Abstract
The evolution of the monoelectron dihydrogen bond H···e···H in the symmetric and asymmetric cluster anions (FH)n{e} (HF)m was studied. This evolution shows a size effect of the subunits on the structure and the bond for the molecular cluster anions. The simplest bridge was formed by one excess electron and two positive charged hydrogen atoms.
Original language | English |
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Pages (from-to) | 10939-10943 |
Number of pages | 5 |
Journal | Journal of Chemical Physics |
Volume | 118 |
Issue number | 24 |
DOIs | |
Publication status | Published - 22 Jun 2003 |
Externally published | Yes |