Temperature-Dependent Organic Functionalization of {Ni6PW9} Species: From Isolated Clusters to 1D Chain

Bin Cai; Jun Wei Zhao; Bai Feng Yang; Huan He; Guo Yu Yang

doi:10.1007/s10876-014-0690-8

Temperature-Dependent Organic Functionalization of {Ni₆PW₉} Species: From Isolated Clusters to 1D Chain

Bin Cai
, Jun Wei Zhao^*
, Bai Feng Yang
, Huan He
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
Henan University
CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Four new hexa-nickel(II)-substituted Keggin-type tungstophosphates [Ni₆(μ₃-OH)₃(oeen)₃(H₂O)₃(B-α-PW₉O₃₄)]·6H₂O (1, oeen = N-(2-hydroxyethyl)enediamine), [Ni₆(μ₃-OH)₃(oeen)₃(H₂O)₄(B-α-PW₉O₃₄)]₂·13H₂O (2), [Ni₆(μ₃-OH)₃(oeen)₂(tran)(H₂O)₃(B-α-PW₉O₃₄)]·3H₂O (3, tran = 1,4,7-triazonane) and [Ni₆(μ₃-OH)₃(oeen)₂(tran)(H₂O)₂(B-α-PW₉O₃₄)]·6H₂O (4) have hydrothermally made by controlling their reaction temperatures. 1-4 have been characterized by elemental analyses, IR spectra, powder X-ray diffraction, thermogravimetric analyses and single-crystal X-ray diffraction, respectively. Structural analyses reveal that they consist of {Ni₆(μ₃-OH)₃(H₂O)_n}⁹⁺ cores and B-α-PW₉O₃₄ (PW₉) units, and further are stabilized by organic neutral oeen/tran molecules. 1-3 are isolated clusters while 4 is the 1D chain structure. It should be noted that the tran molecules in 3 and 4 are derived from the oeen molecules in the starting materials.

Original language	English
Pages (from-to)	1069-1084
Number of pages	16
Journal	Journal of Cluster Science
Volume	25
Issue number	4
DOIs	https://doi.org/10.1007/s10876-014-0690-8
Publication status	Published - Jul 2014

Keywords

Hydrothermal reaction
Lacunary precursor
Organic functionalization
Polyoxometalate
Temperature-dependent synthesis

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10.1007/s10876-014-0690-8

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@article{1459cd7f7907495f8a0d7ade19855401,

title = "Temperature-Dependent Organic Functionalization of \{Ni6PW9\} Species: From Isolated Clusters to 1D Chain",

abstract = "Four new hexa-nickel(II)-substituted Keggin-type tungstophosphates [Ni6(μ3-OH)3(oeen)3(H2O)3(B-α-PW9O34)]·6H2O (1, oeen = N-(2-hydroxyethyl)enediamine), [Ni6(μ3-OH)3(oeen)3(H2O)4(B-α-PW9O34)]2·13H2O (2), [Ni6(μ3-OH)3(oeen)2(tran)(H2O)3(B-α-PW9O34)]·3H2O (3, tran = 1,4,7-triazonane) and [Ni6(μ3-OH)3(oeen)2(tran)(H2O)2(B-α-PW9O34)]·6H2O (4) have hydrothermally made by controlling their reaction temperatures. 1-4 have been characterized by elemental analyses, IR spectra, powder X-ray diffraction, thermogravimetric analyses and single-crystal X-ray diffraction, respectively. Structural analyses reveal that they consist of \{Ni6(μ3-OH)3(H2O)n\}9+ cores and B-α-PW9O34 (PW9) units, and further are stabilized by organic neutral oeen/tran molecules. 1-3 are isolated clusters while 4 is the 1D chain structure. It should be noted that the tran molecules in 3 and 4 are derived from the oeen molecules in the starting materials.",

keywords = "Hydrothermal reaction, Lacunary precursor, Organic functionalization, Polyoxometalate, Temperature-dependent synthesis",

author = "Bin Cai and Zhao, \{Jun Wei\} and Yang, \{Bai Feng\} and Huan He and Yang, \{Guo Yu\}",

year = "2014",

month = jul,

doi = "10.1007/s10876-014-0690-8",

language = "English",

volume = "25",

pages = "1069--1084",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "4",

}

TY - JOUR

T1 - Temperature-Dependent Organic Functionalization of {Ni6PW9} Species

T2 - From Isolated Clusters to 1D Chain

AU - Cai, Bin

AU - Zhao, Jun Wei

AU - Yang, Bai Feng

AU - He, Huan

AU - Yang, Guo Yu

PY - 2014/7

Y1 - 2014/7

N2 - Four new hexa-nickel(II)-substituted Keggin-type tungstophosphates [Ni6(μ3-OH)3(oeen)3(H2O)3(B-α-PW9O34)]·6H2O (1, oeen = N-(2-hydroxyethyl)enediamine), [Ni6(μ3-OH)3(oeen)3(H2O)4(B-α-PW9O34)]2·13H2O (2), [Ni6(μ3-OH)3(oeen)2(tran)(H2O)3(B-α-PW9O34)]·3H2O (3, tran = 1,4,7-triazonane) and [Ni6(μ3-OH)3(oeen)2(tran)(H2O)2(B-α-PW9O34)]·6H2O (4) have hydrothermally made by controlling their reaction temperatures. 1-4 have been characterized by elemental analyses, IR spectra, powder X-ray diffraction, thermogravimetric analyses and single-crystal X-ray diffraction, respectively. Structural analyses reveal that they consist of {Ni6(μ3-OH)3(H2O)n}9+ cores and B-α-PW9O34 (PW9) units, and further are stabilized by organic neutral oeen/tran molecules. 1-3 are isolated clusters while 4 is the 1D chain structure. It should be noted that the tran molecules in 3 and 4 are derived from the oeen molecules in the starting materials.

AB - Four new hexa-nickel(II)-substituted Keggin-type tungstophosphates [Ni6(μ3-OH)3(oeen)3(H2O)3(B-α-PW9O34)]·6H2O (1, oeen = N-(2-hydroxyethyl)enediamine), [Ni6(μ3-OH)3(oeen)3(H2O)4(B-α-PW9O34)]2·13H2O (2), [Ni6(μ3-OH)3(oeen)2(tran)(H2O)3(B-α-PW9O34)]·3H2O (3, tran = 1,4,7-triazonane) and [Ni6(μ3-OH)3(oeen)2(tran)(H2O)2(B-α-PW9O34)]·6H2O (4) have hydrothermally made by controlling their reaction temperatures. 1-4 have been characterized by elemental analyses, IR spectra, powder X-ray diffraction, thermogravimetric analyses and single-crystal X-ray diffraction, respectively. Structural analyses reveal that they consist of {Ni6(μ3-OH)3(H2O)n}9+ cores and B-α-PW9O34 (PW9) units, and further are stabilized by organic neutral oeen/tran molecules. 1-3 are isolated clusters while 4 is the 1D chain structure. It should be noted that the tran molecules in 3 and 4 are derived from the oeen molecules in the starting materials.

KW - Hydrothermal reaction

KW - Lacunary precursor

KW - Organic functionalization

KW - Polyoxometalate

KW - Temperature-dependent synthesis

UR - https://www.scopus.com/pages/publications/84904203488

U2 - 10.1007/s10876-014-0690-8

DO - 10.1007/s10876-014-0690-8

M3 - Article

AN - SCOPUS:84904203488

SN - 1040-7278

VL - 25

SP - 1069

EP - 1084

JO - Journal of Cluster Science

JF - Journal of Cluster Science

IS - 4

ER -

Temperature-Dependent Organic Functionalization of {Ni₆PW₉} Species: From Isolated Clusters to 1D Chain

Abstract

Keywords

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