Synthesis, structure and properties of a neutral zincophosphate monomer decorated with 2,2′-bipyridine ligands

Zhi En Lin; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1016/S1387-7003(03)00178-3

Synthesis, structure and properties of a neutral zincophosphate monomer decorated with 2,2′-bipyridine ligands

Zhi En Lin
, Jie Zhang
, Shou Tian Zheng
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A neutral zincophosphate monomer [Zn(2,2′-bipy)]₂(H₂PO₄)₄ has been synthesized under hydrothermal condition in the presence of 2,2′-bipyridine ligands. The structure consists of a 4-membered ring formed by vertex-sharing ZnO₃N₂ square pyramids and H₂PO₄ tetrahedra, with two H₂PO₄ groups hanging from the zinc atoms. This compound exhibits intense photoluminescence upon photoexcitation at 388 nm.

Original language	English
Pages (from-to)	1035-1038
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	8
DOIs	https://doi.org/10.1016/S1387-7003(03)00178-3
Publication status	Published - 1 Aug 2003
Externally published	Yes

Keywords

Crystal structure
Hybrid materials
Hydrothermal synthesis
Luminescence
Zinc phosphate

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10.1016/S1387-7003(03)00178-3

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title = "Synthesis, structure and properties of a neutral zincophosphate monomer decorated with 2,2′-bipyridine ligands",

abstract = "A neutral zincophosphate monomer [Zn(2,2′-bipy)]2(H2PO4)4 has been synthesized under hydrothermal condition in the presence of 2,2′-bipyridine ligands. The structure consists of a 4-membered ring formed by vertex-sharing ZnO3N2 square pyramids and H2PO4 tetrahedra, with two H2PO4 groups hanging from the zinc atoms. This compound exhibits intense photoluminescence upon photoexcitation at 388 nm.",

keywords = "Crystal structure, Hybrid materials, Hydrothermal synthesis, Luminescence, Zinc phosphate",

author = "Lin, \{Zhi En\} and Jie Zhang and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2003",

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doi = "10.1016/S1387-7003(03)00178-3",

language = "English",

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T1 - Synthesis, structure and properties of a neutral zincophosphate monomer decorated with 2,2′-bipyridine ligands

AU - Lin, Zhi En

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2003/8/1

Y1 - 2003/8/1

N2 - A neutral zincophosphate monomer [Zn(2,2′-bipy)]2(H2PO4)4 has been synthesized under hydrothermal condition in the presence of 2,2′-bipyridine ligands. The structure consists of a 4-membered ring formed by vertex-sharing ZnO3N2 square pyramids and H2PO4 tetrahedra, with two H2PO4 groups hanging from the zinc atoms. This compound exhibits intense photoluminescence upon photoexcitation at 388 nm.

AB - A neutral zincophosphate monomer [Zn(2,2′-bipy)]2(H2PO4)4 has been synthesized under hydrothermal condition in the presence of 2,2′-bipyridine ligands. The structure consists of a 4-membered ring formed by vertex-sharing ZnO3N2 square pyramids and H2PO4 tetrahedra, with two H2PO4 groups hanging from the zinc atoms. This compound exhibits intense photoluminescence upon photoexcitation at 388 nm.

KW - Crystal structure

KW - Hybrid materials

KW - Hydrothermal synthesis

KW - Luminescence

KW - Zinc phosphate

UR - https://www.scopus.com/pages/publications/0042709617

U2 - 10.1016/S1387-7003(03)00178-3

DO - 10.1016/S1387-7003(03)00178-3

M3 - Article

AN - SCOPUS:0042709617

SN - 1387-7003

VL - 6

SP - 1035

EP - 1038

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 8

ER -

Synthesis, structure and properties of a neutral zincophosphate monomer decorated with 2,2′-bipyridine ligands

Abstract

Keywords

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