Synthesis of Highly Strained Cyclobutane Fuels via Room-Temperature-Integrated Oxidation/[2 + 2] Cycloaddition of Lignocellulose-Based Cyclic Ketones and Cyclic Alcohols

Jun Zhang; E. Xiu-Tian-Feng; Bo Yang; Xiumei Ma; Xueping Wang; Ninghui Chang; Qiuyu Zhang; Ji Jun Zou; Junjian Xie

doi:10.1021/acssuschemeng.4c04927

Synthesis of Highly Strained Cyclobutane Fuels via Room-Temperature-Integrated Oxidation/[2 + 2] Cycloaddition of Lignocellulose-Based Cyclic Ketones and Cyclic Alcohols

Jun Zhang, E. Xiu-Tian-Feng, Bo Yang, Xiumei Ma, Xueping Wang, Ninghui Chang, Qiuyu Zhang^*, Ji Jun Zou, Junjian Xie^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

High-energy-density cyclobutane fuels were directly synthesized via room-temperature-integrated one-pot two-step oxidation/self-photosensitized [2 + 2] cycloaddition using lignocellulose-derived cyclic ketones and cyclic alcohols for the first time, which endow much higher density, lower freezing point, and higher neat heat of combustion than other biofuels achieved from the same feedstocks and hence denote a new kind of sustainable high-density fuels appealing for practical applications.

Original language	English
Pages (from-to)	17647-17655
Number of pages	9
Journal	ACS Sustainable Chemistry and Engineering
Volume	12
Issue number	49
DOIs	https://doi.org/10.1021/acssuschemeng.4c04927
Publication status	Published - 9 Dec 2024
Externally published	Yes

Keywords

[2 + 2] cycloaddition
cyclic alcohols
cyclic ketones
high-density fuel
renewable cyclobutane fuel

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/acssuschemeng.4c04927

Cite this

Zhang, J., Xiu-Tian-Feng, E., Yang, B., Ma, X., Wang, X., Chang, N., Zhang, Q., Zou, J. J., & Xie, J. (2024). Synthesis of Highly Strained Cyclobutane Fuels via Room-Temperature-Integrated Oxidation/[2 + 2] Cycloaddition of Lignocellulose-Based Cyclic Ketones and Cyclic Alcohols. ACS Sustainable Chemistry and Engineering, 12(49), 17647-17655. https://doi.org/10.1021/acssuschemeng.4c04927

@article{f4356d16f0fa49e18c8e8be3356cb368,

title = "Synthesis of Highly Strained Cyclobutane Fuels via Room-Temperature-Integrated Oxidation/[2 + 2] Cycloaddition of Lignocellulose-Based Cyclic Ketones and Cyclic Alcohols",

abstract = "High-energy-density cyclobutane fuels were directly synthesized via room-temperature-integrated one-pot two-step oxidation/self-photosensitized [2 + 2] cycloaddition using lignocellulose-derived cyclic ketones and cyclic alcohols for the first time, which endow much higher density, lower freezing point, and higher neat heat of combustion than other biofuels achieved from the same feedstocks and hence denote a new kind of sustainable high-density fuels appealing for practical applications.",

keywords = "[2 + 2] cycloaddition, cyclic alcohols, cyclic ketones, high-density fuel, renewable cyclobutane fuel",

author = "Jun Zhang and E. Xiu-Tian-Feng and Bo Yang and Xiumei Ma and Xueping Wang and Ninghui Chang and Qiuyu Zhang and Zou, {Ji Jun} and Junjian Xie",

note = "Publisher Copyright: {\textcopyright} 2024 American Chemical Society.",

year = "2024",

month = dec,

day = "9",

doi = "10.1021/acssuschemeng.4c04927",

language = "English",

volume = "12",

pages = "17647--17655",

journal = "ACS Sustainable Chemistry and Engineering",

issn = "2168-0485",

publisher = "American Chemical Society",

number = "49",

}

Zhang, J, Xiu-Tian-Feng, E, Yang, B, Ma, X, Wang, X, Chang, N, Zhang, Q, Zou, JJ & Xie, J 2024, 'Synthesis of Highly Strained Cyclobutane Fuels via Room-Temperature-Integrated Oxidation/[2 + 2] Cycloaddition of Lignocellulose-Based Cyclic Ketones and Cyclic Alcohols', ACS Sustainable Chemistry and Engineering, vol. 12, no. 49, pp. 17647-17655. https://doi.org/10.1021/acssuschemeng.4c04927

Synthesis of Highly Strained Cyclobutane Fuels via Room-Temperature-Integrated Oxidation/[2 + 2] Cycloaddition of Lignocellulose-Based Cyclic Ketones and Cyclic Alcohols. / Zhang, Jun; Xiu-Tian-Feng, E.; Yang, Bo et al.
In: ACS Sustainable Chemistry and Engineering, Vol. 12, No. 49, 09.12.2024, p. 17647-17655.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of Highly Strained Cyclobutane Fuels via Room-Temperature-Integrated Oxidation/[2 + 2] Cycloaddition of Lignocellulose-Based Cyclic Ketones and Cyclic Alcohols

AU - Zhang, Jun

AU - Xiu-Tian-Feng, E.

AU - Yang, Bo

AU - Ma, Xiumei

AU - Wang, Xueping

AU - Chang, Ninghui

AU - Zhang, Qiuyu

AU - Zou, Ji Jun

AU - Xie, Junjian

PY - 2024/12/9

Y1 - 2024/12/9

N2 - High-energy-density cyclobutane fuels were directly synthesized via room-temperature-integrated one-pot two-step oxidation/self-photosensitized [2 + 2] cycloaddition using lignocellulose-derived cyclic ketones and cyclic alcohols for the first time, which endow much higher density, lower freezing point, and higher neat heat of combustion than other biofuels achieved from the same feedstocks and hence denote a new kind of sustainable high-density fuels appealing for practical applications.

AB - High-energy-density cyclobutane fuels were directly synthesized via room-temperature-integrated one-pot two-step oxidation/self-photosensitized [2 + 2] cycloaddition using lignocellulose-derived cyclic ketones and cyclic alcohols for the first time, which endow much higher density, lower freezing point, and higher neat heat of combustion than other biofuels achieved from the same feedstocks and hence denote a new kind of sustainable high-density fuels appealing for practical applications.

KW - [2 + 2] cycloaddition

KW - cyclic alcohols

KW - cyclic ketones

KW - high-density fuel

KW - renewable cyclobutane fuel

UR - http://www.scopus.com/inward/record.url?scp=85210312747&partnerID=8YFLogxK

U2 - 10.1021/acssuschemeng.4c04927

DO - 10.1021/acssuschemeng.4c04927

M3 - Article

AN - SCOPUS:85210312747

SN - 2168-0485

VL - 12

SP - 17647

EP - 17655

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

IS - 49

ER -

Synthesis of Highly Strained Cyclobutane Fuels via Room-Temperature-Integrated Oxidation/[2 + 2] Cycloaddition of Lignocellulose-Based Cyclic Ketones and Cyclic Alcohols

Abstract

Keywords

UN SDGs

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