Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II)

Zilong Li; Wen Hua Sun; Leyong Wang; Biao Wu; Cheng He; Chunhua Yan

doi:10.1023/A:1015673100877

Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II)

Zilong Li
, Wen Hua Sun^*
, Leyong Wang
, Biao Wu
, Cheng He
, Chunhua Yan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II) was formed in the reaction of 8-(diphenylphosphino)quinoline with nickel chloride in air. The title complex crystallized in P1 with the following cell dimensions: a = 8.5685(3) Å, b = 10.7736(2) Å, c = 13.4391(5) Å, and α = 110.447(2)°, β = 94.577(2)°; γ = 111.138(2)°, giving a volume of 1053.75(6) Å³. The trans-dichlorobis(8-(diphenylphosphinyl)quinoline) nickel(II) adapts a central symmetric distorted octahedron. The structure is compared to other nickel(II) cation complexes, and possible reasons for the bonding states are discussed.

Original language	English
Pages (from-to)	107-111
Number of pages	5
Journal	Journal of Chemical Crystallography
Volume	32
Issue number	5-6
DOIs	https://doi.org/10.1023/A:1015673100877
Publication status	Published - 2002
Externally published	Yes

Keywords

8-(Diphenylphosphino)quinoline
Nickel chloride
X-ray single crystal structure

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10.1023/A:1015673100877

Cite this

@article{960b34631f424e29a034b50e7ff04ed9,

title = "Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II)",

abstract = "Dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II) was formed in the reaction of 8-(diphenylphosphino)quinoline with nickel chloride in air. The title complex crystallized in P1 with the following cell dimensions: a = 8.5685(3) {\AA}, b = 10.7736(2) {\AA}, c = 13.4391(5) {\AA}, and α = 110.447(2)°, β = 94.577(2)°; γ = 111.138(2)°, giving a volume of 1053.75(6) {\AA}3. The trans-dichlorobis(8-(diphenylphosphinyl)quinoline) nickel(II) adapts a central symmetric distorted octahedron. The structure is compared to other nickel(II) cation complexes, and possible reasons for the bonding states are discussed.",

keywords = "8-(Diphenylphosphino)quinoline, Nickel chloride, X-ray single crystal structure",

author = "Zilong Li and Sun, \{Wen Hua\} and Leyong Wang and Biao Wu and Cheng He and Chunhua Yan",

year = "2002",

doi = "10.1023/A:1015673100877",

language = "English",

volume = "32",

pages = "107--111",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer",

number = "5-6",

}

TY - JOUR

T1 - Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II)

AU - Li, Zilong

AU - Sun, Wen Hua

AU - Wang, Leyong

AU - Wu, Biao

AU - He, Cheng

AU - Yan, Chunhua

PY - 2002

Y1 - 2002

N2 - Dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II) was formed in the reaction of 8-(diphenylphosphino)quinoline with nickel chloride in air. The title complex crystallized in P1 with the following cell dimensions: a = 8.5685(3) Å, b = 10.7736(2) Å, c = 13.4391(5) Å, and α = 110.447(2)°, β = 94.577(2)°; γ = 111.138(2)°, giving a volume of 1053.75(6) Å3. The trans-dichlorobis(8-(diphenylphosphinyl)quinoline) nickel(II) adapts a central symmetric distorted octahedron. The structure is compared to other nickel(II) cation complexes, and possible reasons for the bonding states are discussed.

AB - Dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II) was formed in the reaction of 8-(diphenylphosphino)quinoline with nickel chloride in air. The title complex crystallized in P1 with the following cell dimensions: a = 8.5685(3) Å, b = 10.7736(2) Å, c = 13.4391(5) Å, and α = 110.447(2)°, β = 94.577(2)°; γ = 111.138(2)°, giving a volume of 1053.75(6) Å3. The trans-dichlorobis(8-(diphenylphosphinyl)quinoline) nickel(II) adapts a central symmetric distorted octahedron. The structure is compared to other nickel(II) cation complexes, and possible reasons for the bonding states are discussed.

KW - 8-(Diphenylphosphino)quinoline

KW - Nickel chloride

KW - X-ray single crystal structure

UR - https://www.scopus.com/pages/publications/0036269736

U2 - 10.1023/A:1015673100877

DO - 10.1023/A:1015673100877

M3 - Article

AN - SCOPUS:0036269736

SN - 1074-1542

VL - 32

SP - 107

EP - 111

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 5-6

ER -

Synthesis and X-ray structure of dichlorobis(8-(diphenylphosphinyl)quinoline)nickel(II)

Abstract

Keywords

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