Synthesis of a pentalene centered polycyclic fused system

Yuliang Li; Xiaodong Yin; Yongjun Li; Yulan Zhu; Yuhe Kan; Daoben Zhu

doi:10.1021/ol200213h

Synthesis of a pentalene centered polycyclic fused system

Yuliang Li^*
, Xiaodong Yin
, Yongjun Li^*
, Yulan Zhu
, Yuhe Kan
, Daoben Zhu

^*Corresponding author for this work

CAS - Institute of Chemistry
University of Chinese Academy of Sciences
Huaiyin Normal University

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

A novel pentalene-centered polycyclic 24π-electron system, IB1, was synthesized via a Pd-catalyzed homocoupling reaction. The geometry structure was studied by X-ray diffraction and theoretical method. The HOMO level of IB1 was studied by electrochemical experiment and DFT methods. The IB1 molecule shows a strong electro-donating property and can form a charge transfer complex with electro-acceptor TCNQ, indicating fascinating potential in the field of organic electronics.

Original language	English
Pages (from-to)	1520-1523
Number of pages	4
Journal	Organic Letters
Volume	13
Issue number	6
DOIs	https://doi.org/10.1021/ol200213h
Publication status	Published - 18 Mar 2011
Externally published	Yes

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10.1021/ol200213h

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title = "Synthesis of a pentalene centered polycyclic fused system",

abstract = "A novel pentalene-centered polycyclic 24π-electron system, IB1, was synthesized via a Pd-catalyzed homocoupling reaction. The geometry structure was studied by X-ray diffraction and theoretical method. The HOMO level of IB1 was studied by electrochemical experiment and DFT methods. The IB1 molecule shows a strong electro-donating property and can form a charge transfer complex with electro-acceptor TCNQ, indicating fascinating potential in the field of organic electronics.",

author = "Yuliang Li and Xiaodong Yin and Yongjun Li and Yulan Zhu and Yuhe Kan and Daoben Zhu",

year = "2011",

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T1 - Synthesis of a pentalene centered polycyclic fused system

AU - Li, Yuliang

AU - Yin, Xiaodong

AU - Li, Yongjun

AU - Zhu, Yulan

AU - Kan, Yuhe

AU - Zhu, Daoben

PY - 2011/3/18

Y1 - 2011/3/18

N2 - A novel pentalene-centered polycyclic 24π-electron system, IB1, was synthesized via a Pd-catalyzed homocoupling reaction. The geometry structure was studied by X-ray diffraction and theoretical method. The HOMO level of IB1 was studied by electrochemical experiment and DFT methods. The IB1 molecule shows a strong electro-donating property and can form a charge transfer complex with electro-acceptor TCNQ, indicating fascinating potential in the field of organic electronics.

AB - A novel pentalene-centered polycyclic 24π-electron system, IB1, was synthesized via a Pd-catalyzed homocoupling reaction. The geometry structure was studied by X-ray diffraction and theoretical method. The HOMO level of IB1 was studied by electrochemical experiment and DFT methods. The IB1 molecule shows a strong electro-donating property and can form a charge transfer complex with electro-acceptor TCNQ, indicating fascinating potential in the field of organic electronics.

UR - https://www.scopus.com/pages/publications/79952600210

U2 - 10.1021/ol200213h

DO - 10.1021/ol200213h

M3 - Article

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SN - 1523-7060

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SP - 1520

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JO - Organic Letters

JF - Organic Letters

IS - 6

ER -

Synthesis of a pentalene centered polycyclic fused system

Abstract

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