Synthesis, characterization and catalytic activity of energetic complexes based on 1, 5-diaminotetrazole

Zhi Min Li; Jian Guo Zhang; Jun Wei Liu; Jin Xian Zhai; Tong Lai Zhang; Li Yang

Synthesis, characterization and catalytic activity of energetic complexes based on 1, 5-diaminotetrazole

Zhi Min Li^*
, Jian Guo Zhang
, Jun Wei Liu
, Jin Xian Zhai
, Tong Lai Zhang
, Li Yang

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Two novel energetic coordination compounds using 1, 5-diaminotetrazole as ligand, Co or Cu as the central cation and picric acid as outer ion were synthesized and characterized by elemental analysis, FT-IR spectroscopy. The effects of the two complexes on thermal decomposition of AP, HMX and HNIW were investigated by DSC and TG-DTG technologies. The CCD burning-rate determinate system was used to study the catalysis of the two complexes on the combustion of the GAP/HNIW propellant. The results show the two novel energetic complexes exhibit a good catalytic performance on the thermal decomposition of AP, HMX and HNIW. In addition, the copper complex of [Cu(DAT)₂](PA)₂ can be used as the combustion catalyst to improve the combustion behavior, and to decrease pressure exponent of the GAP/HNIW propellant.

Original language	English
Pages (from-to)	79-85
Number of pages	7
Journal	Guti Huojian Jishu/Journal of Solid Rocket Technology
Volume	34
Issue number	1
Publication status	Published - Feb 2011

Keywords

1, 5-diaminotetrazole
Catalysis
Energetic complexes
Thermal decomposition

Cite this

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title = "Synthesis, characterization and catalytic activity of energetic complexes based on 1, 5-diaminotetrazole",

abstract = "Two novel energetic coordination compounds using 1, 5-diaminotetrazole as ligand, Co or Cu as the central cation and picric acid as outer ion were synthesized and characterized by elemental analysis, FT-IR spectroscopy. The effects of the two complexes on thermal decomposition of AP, HMX and HNIW were investigated by DSC and TG-DTG technologies. The CCD burning-rate determinate system was used to study the catalysis of the two complexes on the combustion of the GAP/HNIW propellant. The results show the two novel energetic complexes exhibit a good catalytic performance on the thermal decomposition of AP, HMX and HNIW. In addition, the copper complex of [Cu(DAT)2](PA)2 can be used as the combustion catalyst to improve the combustion behavior, and to decrease pressure exponent of the GAP/HNIW propellant.",

keywords = "1, 5-diaminotetrazole, Catalysis, Energetic complexes, Thermal decomposition",

author = "Li, \{Zhi Min\} and Zhang, \{Jian Guo\} and Liu, \{Jun Wei\} and Zhai, \{Jin Xian\} and Zhang, \{Tong Lai\} and Li Yang",

year = "2011",

month = feb,

language = "English",

volume = "34",

pages = "79--85",

journal = "Guti Huojian Jishu/Journal of Solid Rocket Technology",

issn = "1006-2793",

publisher = "Journal of Solid Rocket Technology",

number = "1",

}

TY - JOUR

T1 - Synthesis, characterization and catalytic activity of energetic complexes based on 1, 5-diaminotetrazole

AU - Li, Zhi Min

AU - Zhang, Jian Guo

AU - Liu, Jun Wei

AU - Zhai, Jin Xian

AU - Zhang, Tong Lai

AU - Yang, Li

PY - 2011/2

Y1 - 2011/2

N2 - Two novel energetic coordination compounds using 1, 5-diaminotetrazole as ligand, Co or Cu as the central cation and picric acid as outer ion were synthesized and characterized by elemental analysis, FT-IR spectroscopy. The effects of the two complexes on thermal decomposition of AP, HMX and HNIW were investigated by DSC and TG-DTG technologies. The CCD burning-rate determinate system was used to study the catalysis of the two complexes on the combustion of the GAP/HNIW propellant. The results show the two novel energetic complexes exhibit a good catalytic performance on the thermal decomposition of AP, HMX and HNIW. In addition, the copper complex of [Cu(DAT)2](PA)2 can be used as the combustion catalyst to improve the combustion behavior, and to decrease pressure exponent of the GAP/HNIW propellant.

AB - Two novel energetic coordination compounds using 1, 5-diaminotetrazole as ligand, Co or Cu as the central cation and picric acid as outer ion were synthesized and characterized by elemental analysis, FT-IR spectroscopy. The effects of the two complexes on thermal decomposition of AP, HMX and HNIW were investigated by DSC and TG-DTG technologies. The CCD burning-rate determinate system was used to study the catalysis of the two complexes on the combustion of the GAP/HNIW propellant. The results show the two novel energetic complexes exhibit a good catalytic performance on the thermal decomposition of AP, HMX and HNIW. In addition, the copper complex of [Cu(DAT)2](PA)2 can be used as the combustion catalyst to improve the combustion behavior, and to decrease pressure exponent of the GAP/HNIW propellant.

KW - 1, 5-diaminotetrazole

KW - Catalysis

KW - Energetic complexes

KW - Thermal decomposition

UR - https://www.scopus.com/pages/publications/79954464421

M3 - Article

AN - SCOPUS:79954464421

SN - 1006-2793

VL - 34

SP - 79

EP - 85

JO - Guti Huojian Jishu/Journal of Solid Rocket Technology

JF - Guti Huojian Jishu/Journal of Solid Rocket Technology

IS - 1

ER -

Synthesis, characterization and catalytic activity of energetic complexes based on 1, 5-diaminotetrazole

Abstract

Keywords

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