Synthesis and crystal structure of the cryptate complex [Gd(L)(DMF)] · KSCN · CH3CN · 3H2O (L is a deprotonated phenol-based N8O3 cryptand)

Shu Yan Yu; Quan Ming Wang; Biao Wu; Xin Tao Wu; Huai Ming Hu; Liu Fang Wang; An Xin Wu

doi:10.1016/0277-5387(96)00237-9

Synthesis and crystal structure of the cryptate complex [Gd(L)(DMF)] · KSCN · CH₃CN · 3H₂O (L is a deprotonated phenol-based N₈O₃ cryptand)

Shu Yan Yu, Quan Ming Wang, Biao Wu, Xin Tao Wu^*, Huai Ming Hu, Liu Fang Wang, An Xin Wu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The cryptate complex [Gd(L)(DMF)] · KSCN · CH₃CN · 3H₂O has been synthesized by the reaction of gadolinium isothiocyanate and potassium thiocyanate with cryptate [Na(H2L)], which was prepared by a (2 + 3) Schiff-base condensation of tris(2-aminoethyl)amine and 2,6-diformyl-4-methoxyphenol in the presence of NaOH. The Gd atom is encapsulated in the cryptand with an unsymmetric eight-coordinate environment.

Original language	English
Pages (from-to)	321-325
Number of pages	5
Journal	Polyhedron
Volume	16
Issue number	2
DOIs	https://doi.org/10.1016/0277-5387(96)00237-9
Publication status	Published - 1997
Externally published	Yes

Keywords

Complex
Cryptand
Cryptate
Gadolinium
Structure
Synthesis

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10.1016/0277-5387(96)00237-9

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@article{31aff99e37e24a5689f019af99b28fac,

title = "Synthesis and crystal structure of the cryptate complex [Gd(L)(DMF)] · KSCN · CH3CN · 3H2O (L is a deprotonated phenol-based N8O3 cryptand)",

abstract = "The cryptate complex [Gd(L)(DMF)] · KSCN · CH3CN · 3H2O has been synthesized by the reaction of gadolinium isothiocyanate and potassium thiocyanate with cryptate [Na(H2L)], which was prepared by a (2 + 3) Schiff-base condensation of tris(2-aminoethyl)amine and 2,6-diformyl-4-methoxyphenol in the presence of NaOH. The Gd atom is encapsulated in the cryptand with an unsymmetric eight-coordinate environment.",

keywords = "Complex, Cryptand, Cryptate, Gadolinium, Structure, Synthesis",

author = "Yu, {Shu Yan} and Wang, {Quan Ming} and Biao Wu and Wu, {Xin Tao} and Hu, {Huai Ming} and Wang, {Liu Fang} and Wu, {An Xin}",

year = "1997",

doi = "10.1016/0277-5387(96)00237-9",

language = "English",

volume = "16",

pages = "321--325",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "2",

}

TY - JOUR

T1 - Synthesis and crystal structure of the cryptate complex [Gd(L)(DMF)] · KSCN · CH3CN · 3H2O (L is a deprotonated phenol-based N8O3 cryptand)

AU - Yu, Shu Yan

AU - Wang, Quan Ming

AU - Wu, Biao

AU - Wu, Xin Tao

AU - Hu, Huai Ming

AU - Wang, Liu Fang

AU - Wu, An Xin

PY - 1997

Y1 - 1997

N2 - The cryptate complex [Gd(L)(DMF)] · KSCN · CH3CN · 3H2O has been synthesized by the reaction of gadolinium isothiocyanate and potassium thiocyanate with cryptate [Na(H2L)], which was prepared by a (2 + 3) Schiff-base condensation of tris(2-aminoethyl)amine and 2,6-diformyl-4-methoxyphenol in the presence of NaOH. The Gd atom is encapsulated in the cryptand with an unsymmetric eight-coordinate environment.

AB - The cryptate complex [Gd(L)(DMF)] · KSCN · CH3CN · 3H2O has been synthesized by the reaction of gadolinium isothiocyanate and potassium thiocyanate with cryptate [Na(H2L)], which was prepared by a (2 + 3) Schiff-base condensation of tris(2-aminoethyl)amine and 2,6-diformyl-4-methoxyphenol in the presence of NaOH. The Gd atom is encapsulated in the cryptand with an unsymmetric eight-coordinate environment.

KW - Complex

KW - Cryptand

KW - Cryptate

KW - Gadolinium

KW - Structure

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=0040645550&partnerID=8YFLogxK

U2 - 10.1016/0277-5387(96)00237-9

DO - 10.1016/0277-5387(96)00237-9

M3 - Article

AN - SCOPUS:0040645550

SN - 0277-5387

VL - 16

SP - 321

EP - 325

JO - Polyhedron

JF - Polyhedron

IS - 2

ER -

Synthesis and crystal structure of the cryptate complex [Gd(L)(DMF)] · KSCN · CH₃CN · 3H₂O (L is a deprotonated phenol-based N₈O₃ cryptand)

Abstract

Keywords

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