Synthesis, structure and properties of a new noncentrosymmetric aluminoborate

Qin Meng; Guo Ming Wang; Bai Feng Yang; Huan He; Guo Yu Yang

doi:10.1016/j.inoche.2013.12.005

Synthesis, structure and properties of a new noncentrosymmetric aluminoborate

Qin Meng
, Guo Ming Wang^*
, Bai Feng Yang
, Huan He
, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
Qingdao University
CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A new noncentrosymmetric aluminoborate (H₂TETA)[Al(B ₅O₁₀)] (1), has been solvothermally synthesized by using triethylenetetramine (TETA) as the structure-directing agent. Single-crystal X-ray diffraction analysis reveals that the compound crystallizes in the orthorhombic space group Pna2₁ with unit cell parameters a = 12.9696(9) Å, b = 17.0035(8) Å, c = 7.3660(5) Å, V = 1624.41(18) Å³ and Z = 4. Its structure consists of AlO ₄ tetrahedra and B₅O₁₀ clusters and possesses 8-, 11- and 14-ring channels with sra topology. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits moderate SHG signals approximately 1.5 times that of KH₂PO₄ (KDP).

Original language	English
Pages (from-to)	168-171
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	40
DOIs	https://doi.org/10.1016/j.inoche.2013.12.005
Publication status	Published - Feb 2014

Keywords

Aluminoborate
Crystal structure
Nonlinear optical
Solvothermal synthesis

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10.1016/j.inoche.2013.12.005

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@article{9bc79a422bf648e796370f6b0902f17a,

title = "Synthesis, structure and properties of a new noncentrosymmetric aluminoborate",

abstract = "A new noncentrosymmetric aluminoborate (H2TETA)[Al(B 5O10)] (1), has been solvothermally synthesized by using triethylenetetramine (TETA) as the structure-directing agent. Single-crystal X-ray diffraction analysis reveals that the compound crystallizes in the orthorhombic space group Pna21 with unit cell parameters a = 12.9696(9) {\AA}, b = 17.0035(8) {\AA}, c = 7.3660(5) {\AA}, V = 1624.41(18) {\AA}3 and Z = 4. Its structure consists of AlO 4 tetrahedra and B5O10 clusters and possesses 8-, 11- and 14-ring channels with sra topology. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits moderate SHG signals approximately 1.5 times that of KH2PO4 (KDP).",

keywords = "Aluminoborate, Crystal structure, Nonlinear optical, Solvothermal synthesis",

author = "Qin Meng and Wang, \{Guo Ming\} and Yang, \{Bai Feng\} and Huan He and Yang, \{Guo Yu\}",

year = "2014",

month = feb,

doi = "10.1016/j.inoche.2013.12.005",

language = "English",

volume = "40",

pages = "168--171",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Synthesis, structure and properties of a new noncentrosymmetric aluminoborate

AU - Meng, Qin

AU - Wang, Guo Ming

AU - Yang, Bai Feng

AU - He, Huan

AU - Yang, Guo Yu

PY - 2014/2

Y1 - 2014/2

N2 - A new noncentrosymmetric aluminoborate (H2TETA)[Al(B 5O10)] (1), has been solvothermally synthesized by using triethylenetetramine (TETA) as the structure-directing agent. Single-crystal X-ray diffraction analysis reveals that the compound crystallizes in the orthorhombic space group Pna21 with unit cell parameters a = 12.9696(9) Å, b = 17.0035(8) Å, c = 7.3660(5) Å, V = 1624.41(18) Å3 and Z = 4. Its structure consists of AlO 4 tetrahedra and B5O10 clusters and possesses 8-, 11- and 14-ring channels with sra topology. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits moderate SHG signals approximately 1.5 times that of KH2PO4 (KDP).

AB - A new noncentrosymmetric aluminoborate (H2TETA)[Al(B 5O10)] (1), has been solvothermally synthesized by using triethylenetetramine (TETA) as the structure-directing agent. Single-crystal X-ray diffraction analysis reveals that the compound crystallizes in the orthorhombic space group Pna21 with unit cell parameters a = 12.9696(9) Å, b = 17.0035(8) Å, c = 7.3660(5) Å, V = 1624.41(18) Å3 and Z = 4. Its structure consists of AlO 4 tetrahedra and B5O10 clusters and possesses 8-, 11- and 14-ring channels with sra topology. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits moderate SHG signals approximately 1.5 times that of KH2PO4 (KDP).

KW - Aluminoborate

KW - Crystal structure

KW - Nonlinear optical

KW - Solvothermal synthesis

UR - https://www.scopus.com/pages/publications/84891677278

U2 - 10.1016/j.inoche.2013.12.005

DO - 10.1016/j.inoche.2013.12.005

M3 - Article

AN - SCOPUS:84891677278

SN - 1387-7003

VL - 40

SP - 168

EP - 171

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Synthesis, structure and properties of a new noncentrosymmetric aluminoborate

Abstract

Keywords

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