Synthesis of an octathienyl-fused phthalocyanine as a donor material for organic solar cells

Xiaoyang Yan; Haijun Fan; Hongfei Gu; Junliang Zhang; Xuebin Huang; Rubo Zhang; Xiaowei Zhan

doi:10.1016/j.dyepig.2014.11.006

Synthesis of an octathienyl-fused phthalocyanine as a donor material for organic solar cells

Xiaoyang Yan
, Haijun Fan
, Hongfei Gu
, Junliang Zhang
, Xuebin Huang^*
, Rubo Zhang
, Xiaowei Zhan

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
CAS - Institute of Chemistry
Peking University

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

We report the synthesis and properties of a phthalocyanine derivative with eight fused thienyl rings and eight triisopropylsilylethynyl substituents. The fused thienyl rings were designed to enhance intermolecular interactions among the phthalocyanine molecules in the solid state whereas the triisopropylsilylethynyl substituents were aimed to improve solubility. Compared to the simple octa(2-thienyl) substituted phthalocyanine, a remarkable decrease of solubility and a 67 nm red shift in UV-visible absorption maximum were observed. The fused thienyl compound was used as a donor material in bulk heterojunction solar cells. The power conversion efficiency of 0.60% was achieved under simulated solar illumination.

Original language	English
Pages (from-to)	124-128
Number of pages	5
Journal	Dyes and Pigments
Volume	114
Issue number	C
DOIs	https://doi.org/10.1016/j.dyepig.2014.11.006
Publication status	Published - Mar 2015

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Bulk heterojunction solar cells
Donor materials
Fused thienyl rings
Photovoltaic
Phthalocyanine
Synthesis

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10.1016/j.dyepig.2014.11.006

Cite this

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title = "Synthesis of an octathienyl-fused phthalocyanine as a donor material for organic solar cells",

abstract = "We report the synthesis and properties of a phthalocyanine derivative with eight fused thienyl rings and eight triisopropylsilylethynyl substituents. The fused thienyl rings were designed to enhance intermolecular interactions among the phthalocyanine molecules in the solid state whereas the triisopropylsilylethynyl substituents were aimed to improve solubility. Compared to the simple octa(2-thienyl) substituted phthalocyanine, a remarkable decrease of solubility and a 67 nm red shift in UV-visible absorption maximum were observed. The fused thienyl compound was used as a donor material in bulk heterojunction solar cells. The power conversion efficiency of 0.60\% was achieved under simulated solar illumination.",

keywords = "Bulk heterojunction solar cells, Donor materials, Fused thienyl rings, Photovoltaic, Phthalocyanine, Synthesis",

author = "Xiaoyang Yan and Haijun Fan and Hongfei Gu and Junliang Zhang and Xuebin Huang and Rubo Zhang and Xiaowei Zhan",

year = "2015",

month = mar,

doi = "10.1016/j.dyepig.2014.11.006",

language = "English",

volume = "114",

pages = "124--128",

journal = "Dyes and Pigments",

issn = "0143-7208",

publisher = "Elsevier B.V.",

number = "C",

}

TY - JOUR

T1 - Synthesis of an octathienyl-fused phthalocyanine as a donor material for organic solar cells

AU - Yan, Xiaoyang

AU - Fan, Haijun

AU - Gu, Hongfei

AU - Zhang, Junliang

AU - Huang, Xuebin

AU - Zhang, Rubo

AU - Zhan, Xiaowei

PY - 2015/3

Y1 - 2015/3

N2 - We report the synthesis and properties of a phthalocyanine derivative with eight fused thienyl rings and eight triisopropylsilylethynyl substituents. The fused thienyl rings were designed to enhance intermolecular interactions among the phthalocyanine molecules in the solid state whereas the triisopropylsilylethynyl substituents were aimed to improve solubility. Compared to the simple octa(2-thienyl) substituted phthalocyanine, a remarkable decrease of solubility and a 67 nm red shift in UV-visible absorption maximum were observed. The fused thienyl compound was used as a donor material in bulk heterojunction solar cells. The power conversion efficiency of 0.60% was achieved under simulated solar illumination.

AB - We report the synthesis and properties of a phthalocyanine derivative with eight fused thienyl rings and eight triisopropylsilylethynyl substituents. The fused thienyl rings were designed to enhance intermolecular interactions among the phthalocyanine molecules in the solid state whereas the triisopropylsilylethynyl substituents were aimed to improve solubility. Compared to the simple octa(2-thienyl) substituted phthalocyanine, a remarkable decrease of solubility and a 67 nm red shift in UV-visible absorption maximum were observed. The fused thienyl compound was used as a donor material in bulk heterojunction solar cells. The power conversion efficiency of 0.60% was achieved under simulated solar illumination.

KW - Bulk heterojunction solar cells

KW - Donor materials

KW - Fused thienyl rings

KW - Photovoltaic

KW - Phthalocyanine

KW - Synthesis

UR - https://www.scopus.com/pages/publications/84925392827

U2 - 10.1016/j.dyepig.2014.11.006

DO - 10.1016/j.dyepig.2014.11.006

M3 - Article

AN - SCOPUS:84925392827

SN - 0143-7208

VL - 114

SP - 124

EP - 128

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - C

ER -

Synthesis of an octathienyl-fused phthalocyanine as a donor material for organic solar cells

Abstract

UN SDGs

Keywords

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