Synthesis, Structure, and Antibacterial Activity of a Thallium(III)-Containing Polyoxometalate, [Tl2{B-β-SiW8O30(OH)}2]12-

Wassim W. Ayass; Tamás Fodor; Zhengguo Lin; Rachelle M. Smith; Xiaolin Xing; Khaled Abdallah; Imre Tóth; László Zékány; Magda Pascual-Borràs; Antonio Rodríguez-Fortea; Josep M. Poblet; Linyuan Fan; Jie Cao; Bineta Keita; Matthias S. Ullrich; Ulrich Kortz

doi:10.1021/acs.inorgchem.6b01921

Synthesis, Structure, and Antibacterial Activity of a Thallium(III)-Containing Polyoxometalate, [Tl₂{B-β-SiW₈O₃₀(OH)}₂]^12-

Wassim W. Ayass, Tamás Fodor, Zhengguo Lin, Rachelle M. Smith, Xiaolin Xing, Khaled Abdallah, Imre Tóth^*, László Zékány, Magda Pascual-Borràs, Antonio Rodríguez-Fortea, Josep M. Poblet, Linyuan Fan, Jie Cao, Bineta Keita, Matthias S. Ullrich, Ulrich Kortz

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

We have synthesized and structurally characterized the first discrete thallium-containing polyoxometalate, [Tl₂{B-β-SiW₈O₃₀(OH)}₂]^12- (1). Polyanion 1 was characterized in the solid-state and shown to be solution-stable by ^203/205Tl NMR, electrospray ionization mass spectrometry, and electrochemical studies. The antibacterial activity of 1 was also investigated.

Original language	English
Pages (from-to)	10118-10121
Number of pages	4
Journal	Inorganic Chemistry
Volume	55
Issue number	20
DOIs	https://doi.org/10.1021/acs.inorgchem.6b01921
Publication status	Published - 17 Oct 2016
Externally published	Yes

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Ayass, W. W., Fodor, T., Lin, Z., Smith, R. M., Xing, X., Abdallah, K., Tóth, I., Zékány, L., Pascual-Borràs, M., Rodríguez-Fortea, A., Poblet, J. M., Fan, L., Cao, J., Keita, B., Ullrich, M. S., & Kortz, U. (2016). Synthesis, Structure, and Antibacterial Activity of a Thallium(III)-Containing Polyoxometalate, [Tl₂{B-β-SiW₈O₃₀(OH)}₂]^12-. Inorganic Chemistry, 55(20), 10118-10121. https://doi.org/10.1021/acs.inorgchem.6b01921

@article{7645fb8c82784d92b4b75d17d25ae431,

title = "Synthesis, Structure, and Antibacterial Activity of a Thallium(III)-Containing Polyoxometalate, [Tl2{B-β-SiW8O30(OH)}2]12-",

abstract = "We have synthesized and structurally characterized the first discrete thallium-containing polyoxometalate, [Tl2{B-β-SiW8O30(OH)}2]12- (1). Polyanion 1 was characterized in the solid-state and shown to be solution-stable by 203/205Tl NMR, electrospray ionization mass spectrometry, and electrochemical studies. The antibacterial activity of 1 was also investigated.",

author = "Ayass, {Wassim W.} and Tam{\'a}s Fodor and Zhengguo Lin and Smith, {Rachelle M.} and Xiaolin Xing and Khaled Abdallah and Imre T{\'o}th and L{\'a}szl{\'o} Z{\'e}k{\'a}ny and Magda Pascual-Borr{\`a}s and Antonio Rodr{\'i}guez-Fortea and Poblet, {Josep M.} and Linyuan Fan and Jie Cao and Bineta Keita and Ullrich, {Matthias S.} and Ulrich Kortz",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = oct,

day = "17",

doi = "10.1021/acs.inorgchem.6b01921",

language = "English",

volume = "55",

pages = "10118--10121",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "20",

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Ayass, WW, Fodor, T, Lin, Z, Smith, RM, Xing, X, Abdallah, K, Tóth, I, Zékány, L, Pascual-Borràs, M, Rodríguez-Fortea, A, Poblet, JM, Fan, L, Cao, J, Keita, B, Ullrich, MS & Kortz, U 2016, 'Synthesis, Structure, and Antibacterial Activity of a Thallium(III)-Containing Polyoxometalate, [Tl₂{B-β-SiW₈O₃₀(OH)}₂]^12-', Inorganic Chemistry, vol. 55, no. 20, pp. 10118-10121. https://doi.org/10.1021/acs.inorgchem.6b01921

TY - JOUR

T1 - Synthesis, Structure, and Antibacterial Activity of a Thallium(III)-Containing Polyoxometalate, [Tl2{B-β-SiW8O30(OH)}2]12-

AU - Ayass, Wassim W.

AU - Fodor, Tamás

AU - Lin, Zhengguo

AU - Smith, Rachelle M.

AU - Xing, Xiaolin

AU - Abdallah, Khaled

AU - Tóth, Imre

AU - Zékány, László

AU - Pascual-Borràs, Magda

AU - Rodríguez-Fortea, Antonio

AU - Poblet, Josep M.

AU - Fan, Linyuan

AU - Cao, Jie

AU - Keita, Bineta

AU - Ullrich, Matthias S.

AU - Kortz, Ulrich

PY - 2016/10/17

Y1 - 2016/10/17

N2 - We have synthesized and structurally characterized the first discrete thallium-containing polyoxometalate, [Tl2{B-β-SiW8O30(OH)}2]12- (1). Polyanion 1 was characterized in the solid-state and shown to be solution-stable by 203/205Tl NMR, electrospray ionization mass spectrometry, and electrochemical studies. The antibacterial activity of 1 was also investigated.

AB - We have synthesized and structurally characterized the first discrete thallium-containing polyoxometalate, [Tl2{B-β-SiW8O30(OH)}2]12- (1). Polyanion 1 was characterized in the solid-state and shown to be solution-stable by 203/205Tl NMR, electrospray ionization mass spectrometry, and electrochemical studies. The antibacterial activity of 1 was also investigated.

UR - http://www.scopus.com/inward/record.url?scp=84992147637&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.6b01921

DO - 10.1021/acs.inorgchem.6b01921

M3 - Article

AN - SCOPUS:84992147637

SN - 0020-1669

VL - 55

SP - 10118

EP - 10121

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 20

ER -

Synthesis, Structure, and Antibacterial Activity of a Thallium(III)-Containing Polyoxometalate, [Tl₂{B-β-SiW₈O₃₀(OH)}₂]^12-

Abstract

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