Synthesis, Crystal Structure, and Thermal Analysis of a 1D Coordination Compound Cd(SCZ)Cl2 (SCZ=Semicarbazide)

Jian Chao Liu; Wen Chao Tong; Lin Jun Xue; Tong Lai Zhang; Li Yang

doi:10.1080/15421406.2014.927961

Synthesis, Crystal Structure, and Thermal Analysis of a 1D Coordination Compound Cd(SCZ)Cl₂ (SCZ=Semicarbazide)

Jian Chao Liu
, Wen Chao Tong
, Lin Jun Xue
, Tong Lai Zhang
, Li Yang^*

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A novel transition metal multiligand coordination compound Cd(SCZ)Cl₂ was synthesized and characterized by elemental analysis and FTIR spectroscopy. Single-crystal X-ray diffraction analysis revealed that Cd(SCZ)Cl₂ crystallizes in Orthorhombic Pna2₁ space group. The thermal decomposition mechanism of Cd(SCZ)Cl₂ was studied by differential scanning calorimetry (DSC), which revealed that the complex contained one main endothermic process and one main exothermic process between 474 K and 648 K. The nonisothermal kinetics parameters were calculated by the Kissinger's method and Ozawa-Doyle's method, respectively.

Original language	English
Pages (from-to)	125-132
Number of pages	8
Journal	Molecular Crystals and Liquid Crystals
Volume	616
Issue number	1
DOIs	https://doi.org/10.1080/15421406.2014.927961
Publication status	Published - 24 Jul 2015

Keywords

Cadmium(II)
crystal structure
semicarbazide
thermal analysis

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10.1080/15421406.2014.927961

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title = "Synthesis, Crystal Structure, and Thermal Analysis of a 1D Coordination Compound Cd(SCZ)Cl2 (SCZ=Semicarbazide)",

abstract = "A novel transition metal multiligand coordination compound Cd(SCZ)Cl2 was synthesized and characterized by elemental analysis and FTIR spectroscopy. Single-crystal X-ray diffraction analysis revealed that Cd(SCZ)Cl2 crystallizes in Orthorhombic Pna21 space group. The thermal decomposition mechanism of Cd(SCZ)Cl2 was studied by differential scanning calorimetry (DSC), which revealed that the complex contained one main endothermic process and one main exothermic process between 474 K and 648 K. The nonisothermal kinetics parameters were calculated by the Kissinger's method and Ozawa-Doyle's method, respectively.",

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T1 - Synthesis, Crystal Structure, and Thermal Analysis of a 1D Coordination Compound Cd(SCZ)Cl2 (SCZ=Semicarbazide)

AU - Liu, Jian Chao

AU - Tong, Wen Chao

AU - Xue, Lin Jun

AU - Zhang, Tong Lai

AU - Yang, Li

PY - 2015/7/24

Y1 - 2015/7/24

N2 - A novel transition metal multiligand coordination compound Cd(SCZ)Cl2 was synthesized and characterized by elemental analysis and FTIR spectroscopy. Single-crystal X-ray diffraction analysis revealed that Cd(SCZ)Cl2 crystallizes in Orthorhombic Pna21 space group. The thermal decomposition mechanism of Cd(SCZ)Cl2 was studied by differential scanning calorimetry (DSC), which revealed that the complex contained one main endothermic process and one main exothermic process between 474 K and 648 K. The nonisothermal kinetics parameters were calculated by the Kissinger's method and Ozawa-Doyle's method, respectively.

AB - A novel transition metal multiligand coordination compound Cd(SCZ)Cl2 was synthesized and characterized by elemental analysis and FTIR spectroscopy. Single-crystal X-ray diffraction analysis revealed that Cd(SCZ)Cl2 crystallizes in Orthorhombic Pna21 space group. The thermal decomposition mechanism of Cd(SCZ)Cl2 was studied by differential scanning calorimetry (DSC), which revealed that the complex contained one main endothermic process and one main exothermic process between 474 K and 648 K. The nonisothermal kinetics parameters were calculated by the Kissinger's method and Ozawa-Doyle's method, respectively.

KW - Cadmium(II)

KW - crystal structure

KW - semicarbazide

KW - thermal analysis

UR - https://www.scopus.com/pages/publications/84942306263

U2 - 10.1080/15421406.2014.927961

DO - 10.1080/15421406.2014.927961

M3 - Article

AN - SCOPUS:84942306263

SN - 1542-1406

VL - 616

SP - 125

EP - 132

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

IS - 1

ER -

Synthesis, Crystal Structure, and Thermal Analysis of a 1D Coordination Compound Cd(SCZ)Cl₂ (SCZ=Semicarbazide)

Abstract

Keywords

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