = "2015",

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doi = "10.1002/chem.201405290",

language = "English",

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T1 - The first 3-connected SrSi2-type 3D chiral framework constructed from {Ni6PW9} building units

AU - Li, Xin Xiong

AU - Fang, Wei Hui

AU - Zhao, Jun Wei

AU - Yang, Guo Yu

PY - 2015/2/2

Y1 - 2015/2/2

N2 - A novel 3-connected SrSi2-type 3D chiral framework constructed from hexa-NiII-cluster-substituted polyoxometalate (POM) units [Ni(enMe)2]3[WO4]3- [Ni6(enMe)3(OH)3PW9O34]2·9H2O (1) (enMe=1,2-diaminopropane) has been made from a hydrothermal synthetic method. This POM represents the first 3D framework based on {Ni6PW9} units and {WO4} connectors.

AB - A novel 3-connected SrSi2-type 3D chiral framework constructed from hexa-NiII-cluster-substituted polyoxometalate (POM) units [Ni(enMe)2]3[WO4]3- [Ni6(enMe)3(OH)3PW9O34]2·9H2O (1) (enMe=1,2-diaminopropane) has been made from a hydrothermal synthetic method. This POM represents the first 3D framework based on {Ni6PW9} units and {WO4} connectors.

KW - Chiral framework •

KW - Cluster compounds •

KW - Nickel •

KW - Polyoxometalate

UR - https://www.scopus.com/pages/publications/84921648551

U2 - 10.1002/chem.201405290

DO - 10.1002/chem.201405290

M3 - Article

AN - SCOPUS:84921648551

SN - 0947-6539

VL - 21

SP - 2315

EP - 2318

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 6

ER -

The first 3-connected SrSi2-type 3D chiral framework constructed from {Ni6PW9} building units

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Keywords

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