Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand

Bei Bei Tang; Heng Ma; Guan Zheng Li; Yue Bing Wang; Gulinazi Anwar; Rufei Shi; Hui Li

doi:10.1039/c3ce41034j

Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand

Bei Bei Tang, Heng Ma, Guan Zheng Li, Yue Bing Wang, Gulinazi Anwar, Rufei Shi, Hui Li^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Two kinds of tetranuclear Zn(ii) molecular clusters with the designed aroylhydrazone Schiff base ligand (H₃L), [Zn₄(HL) ₄]·3(DMF)·3(H₂O) (1) and [Zn ₄(HL)₂(CH₃COO)₄]·2(DMF) ·2(CH₃OH) (2), have been synthesized and studied. Molecular cluster 1 displayed a Zn₄O₄ boat-shaped core and 2 presented a discrete linear tetranuclear Zn(ii) structure. The luminescent properties of the two molecular clusters have been investigated, which exhibit a wide range of photo-luminescence in different organic solvents.

Original language	English
Pages (from-to)	8069-8073
Number of pages	5
Journal	CrystEngComm
Volume	15
Issue number	40
DOIs	https://doi.org/10.1039/c3ce41034j
Publication status	Published - 28 Oct 2013

Access to Document

10.1039/c3ce41034j

Cite this

@article{473b134a17ba43c392abfc3f40eebb72,

title = "Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand",

abstract = "Two kinds of tetranuclear Zn(ii) molecular clusters with the designed aroylhydrazone Schiff base ligand (H3L), [Zn4(HL) 4]·3(DMF)·3(H2O) (1) and [Zn 4(HL)2(CH3COO)4]·2(DMF) ·2(CH3OH) (2), have been synthesized and studied. Molecular cluster 1 displayed a Zn4O4 boat-shaped core and 2 presented a discrete linear tetranuclear Zn(ii) structure. The luminescent properties of the two molecular clusters have been investigated, which exhibit a wide range of photo-luminescence in different organic solvents.",

author = "Tang, {Bei Bei} and Heng Ma and Li, {Guan Zheng} and Wang, {Yue Bing} and Gulinazi Anwar and Rufei Shi and Hui Li",

year = "2013",

month = oct,

day = "28",

doi = "10.1039/c3ce41034j",

language = "English",

volume = "15",

pages = "8069--8073",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "40",

}

TY - JOUR

T1 - Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand

AU - Tang, Bei Bei

AU - Ma, Heng

AU - Li, Guan Zheng

AU - Wang, Yue Bing

AU - Anwar, Gulinazi

AU - Shi, Rufei

AU - Li, Hui

PY - 2013/10/28

Y1 - 2013/10/28

N2 - Two kinds of tetranuclear Zn(ii) molecular clusters with the designed aroylhydrazone Schiff base ligand (H3L), [Zn4(HL) 4]·3(DMF)·3(H2O) (1) and [Zn 4(HL)2(CH3COO)4]·2(DMF) ·2(CH3OH) (2), have been synthesized and studied. Molecular cluster 1 displayed a Zn4O4 boat-shaped core and 2 presented a discrete linear tetranuclear Zn(ii) structure. The luminescent properties of the two molecular clusters have been investigated, which exhibit a wide range of photo-luminescence in different organic solvents.

AB - Two kinds of tetranuclear Zn(ii) molecular clusters with the designed aroylhydrazone Schiff base ligand (H3L), [Zn4(HL) 4]·3(DMF)·3(H2O) (1) and [Zn 4(HL)2(CH3COO)4]·2(DMF) ·2(CH3OH) (2), have been synthesized and studied. Molecular cluster 1 displayed a Zn4O4 boat-shaped core and 2 presented a discrete linear tetranuclear Zn(ii) structure. The luminescent properties of the two molecular clusters have been investigated, which exhibit a wide range of photo-luminescence in different organic solvents.

UR - http://www.scopus.com/inward/record.url?scp=84884556247&partnerID=8YFLogxK

U2 - 10.1039/c3ce41034j

DO - 10.1039/c3ce41034j

M3 - Article

AN - SCOPUS:84884556247

SN - 1466-8033

VL - 15

SP - 8069

EP - 8073

JO - CrystEngComm

JF - CrystEngComm

IS - 40

ER -

Synthesis, crystal structures and luminescent properties of tetranuclear Zn molecular clusters with aroylhydrazone ligand

Abstract

Access to Document

Other files and links

Fingerprint

Cite this