The enhanced electronic communication in ferrocenemethanol molecular cluster based on intermolecular hydrogen-bonding

Yifan Yang; Qing Zheng; Yuanyuan Yan; Yao Liu; Huibo Shao

doi:10.1016/j.cclet.2017.06.011

The enhanced electronic communication in ferrocenemethanol molecular cluster based on intermolecular hydrogen-bonding

Yifan Yang, Qing Zheng, Yuanyuan Yan, Yao Liu, Huibo Shao^*

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol (described as FcCH₂OH) molecular clusters. The enhanced electronic communication in FcCH₂OH clusters is confirmed and further investigated by differential-pulse voltammetry and cyclic voltammetry. A key finding is that this enhanced electronic communication increases the standard rate constant of the electron transfer process. These results will provide us with a further understanding of the electronic communication within the ferrocenyl derivatives which is based on the intermolecular hydrogen-bonding.

Original language	English
Pages (from-to)	179-182
Number of pages	4
Journal	Chinese Chemical Letters
Volume	29
Issue number	1
DOIs	https://doi.org/10.1016/j.cclet.2017.06.011
Publication status	Published - Jan 2018
Externally published	Yes

Keywords

Cyclic voltammetry
Electron transfer
Enhanced electronic communication
Intermolecular hydrogen-bonding
Molecular clusters

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10.1016/j.cclet.2017.06.011

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@article{d4eda4cae6114098a9b39e91c7541f61,

title = "The enhanced electronic communication in ferrocenemethanol molecular cluster based on intermolecular hydrogen-bonding",

abstract = "This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol (described as FcCH2OH) molecular clusters. The enhanced electronic communication in FcCH2OH clusters is confirmed and further investigated by differential-pulse voltammetry and cyclic voltammetry. A key finding is that this enhanced electronic communication increases the standard rate constant of the electron transfer process. These results will provide us with a further understanding of the electronic communication within the ferrocenyl derivatives which is based on the intermolecular hydrogen-bonding.",

keywords = "Cyclic voltammetry, Electron transfer, Enhanced electronic communication, Intermolecular hydrogen-bonding, Molecular clusters",

author = "Yifan Yang and Qing Zheng and Yuanyuan Yan and Yao Liu and Huibo Shao",

note = "Publisher Copyright: {\textcopyright} 2018 The Author",

year = "2018",

month = jan,

doi = "10.1016/j.cclet.2017.06.011",

language = "English",

volume = "29",

pages = "179--182",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - The enhanced electronic communication in ferrocenemethanol molecular cluster based on intermolecular hydrogen-bonding

AU - Yang, Yifan

AU - Zheng, Qing

AU - Yan, Yuanyuan

AU - Liu, Yao

AU - Shao, Huibo

PY - 2018/1

Y1 - 2018/1

N2 - This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol (described as FcCH2OH) molecular clusters. The enhanced electronic communication in FcCH2OH clusters is confirmed and further investigated by differential-pulse voltammetry and cyclic voltammetry. A key finding is that this enhanced electronic communication increases the standard rate constant of the electron transfer process. These results will provide us with a further understanding of the electronic communication within the ferrocenyl derivatives which is based on the intermolecular hydrogen-bonding.

AB - This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol (described as FcCH2OH) molecular clusters. The enhanced electronic communication in FcCH2OH clusters is confirmed and further investigated by differential-pulse voltammetry and cyclic voltammetry. A key finding is that this enhanced electronic communication increases the standard rate constant of the electron transfer process. These results will provide us with a further understanding of the electronic communication within the ferrocenyl derivatives which is based on the intermolecular hydrogen-bonding.

KW - Cyclic voltammetry

KW - Electron transfer

KW - Enhanced electronic communication

KW - Intermolecular hydrogen-bonding

KW - Molecular clusters

UR - https://www.scopus.com/pages/publications/85028819129

U2 - 10.1016/j.cclet.2017.06.011

DO - 10.1016/j.cclet.2017.06.011

M3 - Article

AN - SCOPUS:85028819129

SN - 1001-8417

VL - 29

SP - 179

EP - 182

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 1

ER -

The enhanced electronic communication in ferrocenemethanol molecular cluster based on intermolecular hydrogen-bonding

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Keywords

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