Synthesis of new tetrazene(N-N{double bond, long}N-N)-linked bi(1,2,4-triazole)

Sheng Hua Li; Si Ping Pang; Xiao Tong Li; Yong Zhong Yu; Xin Qi Zhao

doi:10.1016/j.cclet.2007.08.018

Synthesis of new tetrazene(N-N{double bond, long}N-N)-linked bi(1,2,4-triazole)

Sheng Hua Li
, Si Ping Pang^*
, Xiao Tong Li
, Yong Zhong Yu
, Xin Qi Zhao

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

The reaction of 4-amino-1,2,4-triazole with sodium dichloroisocyanurate (SDCI) afforded new tetrazene(N-N{double bond, long}N-N)-linked bi(1,2,4-triazole) 2a in excellent yield. Increasing the molar ratio of SDCI to 4-amino-1,2,4-triazole, the chlorinated product 1,5,5′-trichloro-4,4′-azo-1,2,4-triazole (2b) was formed. These new compounds have been characterized by MS, ¹H NMR, ¹³C NMR, and elemental analysis.

Original language	English
Pages (from-to)	1176-1178
Number of pages	3
Journal	Chinese Chemical Letters
Volume	18
Issue number	10
DOIs	https://doi.org/10.1016/j.cclet.2007.08.018
Publication status	Published - Oct 2007

Keywords

Synthesis
Tetrazene
Triazole

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10.1016/j.cclet.2007.08.018

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title = "Synthesis of new tetrazene(N-N\{double bond, long\}N-N)-linked bi(1,2,4-triazole)",

abstract = "The reaction of 4-amino-1,2,4-triazole with sodium dichloroisocyanurate (SDCI) afforded new tetrazene(N-N\{double bond, long\}N-N)-linked bi(1,2,4-triazole) 2a in excellent yield. Increasing the molar ratio of SDCI to 4-amino-1,2,4-triazole, the chlorinated product 1,5,5′-trichloro-4,4′-azo-1,2,4-triazole (2b) was formed. These new compounds have been characterized by MS, 1H NMR, 13C NMR, and elemental analysis.",

keywords = "Synthesis, Tetrazene, Triazole",

author = "Li, \{Sheng Hua\} and Pang, \{Si Ping\} and Li, \{Xiao Tong\} and Yu, \{Yong Zhong\} and Zhao, \{Xin Qi\}",

year = "2007",

month = oct,

doi = "10.1016/j.cclet.2007.08.018",

language = "English",

volume = "18",

pages = "1176--1178",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "10",

}

TY - JOUR

T1 - Synthesis of new tetrazene(N-N{double bond, long}N-N)-linked bi(1,2,4-triazole)

AU - Li, Sheng Hua

AU - Pang, Si Ping

AU - Li, Xiao Tong

AU - Yu, Yong Zhong

AU - Zhao, Xin Qi

PY - 2007/10

Y1 - 2007/10

N2 - The reaction of 4-amino-1,2,4-triazole with sodium dichloroisocyanurate (SDCI) afforded new tetrazene(N-N{double bond, long}N-N)-linked bi(1,2,4-triazole) 2a in excellent yield. Increasing the molar ratio of SDCI to 4-amino-1,2,4-triazole, the chlorinated product 1,5,5′-trichloro-4,4′-azo-1,2,4-triazole (2b) was formed. These new compounds have been characterized by MS, 1H NMR, 13C NMR, and elemental analysis.

AB - The reaction of 4-amino-1,2,4-triazole with sodium dichloroisocyanurate (SDCI) afforded new tetrazene(N-N{double bond, long}N-N)-linked bi(1,2,4-triazole) 2a in excellent yield. Increasing the molar ratio of SDCI to 4-amino-1,2,4-triazole, the chlorinated product 1,5,5′-trichloro-4,4′-azo-1,2,4-triazole (2b) was formed. These new compounds have been characterized by MS, 1H NMR, 13C NMR, and elemental analysis.

KW - Synthesis

KW - Tetrazene

KW - Triazole

UR - https://www.scopus.com/pages/publications/34848827930

U2 - 10.1016/j.cclet.2007.08.018

DO - 10.1016/j.cclet.2007.08.018

M3 - Article

AN - SCOPUS:34848827930

SN - 1001-8417

VL - 18

SP - 1176

EP - 1178

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 10

ER -

Synthesis of new tetrazene(N-N{double bond, long}N-N)-linked bi(1,2,4-triazole)

Abstract

Keywords

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