Synthesis of a benzenethiol-derivatized porphyrin for self-assembly

Jicheng Wan; Huiqian Sun; Xuebin Huang

doi:10.1002/cjoc.201200345

Synthesis of a benzenethiol-derivatized porphyrin for self-assembly

Jicheng Wan^*
, Huiqian Sun
, Xuebin Huang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The synthesis of a benzenethiol-derivatized porphyrin for flat-lying self-assembly on gold substrates is described. Acetyl protected thiol is not stable enough in Pd-catalyzed reactions. While acrylate derivatives protected thiol group shows good tolerance in Pd-catalyzed borylations and Suzuki-Miyaura coupling reactions and no catalyst poisoning was observed.

Original language	English
Pages (from-to)	1841-1844
Number of pages	4
Journal	Chinese Journal of Chemistry
Volume	30
Issue number	8
DOIs	https://doi.org/10.1002/cjoc.201200345
Publication status	Published - Aug 2012

Keywords

porphyrin
self-assembly
thiol

Access to Document

10.1002/cjoc.201200345

Cite this

@article{b6312c00ad9340858e9f472afab50493,

title = "Synthesis of a benzenethiol-derivatized porphyrin for self-assembly",

abstract = "The synthesis of a benzenethiol-derivatized porphyrin for flat-lying self-assembly on gold substrates is described. Acetyl protected thiol is not stable enough in Pd-catalyzed reactions. While acrylate derivatives protected thiol group shows good tolerance in Pd-catalyzed borylations and Suzuki-Miyaura coupling reactions and no catalyst poisoning was observed.",

keywords = "porphyrin, self-assembly, thiol",

author = "Jicheng Wan and Huiqian Sun and Xuebin Huang",

year = "2012",

month = aug,

doi = "10.1002/cjoc.201200345",

language = "English",

volume = "30",

pages = "1841--1844",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

publisher = "John Wiley and Sons Inc.",

number = "8",

}

TY - JOUR

T1 - Synthesis of a benzenethiol-derivatized porphyrin for self-assembly

AU - Wan, Jicheng

AU - Sun, Huiqian

AU - Huang, Xuebin

PY - 2012/8

Y1 - 2012/8

N2 - The synthesis of a benzenethiol-derivatized porphyrin for flat-lying self-assembly on gold substrates is described. Acetyl protected thiol is not stable enough in Pd-catalyzed reactions. While acrylate derivatives protected thiol group shows good tolerance in Pd-catalyzed borylations and Suzuki-Miyaura coupling reactions and no catalyst poisoning was observed.

AB - The synthesis of a benzenethiol-derivatized porphyrin for flat-lying self-assembly on gold substrates is described. Acetyl protected thiol is not stable enough in Pd-catalyzed reactions. While acrylate derivatives protected thiol group shows good tolerance in Pd-catalyzed borylations and Suzuki-Miyaura coupling reactions and no catalyst poisoning was observed.

KW - porphyrin

KW - self-assembly

KW - thiol

UR - https://www.scopus.com/pages/publications/84865373986

U2 - 10.1002/cjoc.201200345

DO - 10.1002/cjoc.201200345

M3 - Article

AN - SCOPUS:84865373986

SN - 1001-604X

VL - 30

SP - 1841

EP - 1844

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 8

ER -

Synthesis of a benzenethiol-derivatized porphyrin for self-assembly

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this