Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand

Bei Bei Tang; Heng Ma; Guan Zheng Li; Yue Bing Wang; Gulinazi Anwar; Rufei Shi; Hui Li

doi:10.1039/c3ce41034j

Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand

Bei Bei Tang
, Heng Ma
, Guan Zheng Li
, Yue Bing Wang
, Gulinazi Anwar
, Rufei Shi
, Hui Li^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology
Loras College

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Two kinds of tetranuclear Zn(ii) molecular clusters with the designed aroylhydrazone Schiff base ligand (H₃L), [Zn₄(HL) ₄]·3(DMF)·3(H₂O) (1) and [Zn ₄(HL)₂(CH₃COO)₄]·2(DMF) ·2(CH₃OH) (2), have been synthesized and studied. Molecular cluster 1 displayed a Zn₄O₄ boat-shaped core and 2 presented a discrete linear tetranuclear Zn(ii) structure. The luminescent properties of the two molecular clusters have been investigated, which exhibit a wide range of photo-luminescence in different organic solvents.

Original language	English
Pages (from-to)	8069-8073
Number of pages	5
Journal	CrystEngComm
Volume	15
Issue number	40
DOIs	https://doi.org/10.1039/c3ce41034j
Publication status	Published - 28 Oct 2013

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title = "Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand",

abstract = "Two kinds of tetranuclear Zn(ii) molecular clusters with the designed aroylhydrazone Schiff base ligand (H3L), [Zn4(HL) 4]·3(DMF)·3(H2O) (1) and [Zn 4(HL)2(CH3COO)4]·2(DMF) ·2(CH3OH) (2), have been synthesized and studied. Molecular cluster 1 displayed a Zn4O4 boat-shaped core and 2 presented a discrete linear tetranuclear Zn(ii) structure. The luminescent properties of the two molecular clusters have been investigated, which exhibit a wide range of photo-luminescence in different organic solvents.",

author = "Tang, \{Bei Bei\} and Heng Ma and Li, \{Guan Zheng\} and Wang, \{Yue Bing\} and Gulinazi Anwar and Rufei Shi and Hui Li",

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T1 - Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand

AU - Tang, Bei Bei

AU - Ma, Heng

AU - Li, Guan Zheng

AU - Wang, Yue Bing

AU - Anwar, Gulinazi

AU - Shi, Rufei

AU - Li, Hui

PY - 2013/10/28

Y1 - 2013/10/28

N2 - Two kinds of tetranuclear Zn(ii) molecular clusters with the designed aroylhydrazone Schiff base ligand (H3L), [Zn4(HL) 4]·3(DMF)·3(H2O) (1) and [Zn 4(HL)2(CH3COO)4]·2(DMF) ·2(CH3OH) (2), have been synthesized and studied. Molecular cluster 1 displayed a Zn4O4 boat-shaped core and 2 presented a discrete linear tetranuclear Zn(ii) structure. The luminescent properties of the two molecular clusters have been investigated, which exhibit a wide range of photo-luminescence in different organic solvents.

AB - Two kinds of tetranuclear Zn(ii) molecular clusters with the designed aroylhydrazone Schiff base ligand (H3L), [Zn4(HL) 4]·3(DMF)·3(H2O) (1) and [Zn 4(HL)2(CH3COO)4]·2(DMF) ·2(CH3OH) (2), have been synthesized and studied. Molecular cluster 1 displayed a Zn4O4 boat-shaped core and 2 presented a discrete linear tetranuclear Zn(ii) structure. The luminescent properties of the two molecular clusters have been investigated, which exhibit a wide range of photo-luminescence in different organic solvents.

UR - https://www.scopus.com/pages/publications/84884556247

U2 - 10.1039/c3ce41034j

DO - 10.1039/c3ce41034j

M3 - Article

AN - SCOPUS:84884556247

SN - 1466-8033

VL - 15

SP - 8069

EP - 8073

JO - CrystEngComm

JF - CrystEngComm

IS - 40

ER -

Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand

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