Synthesis and properties of energetic binder poly(2, 2-dinitropropyl methacrylate)

Gong Zheng Zhang; Qin Xu; Shan Zhao; Fang Wang; Peng Wang; Hai Hua Li

Synthesis and properties of energetic binder poly(2, 2-dinitropropyl methacrylate)

Gong Zheng Zhang^*, Qin Xu, Shan Zhao, Fang Wang, Peng Wang, Hai Hua Li

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The energetic binder poly(2, 2-dinitropropyl methacrylate) was synthesized by the free radical polymerization of 2, 2-dinitropropyl methacrylate (DNPMA) in toluene by using azobisiosbutyronitrile as initiator. The effect of initiator concentration on polymer yield was investigated and the polymerization rate equation was determined by experiment. The structure and thermal properties of poly (2, 2-dinitropropyl methacrylate) were also characterized by FT-IR, ¹HNMR, UV, DSC and TGA measurements. The results show that the polymerization rate equation for DNPMA is R_p=k[M]^1.22[I]^0.47. This demonstrates that the chain termination reaction is according to the bimolecular termination mode. The larger polymer yield is obtained at a higher initiator concentration. The thermal decomposition temperature of poly (2, 2-dinitropropyl acrylate) is 238°C. This binder is a thermally stable polymer.

Original language	English
Pages (from-to)	84-87
Number of pages	4
Journal	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
Volume	27
Issue number	SUPPL. 2
Publication status	Published - Dec 2007
Externally published	Yes

Keywords

2, 2-dinitropropyl methacrylate homopolymer
Energetic binder
Free radical polymerization
Gem-dinitro compound

Cite this

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title = "Synthesis and properties of energetic binder poly(2, 2-dinitropropyl methacrylate)",

abstract = "The energetic binder poly(2, 2-dinitropropyl methacrylate) was synthesized by the free radical polymerization of 2, 2-dinitropropyl methacrylate (DNPMA) in toluene by using azobisiosbutyronitrile as initiator. The effect of initiator concentration on polymer yield was investigated and the polymerization rate equation was determined by experiment. The structure and thermal properties of poly (2, 2-dinitropropyl methacrylate) were also characterized by FT-IR, 1HNMR, UV, DSC and TGA measurements. The results show that the polymerization rate equation for DNPMA is Rp=k[M]1.22[I]0.47. This demonstrates that the chain termination reaction is according to the bimolecular termination mode. The larger polymer yield is obtained at a higher initiator concentration. The thermal decomposition temperature of poly (2, 2-dinitropropyl acrylate) is 238°C. This binder is a thermally stable polymer.",

keywords = "2, 2-dinitropropyl methacrylate homopolymer, Energetic binder, Free radical polymerization, Gem-dinitro compound",

author = "Zhang, {Gong Zheng} and Qin Xu and Shan Zhao and Fang Wang and Peng Wang and Li, {Hai Hua}",

year = "2007",

month = dec,

language = "English",

volume = "27",

pages = "84--87",

journal = "Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology",

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TY - JOUR

T1 - Synthesis and properties of energetic binder poly(2, 2-dinitropropyl methacrylate)

AU - Zhang, Gong Zheng

AU - Xu, Qin

AU - Zhao, Shan

AU - Wang, Fang

AU - Wang, Peng

AU - Li, Hai Hua

PY - 2007/12

Y1 - 2007/12

N2 - The energetic binder poly(2, 2-dinitropropyl methacrylate) was synthesized by the free radical polymerization of 2, 2-dinitropropyl methacrylate (DNPMA) in toluene by using azobisiosbutyronitrile as initiator. The effect of initiator concentration on polymer yield was investigated and the polymerization rate equation was determined by experiment. The structure and thermal properties of poly (2, 2-dinitropropyl methacrylate) were also characterized by FT-IR, 1HNMR, UV, DSC and TGA measurements. The results show that the polymerization rate equation for DNPMA is Rp=k[M]1.22[I]0.47. This demonstrates that the chain termination reaction is according to the bimolecular termination mode. The larger polymer yield is obtained at a higher initiator concentration. The thermal decomposition temperature of poly (2, 2-dinitropropyl acrylate) is 238°C. This binder is a thermally stable polymer.

AB - The energetic binder poly(2, 2-dinitropropyl methacrylate) was synthesized by the free radical polymerization of 2, 2-dinitropropyl methacrylate (DNPMA) in toluene by using azobisiosbutyronitrile as initiator. The effect of initiator concentration on polymer yield was investigated and the polymerization rate equation was determined by experiment. The structure and thermal properties of poly (2, 2-dinitropropyl methacrylate) were also characterized by FT-IR, 1HNMR, UV, DSC and TGA measurements. The results show that the polymerization rate equation for DNPMA is Rp=k[M]1.22[I]0.47. This demonstrates that the chain termination reaction is according to the bimolecular termination mode. The larger polymer yield is obtained at a higher initiator concentration. The thermal decomposition temperature of poly (2, 2-dinitropropyl acrylate) is 238°C. This binder is a thermally stable polymer.

KW - 2, 2-dinitropropyl methacrylate homopolymer

KW - Energetic binder

KW - Free radical polymerization

KW - Gem-dinitro compound

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M3 - Article

AN - SCOPUS:40749109795

SN - 1001-0645

VL - 27

SP - 84

EP - 87

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - SUPPL. 2

ER -

Synthesis and properties of energetic binder poly(2, 2-dinitropropyl methacrylate)

Abstract

Keywords

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