Abstract
The cryptate complex [Gd(L)(DMF)] · KSCN · CH3CN · 3H2O has been synthesized by the reaction of gadolinium isothiocyanate and potassium thiocyanate with cryptate [Na(H2L)], which was prepared by a (2 + 3) Schiff-base condensation of tris(2-aminoethyl)amine and 2,6-diformyl-4-methoxyphenol in the presence of NaOH. The Gd atom is encapsulated in the cryptand with an unsymmetric eight-coordinate environment.
Original language | English |
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Pages (from-to) | 321-325 |
Number of pages | 5 |
Journal | Polyhedron |
Volume | 16 |
Issue number | 2 |
DOIs | |
Publication status | Published - 1997 |
Externally published | Yes |
Keywords
- Complex
- Cryptand
- Cryptate
- Gadolinium
- Structure
- Synthesis