Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2]

Hong Peng Jia; Wei Li; Zhan Feng Ju; Jie Zhang

doi:10.1016/j.inoche.2006.12.009

Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn₂Ni₂(MeOSalen)₂(μ_1,1-N₃)₂(N₃)₂]

Hong Peng Jia
, Wei Li
, Zhan Feng Ju
, Jie Zhang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

46 Citations (Scopus)

Abstract

The first heterometal tetranuclear complex with alternating azido and phenoxo bridges, [Mn₂Ni₂(MeOSalen)₂(μ_1,1-N₃)₂(N₃)₂] (MeOSalenH₂ = bis(3-methoxy)salicylideneimine), was synthesized and structurally characterized by X-ray crystallography and spectroscopic methods. Magnetic studies suggest there is a ferromagnetic interaction between the μ_1,1-azido-bridged Mn(II) ions with J = +2.11 cm^-1, while the Ni(II) ions are diamagnetic in the tetranuclear system.

Original language	English
Pages (from-to)	397-400
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	4
DOIs	https://doi.org/10.1016/j.inoche.2006.12.009
Publication status	Published - Apr 2007
Externally published	Yes

Keywords

Crystal structure
Heterometallic complex
Magnetic properties
Manganese(II)
Nickel(II)
Schiff-base

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10.1016/j.inoche.2006.12.009

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title = "Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2]",

abstract = "The first heterometal tetranuclear complex with alternating azido and phenoxo bridges, [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2] (MeOSalenH2 = bis(3-methoxy)salicylideneimine), was synthesized and structurally characterized by X-ray crystallography and spectroscopic methods. Magnetic studies suggest there is a ferromagnetic interaction between the μ1,1-azido-bridged Mn(II) ions with J = +2.11 cm-1, while the Ni(II) ions are diamagnetic in the tetranuclear system.",

keywords = "Crystal structure, Heterometallic complex, Magnetic properties, Manganese(II), Nickel(II), Schiff-base",

author = "Jia, \{Hong Peng\} and Wei Li and Ju, \{Zhan Feng\} and Jie Zhang",

year = "2007",

month = apr,

doi = "10.1016/j.inoche.2006.12.009",

language = "English",

volume = "10",

pages = "397--400",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2]

AU - Jia, Hong Peng

AU - Li, Wei

AU - Ju, Zhan Feng

AU - Zhang, Jie

PY - 2007/4

Y1 - 2007/4

N2 - The first heterometal tetranuclear complex with alternating azido and phenoxo bridges, [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2] (MeOSalenH2 = bis(3-methoxy)salicylideneimine), was synthesized and structurally characterized by X-ray crystallography and spectroscopic methods. Magnetic studies suggest there is a ferromagnetic interaction between the μ1,1-azido-bridged Mn(II) ions with J = +2.11 cm-1, while the Ni(II) ions are diamagnetic in the tetranuclear system.

AB - The first heterometal tetranuclear complex with alternating azido and phenoxo bridges, [Mn2Ni2(MeOSalen)2(μ1,1-N3)2(N3)2] (MeOSalenH2 = bis(3-methoxy)salicylideneimine), was synthesized and structurally characterized by X-ray crystallography and spectroscopic methods. Magnetic studies suggest there is a ferromagnetic interaction between the μ1,1-azido-bridged Mn(II) ions with J = +2.11 cm-1, while the Ni(II) ions are diamagnetic in the tetranuclear system.

KW - Crystal structure

KW - Heterometallic complex

KW - Magnetic properties

KW - Manganese(II)

KW - Nickel(II)

KW - Schiff-base

UR - https://www.scopus.com/pages/publications/33847329571

U2 - 10.1016/j.inoche.2006.12.009

DO - 10.1016/j.inoche.2006.12.009

M3 - Article

AN - SCOPUS:33847329571

SN - 1387-7003

VL - 10

SP - 397

EP - 400

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 4

ER -

Synthesis, structure, and magnetic properties of a novel mixed-bridged heterometal tetranuclear complex [Mn₂Ni₂(MeOSalen)₂(μ_1,1-N₃)₂(N₃)₂]

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Keywords

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