Synthesis and re-refinement of Cu3PSe4

Hong Wei Ma; Guo Cong Guo; Guo Wei Zhou; Ming Sheng Wang; Shan Huo Lin; Zhen Chao Dong; Jin Shun Huang

Synthesis and re-refinement of Cu₃PSe₄

Hong Wei Ma
, Guo Cong Guo^*
, Guo Wei Zhou
, Ming Sheng Wang
, Shan Huo Lin
, Zhen Chao Dong
, Jin Shun Huang

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter
University of Chinese Academy of Sciences

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The title compound Cu₃PSe₄ was synthesized by the reaction of CuCl, P₂Se₅ and Se in a molar ratio of 1:1:1 at 500 °C and structurally characterized by X-ray crystallography. The crystal belongs to orthorhombic, space group Pmn2₁ with cell parameters: a = 7.685(2), b = 6.656(1), c = 6.377(1) Å, V = 326.2(1) Å³, Z = 2, D_c = 5.472 g/cm³, M _r = 537.43, F(000) = 476, μ = 32.12 mm^-1, R = 0.0642, wR = 0.1481 and S = 1.037. The 3-D structure can be regarded as constructed from the alternately stacking of [Cu(2)Se₄] tetrahedral layers and Cu(1)-P-Se tetrahedral layers along the b direction, in which the Cu(2)-Se layer is comprised of corner-sharing [Cu(2)Se₄] tetrahedra along the a and c directions, and the Cu(1)-P-Se layer is consisted of alternately corner-sharing [Cu(1)Se₄] tetrahedra and [PSe₄] tetrahedra along the a and c directions.

Original language	English
Pages (from-to)	288-291
Number of pages	4
Journal	Jiegou Huaxue
Volume	21
Issue number	3
Publication status	Published - 2002
Externally published	Yes

Keywords

Metal chalcogenophosphide
Normal tetrahedral structure
Solid state reaction

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@article{82e1be24b70a404e8d04ca42751b9e71,

title = "Synthesis and re-refinement of Cu3PSe4",

abstract = "The title compound Cu3PSe4 was synthesized by the reaction of CuCl, P2Se5 and Se in a molar ratio of 1:1:1 at 500 °C and structurally characterized by X-ray crystallography. The crystal belongs to orthorhombic, space group Pmn21 with cell parameters: a = 7.685(2), b = 6.656(1), c = 6.377(1) {\AA}, V = 326.2(1) {\AA}3, Z = 2, Dc = 5.472 g/cm3, M r = 537.43, F(000) = 476, μ = 32.12 mm-1, R = 0.0642, wR = 0.1481 and S = 1.037. The 3-D structure can be regarded as constructed from the alternately stacking of [Cu(2)Se4] tetrahedral layers and Cu(1)-P-Se tetrahedral layers along the b direction, in which the Cu(2)-Se layer is comprised of corner-sharing [Cu(2)Se4] tetrahedra along the a and c directions, and the Cu(1)-P-Se layer is consisted of alternately corner-sharing [Cu(1)Se4] tetrahedra and [PSe4] tetrahedra along the a and c directions.",

keywords = "Metal chalcogenophosphide, Normal tetrahedral structure, Solid state reaction",

author = "Ma, \{Hong Wei\} and Guo, \{Guo Cong\} and Zhou, \{Guo Wei\} and Wang, \{Ming Sheng\} and Lin, \{Shan Huo\} and Dong, \{Zhen Chao\} and Huang, \{Jin Shun\}",

year = "2002",

language = "English",

volume = "21",

pages = "288--291",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "3",

}

TY - JOUR

T1 - Synthesis and re-refinement of Cu3PSe4

AU - Ma, Hong Wei

AU - Guo, Guo Cong

AU - Zhou, Guo Wei

AU - Wang, Ming Sheng

AU - Lin, Shan Huo

AU - Dong, Zhen Chao

AU - Huang, Jin Shun

PY - 2002

Y1 - 2002

N2 - The title compound Cu3PSe4 was synthesized by the reaction of CuCl, P2Se5 and Se in a molar ratio of 1:1:1 at 500 °C and structurally characterized by X-ray crystallography. The crystal belongs to orthorhombic, space group Pmn21 with cell parameters: a = 7.685(2), b = 6.656(1), c = 6.377(1) Å, V = 326.2(1) Å3, Z = 2, Dc = 5.472 g/cm3, M r = 537.43, F(000) = 476, μ = 32.12 mm-1, R = 0.0642, wR = 0.1481 and S = 1.037. The 3-D structure can be regarded as constructed from the alternately stacking of [Cu(2)Se4] tetrahedral layers and Cu(1)-P-Se tetrahedral layers along the b direction, in which the Cu(2)-Se layer is comprised of corner-sharing [Cu(2)Se4] tetrahedra along the a and c directions, and the Cu(1)-P-Se layer is consisted of alternately corner-sharing [Cu(1)Se4] tetrahedra and [PSe4] tetrahedra along the a and c directions.

AB - The title compound Cu3PSe4 was synthesized by the reaction of CuCl, P2Se5 and Se in a molar ratio of 1:1:1 at 500 °C and structurally characterized by X-ray crystallography. The crystal belongs to orthorhombic, space group Pmn21 with cell parameters: a = 7.685(2), b = 6.656(1), c = 6.377(1) Å, V = 326.2(1) Å3, Z = 2, Dc = 5.472 g/cm3, M r = 537.43, F(000) = 476, μ = 32.12 mm-1, R = 0.0642, wR = 0.1481 and S = 1.037. The 3-D structure can be regarded as constructed from the alternately stacking of [Cu(2)Se4] tetrahedral layers and Cu(1)-P-Se tetrahedral layers along the b direction, in which the Cu(2)-Se layer is comprised of corner-sharing [Cu(2)Se4] tetrahedra along the a and c directions, and the Cu(1)-P-Se layer is consisted of alternately corner-sharing [Cu(1)Se4] tetrahedra and [PSe4] tetrahedra along the a and c directions.

KW - Metal chalcogenophosphide

KW - Normal tetrahedral structure

KW - Solid state reaction

UR - https://www.scopus.com/pages/publications/33750344922

M3 - Article

AN - SCOPUS:33750344922

SN - 0254-5861

VL - 21

SP - 288

EP - 291

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 3

ER -

Synthesis and re-refinement of Cu₃PSe₄

Abstract

Keywords

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