Synthesis and structure of a novel microporous gallium phosphate Ga 3P2O8(OH)3(H2O) containing [344484] cages

Yu Du; Ji Hong Yu; Ji Yang Li; Qin He Pan; Ru Ren Xu

Synthesis and structure of a novel microporous gallium phosphate Ga ₃P₂O₈(OH)₃(H₂O) containing [3⁴4⁴8⁴] cages

Yu Du^*, Ji Hong Yu, Ji Yang Li, Qin He Pan, Ru Ren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Open-framework metal phosphates have been the subject of intense research owing to their interesting structural chemistry and potential applications in catalysis and ion exchange. The gallium phosphate family has exhibits rich structural chemistry. A novel gallium phosphate Ga₃P ₂O₈(OH)₃(H₂O)(GaPO-CJ36) has been prepared in a hydrothermal reaction system of GaO(OH)-H₃PO ₄-Co(chxn)₃Cl₃-H₂O at 180 °C for 7 days. Single-crystal X-ray analysis shows that GaPO-CJ36 crystallizes in the P2₁/c space group with a=1.833 35(12) nm, b=0.50394(3) nm, c=1.06290(9) nm, F=0.982 01(12) nm³, and Z=4. The connection of GaO₂(OH)₃(H₂O) octahedra, PO₄ and GaO₄ tetrahedra through vertex oxygen atoms forms a three-dimensional open framework, which contains 8-ring channels along the [010] direction. Its structure is composed of interesting [3⁴4⁴8⁴] cages, which have not been found in known gallium phosphates.

Original language	English
Pages (from-to)	1503-1506
Number of pages	4
Journal	Chinese Journal of Inorganic Chemistry
Volume	22
Issue number	8
Publication status	Published - Aug 2006
Externally published	Yes

Keywords

Crystal structure
Gallium phosphate
Hydrothermal synthesis

Cite this

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title = "Synthesis and structure of a novel microporous gallium phosphate Ga 3P2O8(OH)3(H2O) containing [344484] cages",

abstract = "Open-framework metal phosphates have been the subject of intense research owing to their interesting structural chemistry and potential applications in catalysis and ion exchange. The gallium phosphate family has exhibits rich structural chemistry. A novel gallium phosphate Ga3P 2O8(OH)3(H2O)(GaPO-CJ36) has been prepared in a hydrothermal reaction system of GaO(OH)-H3PO 4-Co(chxn)3Cl3-H2O at 180 °C for 7 days. Single-crystal X-ray analysis shows that GaPO-CJ36 crystallizes in the P21/c space group with a=1.833 35(12) nm, b=0.50394(3) nm, c=1.06290(9) nm, F=0.982 01(12) nm3, and Z=4. The connection of GaO2(OH)3(H2O) octahedra, PO4 and GaO4 tetrahedra through vertex oxygen atoms forms a three-dimensional open framework, which contains 8-ring channels along the [010] direction. Its structure is composed of interesting [344484] cages, which have not been found in known gallium phosphates.",

keywords = "Crystal structure, Gallium phosphate, Hydrothermal synthesis",

author = "Yu Du and Yu, {Ji Hong} and Li, {Ji Yang} and Pan, {Qin He} and Xu, {Ru Ren}",

year = "2006",

month = aug,

language = "English",

volume = "22",

pages = "1503--1506",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "8",

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TY - JOUR

T1 - Synthesis and structure of a novel microporous gallium phosphate Ga 3P2O8(OH)3(H2O) containing [344484] cages

AU - Du, Yu

AU - Yu, Ji Hong

AU - Li, Ji Yang

AU - Pan, Qin He

AU - Xu, Ru Ren

PY - 2006/8

Y1 - 2006/8

N2 - Open-framework metal phosphates have been the subject of intense research owing to their interesting structural chemistry and potential applications in catalysis and ion exchange. The gallium phosphate family has exhibits rich structural chemistry. A novel gallium phosphate Ga3P 2O8(OH)3(H2O)(GaPO-CJ36) has been prepared in a hydrothermal reaction system of GaO(OH)-H3PO 4-Co(chxn)3Cl3-H2O at 180 °C for 7 days. Single-crystal X-ray analysis shows that GaPO-CJ36 crystallizes in the P21/c space group with a=1.833 35(12) nm, b=0.50394(3) nm, c=1.06290(9) nm, F=0.982 01(12) nm3, and Z=4. The connection of GaO2(OH)3(H2O) octahedra, PO4 and GaO4 tetrahedra through vertex oxygen atoms forms a three-dimensional open framework, which contains 8-ring channels along the [010] direction. Its structure is composed of interesting [344484] cages, which have not been found in known gallium phosphates.

AB - Open-framework metal phosphates have been the subject of intense research owing to their interesting structural chemistry and potential applications in catalysis and ion exchange. The gallium phosphate family has exhibits rich structural chemistry. A novel gallium phosphate Ga3P 2O8(OH)3(H2O)(GaPO-CJ36) has been prepared in a hydrothermal reaction system of GaO(OH)-H3PO 4-Co(chxn)3Cl3-H2O at 180 °C for 7 days. Single-crystal X-ray analysis shows that GaPO-CJ36 crystallizes in the P21/c space group with a=1.833 35(12) nm, b=0.50394(3) nm, c=1.06290(9) nm, F=0.982 01(12) nm3, and Z=4. The connection of GaO2(OH)3(H2O) octahedra, PO4 and GaO4 tetrahedra through vertex oxygen atoms forms a three-dimensional open framework, which contains 8-ring channels along the [010] direction. Its structure is composed of interesting [344484] cages, which have not been found in known gallium phosphates.

KW - Crystal structure

KW - Gallium phosphate

KW - Hydrothermal synthesis

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M3 - Article

AN - SCOPUS:33748662864

SN - 1001-4861

VL - 22

SP - 1503

EP - 1506

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 8

ER -

Synthesis and structure of a novel microporous gallium phosphate Ga ₃P₂O₈(OH)₃(H₂O) containing [3⁴4⁴8⁴] cages

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Keywords

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