Synthesis, characterization, and magnetic properties of a 1D oxalate-bridged MnII complex consisting of 10-membered ring units

Wei Li; Hong Peng Jia; Zhan Feng Ju; Jie Zhang

doi:10.1002/ejic.200800175

Synthesis, characterization, and magnetic properties of a 1D oxalate-bridged Mn^II complex consisting of 10-membered ring units

Wei Li, Hong Peng Jia, Zhan Feng Ju, Jie Zhang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Self-assembly of the newly synthesized 2-methyl-4,6-bis(4′-pyridyl- 1′-pyridinio)pyrimidine dichloride (MbppCl₂) with MnCl ₂·4H₂O and Na₂C₂O₄ affords an unprecedented chain-like oxalate-bridged Mn^II polymer consisting of 10-membered ring units, {[Mn₃(OH)(H₂O) ₂(Mbpp)(C₂O₄)_3.5]· 6.5H ₂O}_n (1), which exhibits spin-canted antiferromagnetism at low temperature.

Original language	English
Pages (from-to)	3367-3371
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Issue number	21
DOIs	https://doi.org/10.1002/ejic.200800175
Publication status	Published - Jul 2008
Externally published	Yes

Keywords

Bipyridinium
Magnetic properties
Manganese
Oxalate complexes
Spin-canting

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10.1002/ejic.200800175

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title = "Synthesis, characterization, and magnetic properties of a 1D oxalate-bridged MnII complex consisting of 10-membered ring units",

abstract = "Self-assembly of the newly synthesized 2-methyl-4,6-bis(4′-pyridyl- 1′-pyridinio)pyrimidine dichloride (MbppCl2) with MnCl 2·4H2O and Na2C2O4 affords an unprecedented chain-like oxalate-bridged MnII polymer consisting of 10-membered ring units, {[Mn3(OH)(H2O) 2(Mbpp)(C2O4)3.5]· 6.5H 2O}n (1), which exhibits spin-canted antiferromagnetism at low temperature.",

keywords = "Bipyridinium, Magnetic properties, Manganese, Oxalate complexes, Spin-canting",

author = "Wei Li and Jia, {Hong Peng} and Ju, {Zhan Feng} and Jie Zhang",

year = "2008",

month = jul,

doi = "10.1002/ejic.200800175",

language = "English",

pages = "3367--3371",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "21",

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T1 - Synthesis, characterization, and magnetic properties of a 1D oxalate-bridged MnII complex consisting of 10-membered ring units

AU - Li, Wei

AU - Jia, Hong Peng

AU - Ju, Zhan Feng

AU - Zhang, Jie

PY - 2008/7

Y1 - 2008/7

N2 - Self-assembly of the newly synthesized 2-methyl-4,6-bis(4′-pyridyl- 1′-pyridinio)pyrimidine dichloride (MbppCl2) with MnCl 2·4H2O and Na2C2O4 affords an unprecedented chain-like oxalate-bridged MnII polymer consisting of 10-membered ring units, {[Mn3(OH)(H2O) 2(Mbpp)(C2O4)3.5]· 6.5H 2O}n (1), which exhibits spin-canted antiferromagnetism at low temperature.

AB - Self-assembly of the newly synthesized 2-methyl-4,6-bis(4′-pyridyl- 1′-pyridinio)pyrimidine dichloride (MbppCl2) with MnCl 2·4H2O and Na2C2O4 affords an unprecedented chain-like oxalate-bridged MnII polymer consisting of 10-membered ring units, {[Mn3(OH)(H2O) 2(Mbpp)(C2O4)3.5]· 6.5H 2O}n (1), which exhibits spin-canted antiferromagnetism at low temperature.

KW - Bipyridinium

KW - Magnetic properties

KW - Manganese

KW - Oxalate complexes

KW - Spin-canting

UR - http://www.scopus.com/inward/record.url?scp=53349145944&partnerID=8YFLogxK

U2 - 10.1002/ejic.200800175

DO - 10.1002/ejic.200800175

M3 - Article

AN - SCOPUS:53349145944

SN - 1434-1948

SP - 3367

EP - 3371

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 21

ER -

Synthesis, characterization, and magnetic properties of a 1D oxalate-bridged Mn^II complex consisting of 10-membered ring units

Abstract

Keywords

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