TY - JOUR
T1 - Synthesis of 3d-3d heterometallic 4-amino-1,2,4-triazole complex with the structure depending on the reaction time
AU - Zhang, H. Y.
AU - Li, H.
AU - Liu, G.
AU - Liu, T. T.
AU - Yue, F.
AU - Wang, J. D.
PY - 2011/11
Y1 - 2011/11
N2 - One-pot reaction containing Zn(NO 3) 2, Cd(NO 3) 2, NH 4SCN, and 4-amino-1,2,4-triazole (Atrz) proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz) 2(SCN) 2] nHowever, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd 2.84Zn 2.16(Atrz) 6(SCN) 10] • 4H 2O (I) with 6 6 topology was obtained. The fluorescent property of I in the solid state was discussed.
AB - One-pot reaction containing Zn(NO 3) 2, Cd(NO 3) 2, NH 4SCN, and 4-amino-1,2,4-triazole (Atrz) proceeded by refluxing for different periods and gave different products. When the mixture was refluxed for 1 h, the product was a 1D chain polymer [Cd(Atrz) 2(SCN) 2] nHowever, when the refluxing time was increased to 3 h, a novel 3D 3d-3d heterometallic framework complex [Cd 2.84Zn 2.16(Atrz) 6(SCN) 10] • 4H 2O (I) with 6 6 topology was obtained. The fluorescent property of I in the solid state was discussed.
UR - http://www.scopus.com/inward/record.url?scp=83455259386&partnerID=8YFLogxK
U2 - 10.1134/S1070328411110133
DO - 10.1134/S1070328411110133
M3 - Article
AN - SCOPUS:83455259386
SN - 1070-3284
VL - 37
SP - 839
EP - 844
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
IS - 11
ER -