The electrochemical properties of 12-molybdophosphoric acid modified ionic liquid carbon paste electrode

Tao Dong; Jianbo Du; Minhua Cao; Changwen Hu

doi:10.1007/s10876-010-0302-1

The electrochemical properties of 12-molybdophosphoric acid modified ionic liquid carbon paste electrode

Tao Dong
, Jianbo Du
, Minhua Cao^*
, Changwen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A [C₈mim]₃PMo₁₂O₄₀-modified ionic liquid carbon paste electrode ([C₈mim]₃PMo₁₂O₄₀-ILCPE, C₈mim = 1-methyl-3-octylimidazolium) was successfully fabricated. Its electrochemical properties were carried out on the cyclic voltammograms. The results of the cyclic voltammograms indicated that [C₈mim]₃PMo₁₂O₄₀-ILCPE exhibited remarkable electrocatalytic activities toward the reduction of BrO₃^- and good stability. The value of I_pc was as a function with the concentration of bromate from 2 × 10^-6 to 1 × 10^-4 M, which indicated that the [C₈mim]₃PMo₁₂O₄₀-ILCPE can be a candidate for electrochemical sensor.

Original language	English
Pages (from-to)	155-162
Number of pages	8
Journal	Journal of Cluster Science
Volume	21
Issue number	2
DOIs	https://doi.org/10.1007/s10876-010-0302-1
Publication status	Published - 2010

Keywords

Carbon paste electrode
Electrochemical
Ionic liquid
Polyoxometalate

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title = "The electrochemical properties of 12-molybdophosphoric acid modified ionic liquid carbon paste electrode",

abstract = "A [C8mim]3PMo12O40-modified ionic liquid carbon paste electrode ([C8mim]3PMo12O40-ILCPE, C8mim = 1-methyl-3-octylimidazolium) was successfully fabricated. Its electrochemical properties were carried out on the cyclic voltammograms. The results of the cyclic voltammograms indicated that [C8mim]3PMo12O40-ILCPE exhibited remarkable electrocatalytic activities toward the reduction of BrO3- and good stability. The value of Ipc was as a function with the concentration of bromate from 2 × 10-6 to 1 × 10-4 M, which indicated that the [C8mim]3PMo12O40-ILCPE can be a candidate for electrochemical sensor.",

keywords = "Carbon paste electrode, Electrochemical, Ionic liquid, Polyoxometalate",

author = "Tao Dong and Jianbo Du and Minhua Cao and Changwen Hu",

year = "2010",

doi = "10.1007/s10876-010-0302-1",

language = "English",

volume = "21",

pages = "155--162",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "2",

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TY - JOUR

T1 - The electrochemical properties of 12-molybdophosphoric acid modified ionic liquid carbon paste electrode

AU - Dong, Tao

AU - Du, Jianbo

AU - Cao, Minhua

AU - Hu, Changwen

PY - 2010

Y1 - 2010

N2 - A [C8mim]3PMo12O40-modified ionic liquid carbon paste electrode ([C8mim]3PMo12O40-ILCPE, C8mim = 1-methyl-3-octylimidazolium) was successfully fabricated. Its electrochemical properties were carried out on the cyclic voltammograms. The results of the cyclic voltammograms indicated that [C8mim]3PMo12O40-ILCPE exhibited remarkable electrocatalytic activities toward the reduction of BrO3- and good stability. The value of Ipc was as a function with the concentration of bromate from 2 × 10-6 to 1 × 10-4 M, which indicated that the [C8mim]3PMo12O40-ILCPE can be a candidate for electrochemical sensor.

AB - A [C8mim]3PMo12O40-modified ionic liquid carbon paste electrode ([C8mim]3PMo12O40-ILCPE, C8mim = 1-methyl-3-octylimidazolium) was successfully fabricated. Its electrochemical properties were carried out on the cyclic voltammograms. The results of the cyclic voltammograms indicated that [C8mim]3PMo12O40-ILCPE exhibited remarkable electrocatalytic activities toward the reduction of BrO3- and good stability. The value of Ipc was as a function with the concentration of bromate from 2 × 10-6 to 1 × 10-4 M, which indicated that the [C8mim]3PMo12O40-ILCPE can be a candidate for electrochemical sensor.

KW - Carbon paste electrode

KW - Electrochemical

KW - Ionic liquid

KW - Polyoxometalate

UR - https://www.scopus.com/pages/publications/77953536392

U2 - 10.1007/s10876-010-0302-1

DO - 10.1007/s10876-010-0302-1

M3 - Article

AN - SCOPUS:77953536392

SN - 1040-7278

VL - 21

SP - 155

EP - 162

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 2

ER -

The electrochemical properties of 12-molybdophosphoric acid modified ionic liquid carbon paste electrode

Abstract

Keywords

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