Synthesis of two new cage molecules containing trinitromethyl group

Cheng Hui Sun; Xin Qi Zhao; Yu Chuan Li; Si Ping Pang

doi:10.1016/j.cclet.2009.12.001

Synthesis of two new cage molecules containing trinitromethyl group

Cheng Hui Sun^*
, Xin Qi Zhao
, Yu Chuan Li
, Si Ping Pang

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, ¹H NMR, MS and single crystal X-ray. DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound.

Original language	English
Pages (from-to)	572-575
Number of pages	4
Journal	Chinese Chemical Letters
Volume	21
Issue number	5
DOIs	https://doi.org/10.1016/j.cclet.2009.12.001
Publication status	Published - May 2010

Keywords

Cage compound
Synthesis
Trinitromethyl group
X-ray crystal structure

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10.1016/j.cclet.2009.12.001

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title = "Synthesis of two new cage molecules containing trinitromethyl group",

abstract = "Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, 1H NMR, MS and single crystal X-ray. DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound.",

keywords = "Cage compound, Synthesis, Trinitromethyl group, X-ray crystal structure",

author = "Sun, \{Cheng Hui\} and Zhao, \{Xin Qi\} and Li, \{Yu Chuan\} and Pang, \{Si Ping\}",

year = "2010",

month = may,

doi = "10.1016/j.cclet.2009.12.001",

language = "English",

volume = "21",

pages = "572--575",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "5",

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TY - JOUR

T1 - Synthesis of two new cage molecules containing trinitromethyl group

AU - Sun, Cheng Hui

AU - Zhao, Xin Qi

AU - Li, Yu Chuan

AU - Pang, Si Ping

PY - 2010/5

Y1 - 2010/5

N2 - Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, 1H NMR, MS and single crystal X-ray. DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound.

AB - Two new cage compounds, 4-trinitroethyl-10-nitro-2,6,8,12-tetraacetylhexaazaisowurtzitane (3) and 4-trinitroethyl-2,6,8,10,12-pentanitrohexaazaisowurtzitane (4), containing trinitromethyl group were synthesized by a novel method, and their structures were confirmed by IR, 1H NMR, MS and single crystal X-ray. DSC result shows that compound 4 has surprising thermal stability and could be a potential energetic compound.

KW - Cage compound

KW - Synthesis

KW - Trinitromethyl group

KW - X-ray crystal structure

UR - https://www.scopus.com/pages/publications/77949915819

U2 - 10.1016/j.cclet.2009.12.001

DO - 10.1016/j.cclet.2009.12.001

M3 - Article

AN - SCOPUS:77949915819

SN - 1001-8417

VL - 21

SP - 572

EP - 575

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 5

ER -

Synthesis of two new cage molecules containing trinitromethyl group

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Keywords

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