Synthesis and description of a novel metal-organic framework based on trigonal prismatic building blocks

Bing Li; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/zaac.200801363

Synthesis and description of a novel metal-organic framework based on trigonal prismatic building blocks

Bing Li^*, Shou Tian Zheng, Guo Yu Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A novel metal-organic framework based on trigonal prismatic building blocks has been hydrothermally prepared and structurally characterized. It crystallizes in the cubic space group Pa3̄ with Z = 8. The oxo-centered trinuclear complex units are bridged by 1,3-benzenedicarboxylate (1,3-BDC) ligands, forming a new 3D open-framework [Fe₃O(H₂O) ₃(U-BDC)₃][Cl]-9H₂O (1). Its magnetic behavior has been quantitively analyzed by the Bleaney-Bowers equation, indicating the presence of antiferromagnetic interactions within the trinuclear Fe ^III atoms.

Original language	English
Pages (from-to)	1345-1347
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	635
Issue number	9-10
DOIs	https://doi.org/10.1002/zaac.200801363
Publication status	Published - Jul 2009
Externally published	Yes

Keywords

Coordination polymers
Crystal structure
Hydrothermal, synthesis
Metal-organic frameworks
X-ray diffraction

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10.1002/zaac.200801363

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title = "Synthesis and description of a novel metal-organic framework based on trigonal prismatic building blocks",

abstract = "A novel metal-organic framework based on trigonal prismatic building blocks has been hydrothermally prepared and structurally characterized. It crystallizes in the cubic space group Pa{\=3} with Z = 8. The oxo-centered trinuclear complex units are bridged by 1,3-benzenedicarboxylate (1,3-BDC) ligands, forming a new 3D open-framework [Fe3O(H2O) 3(U-BDC)3][Cl]-9H2O (1). Its magnetic behavior has been quantitively analyzed by the Bleaney-Bowers equation, indicating the presence of antiferromagnetic interactions within the trinuclear Fe III atoms.",

keywords = "Coordination polymers, Crystal structure, Hydrothermal, synthesis, Metal-organic frameworks, X-ray diffraction",

author = "Bing Li and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2009",

month = jul,

doi = "10.1002/zaac.200801363",

language = "English",

volume = "635",

pages = "1345--1347",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

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publisher = "Wiley-VCH Verlag",

number = "9-10",

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T1 - Synthesis and description of a novel metal-organic framework based on trigonal prismatic building blocks

AU - Li, Bing

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2009/7

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N2 - A novel metal-organic framework based on trigonal prismatic building blocks has been hydrothermally prepared and structurally characterized. It crystallizes in the cubic space group Pa3̄ with Z = 8. The oxo-centered trinuclear complex units are bridged by 1,3-benzenedicarboxylate (1,3-BDC) ligands, forming a new 3D open-framework [Fe3O(H2O) 3(U-BDC)3][Cl]-9H2O (1). Its magnetic behavior has been quantitively analyzed by the Bleaney-Bowers equation, indicating the presence of antiferromagnetic interactions within the trinuclear Fe III atoms.

AB - A novel metal-organic framework based on trigonal prismatic building blocks has been hydrothermally prepared and structurally characterized. It crystallizes in the cubic space group Pa3̄ with Z = 8. The oxo-centered trinuclear complex units are bridged by 1,3-benzenedicarboxylate (1,3-BDC) ligands, forming a new 3D open-framework [Fe3O(H2O) 3(U-BDC)3][Cl]-9H2O (1). Its magnetic behavior has been quantitively analyzed by the Bleaney-Bowers equation, indicating the presence of antiferromagnetic interactions within the trinuclear Fe III atoms.

KW - Coordination polymers

KW - Crystal structure

KW - Hydrothermal, synthesis

KW - Metal-organic frameworks

KW - X-ray diffraction

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DO - 10.1002/zaac.200801363

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SN - 0044-2313

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JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 9-10

ER -

Synthesis and description of a novel metal-organic framework based on trigonal prismatic building blocks

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Keywords

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