Synthesis, characterization, and properties of a novel polyhedral oligomeric octamethyldiphenylsulfonylsilsesquioxane

Ziqian Li; Dinghua Li; Rongjie Yang

doi:10.1007/s10853-014-8629-x

Synthesis, characterization, and properties of a novel polyhedral oligomeric octamethyldiphenylsulfonylsilsesquioxane

Ziqian Li
, Dinghua Li^*
, Rongjie Yang

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Abstract: A novel polyhedral oligomeric octamethyldiphenylsulfonylsilsesquioxane (OMDPSS) was synthesized from octaphenylsilsesquioxane and benzenesulfonyl chloride via a Friedel–Crafts reaction in high yield. OMDPSS was characterized by Fourier transform infrared spectroscopy, ¹H NMR, ¹³C NMR, and ²⁹Si NMR spectroscopy, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI–TOF MS), wide-angle X-ray diffraction, differential scanning calorimetry, and elemental analysis, and found to be an amorphous polyhedral oligomeric silsesquioxane with a (RSiO_3/2)₈ structure. OMDPSS exhibited good solubility in commonly used solvents and superior thermal stability according to thermogravimetric analysis. Its initial thermal decomposition temperature (T_d5%) was found to be 401 °C in air and 428 °C in nitrogen.

Graphical abstract: [Figure not available: see fulltext.]

Original language	English
Pages (from-to)	697-703
Number of pages	7
Journal	Journal of Materials Science
Volume	50
Issue number	2
DOIs	https://doi.org/10.1007/s10853-014-8629-x
Publication status	Published - 22 Nov 2014
Externally published	Yes

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title = "Synthesis, characterization, and properties of a novel polyhedral oligomeric octamethyldiphenylsulfonylsilsesquioxane",

abstract = "Abstract: A novel polyhedral oligomeric octamethyldiphenylsulfonylsilsesquioxane (OMDPSS) was synthesized from octaphenylsilsesquioxane and benzenesulfonyl chloride via a Friedel{\textendash}Crafts reaction in high yield. OMDPSS was characterized by Fourier transform infrared spectroscopy, 1H NMR, 13C NMR, and 29Si NMR spectroscopy, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI{\textendash}TOF MS), wide-angle X-ray diffraction, differential scanning calorimetry, and elemental analysis, and found to be an amorphous polyhedral oligomeric silsesquioxane with a (RSiO3/2)8 structure. OMDPSS exhibited good solubility in commonly used solvents and superior thermal stability according to thermogravimetric analysis. Its initial thermal decomposition temperature (Td5\%) was found to be 401 °C in air and 428 °C in nitrogen.Graphical abstract: [Figure not available: see fulltext.]",

author = "Ziqian Li and Dinghua Li and Rongjie Yang",

note = "Publisher Copyright: {\textcopyright} 2014, Springer Science+Business Media New York.",

year = "2014",

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doi = "10.1007/s10853-014-8629-x",

language = "English",

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T1 - Synthesis, characterization, and properties of a novel polyhedral oligomeric octamethyldiphenylsulfonylsilsesquioxane

AU - Li, Ziqian

AU - Li, Dinghua

AU - Yang, Rongjie

PY - 2014/11/22

Y1 - 2014/11/22

N2 - Abstract: A novel polyhedral oligomeric octamethyldiphenylsulfonylsilsesquioxane (OMDPSS) was synthesized from octaphenylsilsesquioxane and benzenesulfonyl chloride via a Friedel–Crafts reaction in high yield. OMDPSS was characterized by Fourier transform infrared spectroscopy, 1H NMR, 13C NMR, and 29Si NMR spectroscopy, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI–TOF MS), wide-angle X-ray diffraction, differential scanning calorimetry, and elemental analysis, and found to be an amorphous polyhedral oligomeric silsesquioxane with a (RSiO3/2)8 structure. OMDPSS exhibited good solubility in commonly used solvents and superior thermal stability according to thermogravimetric analysis. Its initial thermal decomposition temperature (Td5%) was found to be 401 °C in air and 428 °C in nitrogen.Graphical abstract: [Figure not available: see fulltext.]

AB - Abstract: A novel polyhedral oligomeric octamethyldiphenylsulfonylsilsesquioxane (OMDPSS) was synthesized from octaphenylsilsesquioxane and benzenesulfonyl chloride via a Friedel–Crafts reaction in high yield. OMDPSS was characterized by Fourier transform infrared spectroscopy, 1H NMR, 13C NMR, and 29Si NMR spectroscopy, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI–TOF MS), wide-angle X-ray diffraction, differential scanning calorimetry, and elemental analysis, and found to be an amorphous polyhedral oligomeric silsesquioxane with a (RSiO3/2)8 structure. OMDPSS exhibited good solubility in commonly used solvents and superior thermal stability according to thermogravimetric analysis. Its initial thermal decomposition temperature (Td5%) was found to be 401 °C in air and 428 °C in nitrogen.Graphical abstract: [Figure not available: see fulltext.]

UR - https://www.scopus.com/pages/publications/84911988149

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DO - 10.1007/s10853-014-8629-x

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EP - 703

JO - Journal of Materials Science

JF - Journal of Materials Science

IS - 2

ER -

Synthesis, characterization, and properties of a novel polyhedral oligomeric octamethyldiphenylsulfonylsilsesquioxane

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