The effect of packing density on the electron-transfer kinetics of an azobenzenethiol monolayer on gold

Hui Bo Shao; Hua Zhong Yu; Jian Wei Zhao; Hao Li Zhang; Zhong Fan Liu

doi:10.1246/cl.1997.749

The effect of packing density on the electron-transfer kinetics of an azobenzenethiol monolayer on gold

Hui Bo Shao, Hua Zhong Yu, Jian Wei Zhao, Hao Li Zhang, Zhong Fan Liu^*

^*Corresponding author for this work

Peking University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The effect of molecular packing density on the electron transfer kinetics in an azobenzene self-assembled monolayer on gold was investigated for the first time by controlling the assembling time. The apparent electron transfer rate constant (k_s) showed a gradual decrease with increasing the molecular packing density, which can be well understood in terms of a structural inhibition occurred in the closely packed monolayer on the reduction/oxidation of azobenzene.

Original language	English
Pages (from-to)	749-750
Number of pages	2
Journal	Chemistry Letters
Issue number	8
DOIs	https://doi.org/10.1246/cl.1997.749
Publication status	Published - 1997
Externally published	Yes

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10.1246/cl.1997.749

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title = "The effect of packing density on the electron-transfer kinetics of an azobenzenethiol monolayer on gold",

abstract = "The effect of molecular packing density on the electron transfer kinetics in an azobenzene self-assembled monolayer on gold was investigated for the first time by controlling the assembling time. The apparent electron transfer rate constant (ks) showed a gradual decrease with increasing the molecular packing density, which can be well understood in terms of a structural inhibition occurred in the closely packed monolayer on the reduction/oxidation of azobenzene.",

author = "Shao, {Hui Bo} and Yu, {Hua Zhong} and Zhao, {Jian Wei} and Zhang, {Hao Li} and Liu, {Zhong Fan}",

year = "1997",

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language = "English",

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journal = "Chemistry Letters",

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T1 - The effect of packing density on the electron-transfer kinetics of an azobenzenethiol monolayer on gold

AU - Shao, Hui Bo

AU - Yu, Hua Zhong

AU - Zhao, Jian Wei

AU - Zhang, Hao Li

AU - Liu, Zhong Fan

PY - 1997

Y1 - 1997

N2 - The effect of molecular packing density on the electron transfer kinetics in an azobenzene self-assembled monolayer on gold was investigated for the first time by controlling the assembling time. The apparent electron transfer rate constant (ks) showed a gradual decrease with increasing the molecular packing density, which can be well understood in terms of a structural inhibition occurred in the closely packed monolayer on the reduction/oxidation of azobenzene.

AB - The effect of molecular packing density on the electron transfer kinetics in an azobenzene self-assembled monolayer on gold was investigated for the first time by controlling the assembling time. The apparent electron transfer rate constant (ks) showed a gradual decrease with increasing the molecular packing density, which can be well understood in terms of a structural inhibition occurred in the closely packed monolayer on the reduction/oxidation of azobenzene.

UR - http://www.scopus.com/inward/record.url?scp=0031518423&partnerID=8YFLogxK

U2 - 10.1246/cl.1997.749

DO - 10.1246/cl.1997.749

M3 - Article

AN - SCOPUS:0031518423

SN - 0366-7022

SP - 749

EP - 750

JO - Chemistry Letters

JF - Chemistry Letters

IS - 8

ER -

The effect of packing density on the electron-transfer kinetics of an azobenzenethiol monolayer on gold

Abstract

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