TY - JOUR
T1 - Synthesis of uniform-sized spherical monodisperse K2Ba[Ni(NO2)6] via polymer-assisted anti-solvent crystallization method for the enhanced catalytic pyrolysis of HNIW
AU - Zhu, Fengdan
AU - Liu, Chang
AU - Yang, Desheng
AU - Bai, Chaofei
AU - Zeng, Xinlong
AU - Niu, Ziteng
AU - Li, Guoping
AU - Luo, Yunjun
N1 - Publisher Copyright:
© 2024 Elsevier B.V.
PY - 2025/1/5
Y1 - 2025/1/5
N2 - Nitro complexes (NCs) have been selected as combustion catalysts for propellants due to their synergistic behavior. However, NCs prepared by traditional methods suffer from poor dispersion and irregular shape, which limit their catalytic potential. Hence, a polymer-assisted anti-solvent crystallization (PAASC) strategy was developed to fabricate potassium barium hexanitronickelate (K2Ba[Ni(NO2)6], PBHNN) crystals. In this method, emulsion particles created by mixing the solvent with the poor solvent serve as spherical templates. The particle size and monodispersity of PBHNN are controlled by PVP content. With 0.042 mol/L PVP, PBHNN were monodisperse with a particle size of 1.05±0.03 μm, which showed the best catalytic behavior for increasing the exothermic amount of hexanitrohexaazaisowurtzitane (HNIW) by 100.6 %. The high catalytic performance is due to the large specific surface area and improved contact efficiency. The in-situ TG-FTIR-MS test revealed that the procedure of PBHNN enhanced the pyrolysis of HNIW. The N-NO2 bonds of HNIW are weakened by the strong attraction of metal oxides to electrons, which accelerates the formation of NO2. Consequently, increased NO2 promotes subsequent oxidation reactions and improves the pyrolysis efficiency of individual HNIW. Therefore, the PAASC method is crucial for the fabrication of spherical monodisperse NCs with uniform particle size and high catalytic activity.
AB - Nitro complexes (NCs) have been selected as combustion catalysts for propellants due to their synergistic behavior. However, NCs prepared by traditional methods suffer from poor dispersion and irregular shape, which limit their catalytic potential. Hence, a polymer-assisted anti-solvent crystallization (PAASC) strategy was developed to fabricate potassium barium hexanitronickelate (K2Ba[Ni(NO2)6], PBHNN) crystals. In this method, emulsion particles created by mixing the solvent with the poor solvent serve as spherical templates. The particle size and monodispersity of PBHNN are controlled by PVP content. With 0.042 mol/L PVP, PBHNN were monodisperse with a particle size of 1.05±0.03 μm, which showed the best catalytic behavior for increasing the exothermic amount of hexanitrohexaazaisowurtzitane (HNIW) by 100.6 %. The high catalytic performance is due to the large specific surface area and improved contact efficiency. The in-situ TG-FTIR-MS test revealed that the procedure of PBHNN enhanced the pyrolysis of HNIW. The N-NO2 bonds of HNIW are weakened by the strong attraction of metal oxides to electrons, which accelerates the formation of NO2. Consequently, increased NO2 promotes subsequent oxidation reactions and improves the pyrolysis efficiency of individual HNIW. Therefore, the PAASC method is crucial for the fabrication of spherical monodisperse NCs with uniform particle size and high catalytic activity.
KW - Hexanitro complexes
KW - HNIW
KW - Monodisperse spherical crystals
KW - Polymer-assisted anti-solvent crystallization
UR - http://www.scopus.com/inward/record.url?scp=85205363331&partnerID=8YFLogxK
U2 - 10.1016/j.colsurfa.2024.135458
DO - 10.1016/j.colsurfa.2024.135458
M3 - Article
AN - SCOPUS:85205363331
SN - 0927-7757
VL - 704
JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects
JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects
M1 - 135458
ER -