Synthesis, structure and characterization of a new nonlinear optical calcium borate [Ca2B5O9]·[H(OH)2]

Yu Jia Sun; Zhong Zhang; Yue Lin Wang; Guo Yu Yang

doi:10.1016/j.inoche.2017.11.006

Synthesis, structure and characterization of a new nonlinear optical calcium borate [Ca₂B₅O₉]·[H(OH)₂]

Yu Jia Sun
, Zhong Zhang
, Yue Lin Wang
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A new nonlinear optical crystal [Ca₂B₅O₉]·[H(OH)₂] (1) has been synthesized under hydrothermal condition. Compound 1 crystallizes in the monoclinic space group C2 with lattice constants a = 10.111(2) Å, b = 7.754(11) Å, c = 6.198(14) Å, β = 127.04(3)° and Z = 2. The fundamental building block (FBB) of 1 is a [B₅O₁₂] unit with two BO₃ triangles and three BO₄ tetrahedra. 1 was characterized by single-crystal X-ray diffraction, IR and UV–Vis spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) respectively. Also, powder second harmonic generation (SHG) measurements indicate that 1 is phase matchable and displays a SHG response of about 3.5 times that of KDP (KH₂PO₄).

Original language	English
Pages (from-to)	308-311
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	86
DOIs	https://doi.org/10.1016/j.inoche.2017.11.006
Publication status	Published - Dec 2017

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@article{3a8244405f4d46998ec97cbdcf7efd1d,

title = "Synthesis, structure and characterization of a new nonlinear optical calcium borate [Ca2B5O9]·[H(OH)2]",

abstract = "A new nonlinear optical crystal [Ca2B5O9]·[H(OH)2] (1) has been synthesized under hydrothermal condition. Compound 1 crystallizes in the monoclinic space group C2 with lattice constants a = 10.111(2) {\AA}, b = 7.754(11) {\AA}, c = 6.198(14) {\AA}, β = 127.04(3)° and Z = 2. The fundamental building block (FBB) of 1 is a [B5O12] unit with two BO3 triangles and three BO4 tetrahedra. 1 was characterized by single-crystal X-ray diffraction, IR and UV–Vis spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) respectively. Also, powder second harmonic generation (SHG) measurements indicate that 1 is phase matchable and displays a SHG response of about 3.5 times that of KDP (KH2PO4).",

author = "Sun, \{Yu Jia\} and Zhong Zhang and Wang, \{Yue Lin\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2017",

year = "2017",

month = dec,

doi = "10.1016/j.inoche.2017.11.006",

language = "English",

volume = "86",

pages = "308--311",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Synthesis, structure and characterization of a new nonlinear optical calcium borate [Ca2B5O9]·[H(OH)2]

AU - Sun, Yu Jia

AU - Zhang, Zhong

AU - Wang, Yue Lin

AU - Yang, Guo Yu

PY - 2017/12

Y1 - 2017/12

N2 - A new nonlinear optical crystal [Ca2B5O9]·[H(OH)2] (1) has been synthesized under hydrothermal condition. Compound 1 crystallizes in the monoclinic space group C2 with lattice constants a = 10.111(2) Å, b = 7.754(11) Å, c = 6.198(14) Å, β = 127.04(3)° and Z = 2. The fundamental building block (FBB) of 1 is a [B5O12] unit with two BO3 triangles and three BO4 tetrahedra. 1 was characterized by single-crystal X-ray diffraction, IR and UV–Vis spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) respectively. Also, powder second harmonic generation (SHG) measurements indicate that 1 is phase matchable and displays a SHG response of about 3.5 times that of KDP (KH2PO4).

AB - A new nonlinear optical crystal [Ca2B5O9]·[H(OH)2] (1) has been synthesized under hydrothermal condition. Compound 1 crystallizes in the monoclinic space group C2 with lattice constants a = 10.111(2) Å, b = 7.754(11) Å, c = 6.198(14) Å, β = 127.04(3)° and Z = 2. The fundamental building block (FBB) of 1 is a [B5O12] unit with two BO3 triangles and three BO4 tetrahedra. 1 was characterized by single-crystal X-ray diffraction, IR and UV–Vis spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) respectively. Also, powder second harmonic generation (SHG) measurements indicate that 1 is phase matchable and displays a SHG response of about 3.5 times that of KDP (KH2PO4).

UR - https://www.scopus.com/pages/publications/85034074746

U2 - 10.1016/j.inoche.2017.11.006

DO - 10.1016/j.inoche.2017.11.006

M3 - Article

AN - SCOPUS:85034074746

SN - 1387-7003

VL - 86

SP - 308

EP - 311

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Synthesis, structure and characterization of a new nonlinear optical calcium borate [Ca₂B₅O₉]·[H(OH)₂]

Abstract

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