Abstract
Zinc sulfide (ZnS) sheathed zinc (Zn)-cadmium (Cd) nanowire heterojunctions have been prepared by thermal evaporating of ZnS and CdS powders in a vertical induction furnace at 1200 °C. Studies found that both the Zn and Cd subnanowires, within a single nanoheterojunction, are single-crystallines with the growth directions perpendicular to the [2110] plane, whereas the sheathed ZnS is polycrystalline with a thickness of ca. 5 nm. The Zn/Cd interface structure in the ZnS sheathed Zn-Cd nanowire heterojunctions was thoroughly experimentally studied by high-resolution transmission electron microscopy and theoretically studied using a near-coincidence site lattice (NCSL) concept. The results show that the Cd and Zn have a crystalline orientation relationship as [0001]Zn//[0001]Cd, (101̄0)zn// (101̄0)cd, (011̄0)zn//(11̄00)Cd, and (1̄100)Zn//(1̄100)Cd.
| Original language | English |
|---|---|
| Pages (from-to) | 14123-14127 |
| Number of pages | 5 |
| Journal | Journal of Physical Chemistry B |
| Volume | 110 |
| Issue number | 29 |
| DOIs | |
| Publication status | Published - 27 Jul 2006 |
| Externally published | Yes |
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