Synthesis, crystal structure and thermal stability of a novel 3D microporous coordination polymer: Na2[Co(1,4-napdc) 2(DMF)2]

Rui Feng Wu; Tong Lai Zhang; Jian Guo Zhang; Xiao Jing Qiao; Li Yang; Jin Yu Guo

doi:10.1007/s11243-006-0076-3

Synthesis, crystal structure and thermal stability of a novel 3D microporous coordination polymer: Na₂[Co(1,4-napdc) ₂(DMF)₂]

Rui Feng Wu
, Tong Lai Zhang^*
, Jian Guo Zhang
, Xiao Jing Qiao
, Li Yang
, Jin Yu Guo

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology
Inner Mongolia University of Technology

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A new 3D inorganic-organic hybrid framework microporous material Na ₂Co(1,4-napdc)₂(DMF)₂(1,4-napdc = napthalene-1,4-dicarboxylate), which is constructed by coordination of cobalt ion and sodium ions with napthalene-1,4-dicarboxylate and DMF, is synthesized under solvothermal conditions. Two bidentate-bridging and two chelate-bridged carboxylate link a cobalt (II) and two sodiums (I) to the dimer structure. The square grids constructed with the caged-laddered-shaped secondary building units (SBUs) built by Co-O-Na-O and Co-O-C-O bond and 1,4-napdc links stack over each other to generate infinite 3D networks, which have a microporous channel (11.05 × 11.05 Å²) along the crystallographic c-axis. The thermal stability of the compound was investigated by differential scanning calorimetric and thermogravimetric analysis. The complexes could be anticipated as potential heat-resistant energetic material.

Original language	English
Pages (from-to)	874-878
Number of pages	5
Journal	Transition Metal Chemistry
Volume	31
Issue number	7
DOIs	https://doi.org/10.1007/s11243-006-0076-3
Publication status	Published - Oct 2006

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title = "Synthesis, crystal structure and thermal stability of a novel 3D microporous coordination polymer: Na2[Co(1,4-napdc) 2(DMF)2]",

abstract = "A new 3D inorganic-organic hybrid framework microporous material Na 2Co(1,4-napdc)2(DMF)2(1,4-napdc = napthalene-1,4-dicarboxylate), which is constructed by coordination of cobalt ion and sodium ions with napthalene-1,4-dicarboxylate and DMF, is synthesized under solvothermal conditions. Two bidentate-bridging and two chelate-bridged carboxylate link a cobalt (II) and two sodiums (I) to the dimer structure. The square grids constructed with the caged-laddered-shaped secondary building units (SBUs) built by Co-O-Na-O and Co-O-C-O bond and 1,4-napdc links stack over each other to generate infinite 3D networks, which have a microporous channel (11.05 {\texttimes} 11.05 {\AA}2) along the crystallographic c-axis. The thermal stability of the compound was investigated by differential scanning calorimetric and thermogravimetric analysis. The complexes could be anticipated as potential heat-resistant energetic material.",

author = "Wu, \{Rui Feng\} and Zhang, \{Tong Lai\} and Zhang, \{Jian Guo\} and Qiao, \{Xiao Jing\} and Li Yang and Guo, \{Jin Yu\}",

year = "2006",

month = oct,

doi = "10.1007/s11243-006-0076-3",

language = "English",

volume = "31",

pages = "874--878",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "7",

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TY - JOUR

T1 - Synthesis, crystal structure and thermal stability of a novel 3D microporous coordination polymer

T2 - Na2[Co(1,4-napdc) 2(DMF)2]

AU - Wu, Rui Feng

AU - Zhang, Tong Lai

AU - Zhang, Jian Guo

AU - Qiao, Xiao Jing

AU - Yang, Li

AU - Guo, Jin Yu

PY - 2006/10

Y1 - 2006/10

N2 - A new 3D inorganic-organic hybrid framework microporous material Na 2Co(1,4-napdc)2(DMF)2(1,4-napdc = napthalene-1,4-dicarboxylate), which is constructed by coordination of cobalt ion and sodium ions with napthalene-1,4-dicarboxylate and DMF, is synthesized under solvothermal conditions. Two bidentate-bridging and two chelate-bridged carboxylate link a cobalt (II) and two sodiums (I) to the dimer structure. The square grids constructed with the caged-laddered-shaped secondary building units (SBUs) built by Co-O-Na-O and Co-O-C-O bond and 1,4-napdc links stack over each other to generate infinite 3D networks, which have a microporous channel (11.05 × 11.05 Å2) along the crystallographic c-axis. The thermal stability of the compound was investigated by differential scanning calorimetric and thermogravimetric analysis. The complexes could be anticipated as potential heat-resistant energetic material.

AB - A new 3D inorganic-organic hybrid framework microporous material Na 2Co(1,4-napdc)2(DMF)2(1,4-napdc = napthalene-1,4-dicarboxylate), which is constructed by coordination of cobalt ion and sodium ions with napthalene-1,4-dicarboxylate and DMF, is synthesized under solvothermal conditions. Two bidentate-bridging and two chelate-bridged carboxylate link a cobalt (II) and two sodiums (I) to the dimer structure. The square grids constructed with the caged-laddered-shaped secondary building units (SBUs) built by Co-O-Na-O and Co-O-C-O bond and 1,4-napdc links stack over each other to generate infinite 3D networks, which have a microporous channel (11.05 × 11.05 Å2) along the crystallographic c-axis. The thermal stability of the compound was investigated by differential scanning calorimetric and thermogravimetric analysis. The complexes could be anticipated as potential heat-resistant energetic material.

UR - https://www.scopus.com/pages/publications/33749000350

U2 - 10.1007/s11243-006-0076-3

DO - 10.1007/s11243-006-0076-3

M3 - Article

AN - SCOPUS:33749000350

SN - 0340-4285

VL - 31

SP - 874

EP - 878

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 7

ER -

Synthesis, crystal structure and thermal stability of a novel 3D microporous coordination polymer: Na₂[Co(1,4-napdc) ₂(DMF)₂]

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