The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers

Xiao Dong Yang; Cheng Chen; Ya Jun Zhang; Li Xuan Cai; Jie Zhang

doi:10.1016/j.inoche.2015.07.022

The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers

Xiao Dong Yang
, Cheng Chen
, Ya Jun Zhang
, Li Xuan Cai
, Jie Zhang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Two layer-like coordination polymers, {[Cd(Bpyen)_0.5(m-BDC)(H₂O)Br]·4H₂O}(1) and {[Cd(Bpyen)_0.5(o-BDC)Br]·H₂O}(2), have been solvothermally synthesized and structurally characterized. The two compounds own common rapid photochromic response but different decolorization behaviors. The photoproduct of compound 2 is more stable in air. The relationship between structure and photoresponsive behavior has been studied in detail.

Original language	English
Pages (from-to)	122-125
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	60
DOIs	https://doi.org/10.1016/j.inoche.2015.07.022
Publication status	Published - 27 Oct 2015
Externally published	Yes

Keywords

(6,3) topology
Bipyridinium
Cadmium(II) complex
Decolorization
Photochromism
Single crystal

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10.1016/j.inoche.2015.07.022

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title = "The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers",

abstract = "Two layer-like coordination polymers, \{[Cd(Bpyen)0.5(m-BDC)(H2O)Br]·4H2O\}(1) and \{[Cd(Bpyen)0.5(o-BDC)Br]·H2O\}(2), have been solvothermally synthesized and structurally characterized. The two compounds own common rapid photochromic response but different decolorization behaviors. The photoproduct of compound 2 is more stable in air. The relationship between structure and photoresponsive behavior has been studied in detail.",

keywords = "(6,3) topology, Bipyridinium, Cadmium(II) complex, Decolorization, Photochromism, Single crystal",

author = "Yang, \{Xiao Dong\} and Cheng Chen and Zhang, \{Ya Jun\} and Cai, \{Li Xuan\} and Jie Zhang",

year = "2015",

month = oct,

day = "27",

doi = "10.1016/j.inoche.2015.07.022",

language = "English",

volume = "60",

pages = "122--125",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers

AU - Yang, Xiao Dong

AU - Chen, Cheng

AU - Zhang, Ya Jun

AU - Cai, Li Xuan

AU - Zhang, Jie

PY - 2015/10/27

Y1 - 2015/10/27

N2 - Two layer-like coordination polymers, {[Cd(Bpyen)0.5(m-BDC)(H2O)Br]·4H2O}(1) and {[Cd(Bpyen)0.5(o-BDC)Br]·H2O}(2), have been solvothermally synthesized and structurally characterized. The two compounds own common rapid photochromic response but different decolorization behaviors. The photoproduct of compound 2 is more stable in air. The relationship between structure and photoresponsive behavior has been studied in detail.

AB - Two layer-like coordination polymers, {[Cd(Bpyen)0.5(m-BDC)(H2O)Br]·4H2O}(1) and {[Cd(Bpyen)0.5(o-BDC)Br]·H2O}(2), have been solvothermally synthesized and structurally characterized. The two compounds own common rapid photochromic response but different decolorization behaviors. The photoproduct of compound 2 is more stable in air. The relationship between structure and photoresponsive behavior has been studied in detail.

KW - (6,3) topology

KW - Bipyridinium

KW - Cadmium(II) complex

KW - Decolorization

KW - Photochromism

KW - Single crystal

UR - https://www.scopus.com/pages/publications/84940039699

U2 - 10.1016/j.inoche.2015.07.022

DO - 10.1016/j.inoche.2015.07.022

M3 - Article

AN - SCOPUS:84940039699

SN - 1387-7003

VL - 60

SP - 122

EP - 125

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

The effects of molecular configuration on the photochromism and decolorization of two bipyridinium-based coordination polymers

Abstract

Keywords

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