The effect of mixed amines on the competitive formation of two open-framework zinc phosphates with 16-ring large channels

You Wei Yao; Guang Zhen Liu; Shou Tian Zheng; Guo Yu Yang

doi:10.1016/j.micromeso.2007.09.032

The effect of mixed amines on the competitive formation of two open-framework zinc phosphates with 16-ring large channels

You Wei Yao
, Guang Zhen Liu
, Shou Tian Zheng
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter
Luoyang Normal University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Two new zinc phosphates, Zn₆P₈O₂₆(OH)₆[H₃dien]₂ (I) and Zn₆P₈O₂₉(OH)₃[H₃dien]₃ (II) (dien = diethylenetriamine), were solvothermally synthesized in the presence of a mixture of organic amines. Both two structures are built by the alternate linkages between ZnO₄ and (H)PO₄ tetrahedral moieties producing two intimately related (3,4)-connected framework structures with the 16-ring large channels. The successful synthesis of the two compounds illustrates that a specific "secondary" organic additive governs the resulting open-framework structures besides a "primary" organic amine plays a structure-directing role. Crystal data: triclinic, P over(1, ̄), a = 8.5619(1), b = 13.5037(2), c = 16.9251(1) Å, α = 69.545(1)°, β = 89.573(1)°, γ = 86.684(1)°, V = 1830.21(4) Å³, Z = 2 for I, and monoclinic, P2₁/c, a = 31.9204(3), b = 8.3759(2), c = 15.7894(3) Å, β = 97.062(1)°, V = 4189.46(13) Å³, Z = 4 for II.

Original language	English
Pages (from-to)	219-224
Number of pages	6
Journal	Microporous and Mesoporous Materials
Volume	112
Issue number	1-3
DOIs	https://doi.org/10.1016/j.micromeso.2007.09.032
Publication status	Published - 1 Jul 2008
Externally published	Yes

Keywords

Hydro-/solvo-thermal synthesis
Mixed-templated synthesis
Open-framework
Phosphates

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10.1016/j.micromeso.2007.09.032

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@article{ec703ec5b67e47ddaf6d3c0e8ec93119,

title = "The effect of mixed amines on the competitive formation of two open-framework zinc phosphates with 16-ring large channels",

abstract = "Two new zinc phosphates, Zn6P8O26(OH)6[H3dien]2 (I) and Zn6P8O29(OH)3[H3dien]3 (II) (dien = diethylenetriamine), were solvothermally synthesized in the presence of a mixture of organic amines. Both two structures are built by the alternate linkages between ZnO4 and (H)PO4 tetrahedral moieties producing two intimately related (3,4)-connected framework structures with the 16-ring large channels. The successful synthesis of the two compounds illustrates that a specific {"}secondary{"} organic additive governs the resulting open-framework structures besides a {"}primary{"} organic amine plays a structure-directing role. Crystal data: triclinic, P over(1,{\= }), a = 8.5619(1), b = 13.5037(2), c = 16.9251(1) {\AA}, α = 69.545(1)°, β = 89.573(1)°, γ = 86.684(1)°, V = 1830.21(4) {\AA}3, Z = 2 for I, and monoclinic, P21/c, a = 31.9204(3), b = 8.3759(2), c = 15.7894(3) {\AA}, β = 97.062(1)°, V = 4189.46(13) {\AA}3, Z = 4 for II.",

keywords = "Hydro-/solvo-thermal synthesis, Mixed-templated synthesis, Open-framework, Phosphates",

author = "Yao, \{You Wei\} and Liu, \{Guang Zhen\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2008",

month = jul,

day = "1",

doi = "10.1016/j.micromeso.2007.09.032",

language = "English",

volume = "112",

pages = "219--224",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - The effect of mixed amines on the competitive formation of two open-framework zinc phosphates with 16-ring large channels

AU - Yao, You Wei

AU - Liu, Guang Zhen

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2008/7/1

Y1 - 2008/7/1

N2 - Two new zinc phosphates, Zn6P8O26(OH)6[H3dien]2 (I) and Zn6P8O29(OH)3[H3dien]3 (II) (dien = diethylenetriamine), were solvothermally synthesized in the presence of a mixture of organic amines. Both two structures are built by the alternate linkages between ZnO4 and (H)PO4 tetrahedral moieties producing two intimately related (3,4)-connected framework structures with the 16-ring large channels. The successful synthesis of the two compounds illustrates that a specific "secondary" organic additive governs the resulting open-framework structures besides a "primary" organic amine plays a structure-directing role. Crystal data: triclinic, P over(1, ̄), a = 8.5619(1), b = 13.5037(2), c = 16.9251(1) Å, α = 69.545(1)°, β = 89.573(1)°, γ = 86.684(1)°, V = 1830.21(4) Å3, Z = 2 for I, and monoclinic, P21/c, a = 31.9204(3), b = 8.3759(2), c = 15.7894(3) Å, β = 97.062(1)°, V = 4189.46(13) Å3, Z = 4 for II.

AB - Two new zinc phosphates, Zn6P8O26(OH)6[H3dien]2 (I) and Zn6P8O29(OH)3[H3dien]3 (II) (dien = diethylenetriamine), were solvothermally synthesized in the presence of a mixture of organic amines. Both two structures are built by the alternate linkages between ZnO4 and (H)PO4 tetrahedral moieties producing two intimately related (3,4)-connected framework structures with the 16-ring large channels. The successful synthesis of the two compounds illustrates that a specific "secondary" organic additive governs the resulting open-framework structures besides a "primary" organic amine plays a structure-directing role. Crystal data: triclinic, P over(1, ̄), a = 8.5619(1), b = 13.5037(2), c = 16.9251(1) Å, α = 69.545(1)°, β = 89.573(1)°, γ = 86.684(1)°, V = 1830.21(4) Å3, Z = 2 for I, and monoclinic, P21/c, a = 31.9204(3), b = 8.3759(2), c = 15.7894(3) Å, β = 97.062(1)°, V = 4189.46(13) Å3, Z = 4 for II.

KW - Hydro-/solvo-thermal synthesis

KW - Mixed-templated synthesis

KW - Open-framework

KW - Phosphates

UR - https://www.scopus.com/pages/publications/43249085268

U2 - 10.1016/j.micromeso.2007.09.032

DO - 10.1016/j.micromeso.2007.09.032

M3 - Article

AN - SCOPUS:43249085268

SN - 1387-1811

VL - 112

SP - 219

EP - 224

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 1-3

ER -

The effect of mixed amines on the competitive formation of two open-framework zinc phosphates with 16-ring large channels

Abstract

Keywords

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