Synthesis of hexagonal boron carbonitride phase by solvothermal method

Fu Lin Huang; Chuan Bao Cao; Xu Xiang; Rui Tao Lv; He Sun Zhu

doi:10.1016/j.diamond.2004.03.001

Synthesis of hexagonal boron carbonitride phase by solvothermal method

Fu Lin Huang
, Chuan Bao Cao^*
, Xu Xiang
, Rui Tao Lv
, He Sun Zhu

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

A solvothermal reaction of CH₃CN·BCl₃ and lithium nitride (Li₃N) using benzene as the solvent has been successfully applied to prepare boron carbonitride at 300°C and less than about 7 MPa. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) are used to confirm their chemical composition and atomic-level hybrid. X-ray diffraction (XRD) and transmission electron diffraction (TED) analysis indicate that the powders have hexagonal network structures.

Original language	English
Pages (from-to)	1757-1760
Number of pages	4
Journal	Diamond and Related Materials
Volume	13
Issue number	10
DOIs	https://doi.org/10.1016/j.diamond.2004.03.001
Publication status	Published - Oct 2004

Keywords

BCN
High pressure crystal growth
Metastable phases
Solvothermal synthesis

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10.1016/j.diamond.2004.03.001

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title = "Synthesis of hexagonal boron carbonitride phase by solvothermal method",

abstract = "A solvothermal reaction of CH3CN·BCl3 and lithium nitride (Li3N) using benzene as the solvent has been successfully applied to prepare boron carbonitride at 300°C and less than about 7 MPa. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) are used to confirm their chemical composition and atomic-level hybrid. X-ray diffraction (XRD) and transmission electron diffraction (TED) analysis indicate that the powders have hexagonal network structures.",

keywords = "BCN, High pressure crystal growth, Metastable phases, Solvothermal synthesis",

author = "Huang, \{Fu Lin\} and Cao, \{Chuan Bao\} and Xu Xiang and Lv, \{Rui Tao\} and Zhu, \{He Sun\}",

year = "2004",

month = oct,

doi = "10.1016/j.diamond.2004.03.001",

language = "English",

volume = "13",

pages = "1757--1760",

journal = "Diamond and Related Materials",

issn = "0925-9635",

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TY - JOUR

T1 - Synthesis of hexagonal boron carbonitride phase by solvothermal method

AU - Huang, Fu Lin

AU - Cao, Chuan Bao

AU - Xiang, Xu

AU - Lv, Rui Tao

AU - Zhu, He Sun

PY - 2004/10

Y1 - 2004/10

N2 - A solvothermal reaction of CH3CN·BCl3 and lithium nitride (Li3N) using benzene as the solvent has been successfully applied to prepare boron carbonitride at 300°C and less than about 7 MPa. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) are used to confirm their chemical composition and atomic-level hybrid. X-ray diffraction (XRD) and transmission electron diffraction (TED) analysis indicate that the powders have hexagonal network structures.

AB - A solvothermal reaction of CH3CN·BCl3 and lithium nitride (Li3N) using benzene as the solvent has been successfully applied to prepare boron carbonitride at 300°C and less than about 7 MPa. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) are used to confirm their chemical composition and atomic-level hybrid. X-ray diffraction (XRD) and transmission electron diffraction (TED) analysis indicate that the powders have hexagonal network structures.

KW - BCN

KW - High pressure crystal growth

KW - Metastable phases

KW - Solvothermal synthesis

UR - https://www.scopus.com/pages/publications/9644290870

U2 - 10.1016/j.diamond.2004.03.001

DO - 10.1016/j.diamond.2004.03.001

M3 - Article

AN - SCOPUS:9644290870

SN - 0925-9635

VL - 13

SP - 1757

EP - 1760

JO - Diamond and Related Materials

JF - Diamond and Related Materials

IS - 10

ER -

Synthesis of hexagonal boron carbonitride phase by solvothermal method

Abstract

Keywords

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