Synthesis and crystal structure of metal-organic frameworks [Ln2(pydc-3,5)3(H2O)9]n 3nH2O (Ln = Sm, Eu, Gd, Dy; pydc-3,5 = pyridine-3,5-dicarboxylate) along with the photoluminescent property of its europium one

Qisong Shi; Shu Zhang; Qian Wang; Hongwei Ma; Guoqiang Yang; Wen Hua Sun

doi:10.1016/j.molstruc.2006.10.013

Synthesis and crystal structure of metal-organic frameworks [Ln₂(pydc-3,5)₃(H₂O)₉]_n3nH₂O (Ln = Sm, Eu, Gd, Dy; pydc-3,5 = pyridine-3,5-dicarboxylate) along with the photoluminescent property of its europium one

Qisong Shi
, Shu Zhang
, Qian Wang
, Hongwei Ma
, Guoqiang Yang
, Wen Hua Sun^*

^*Corresponding author for this work

Peking University
Beijing Institute of Petrochemical Technology
CAS - Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Rare-earth metal-organic frameworks, [Ln₂(pydc)₃(H₂O)₉] _n3nH₂O (Ln = Sm, Eu, Gd, Dy; pydc = pyridine-3,5-dicarboxylate), were synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The solid-state photoluminescence measurements exhibited red light-emitting characteristic of europium (III) coordination polymer. The title compounds consist of one-dimensional dual chains, in which each metal atom is nine-coordinated with oxygen atoms.

Original language	English
Pages (from-to)	185-189
Number of pages	5
Journal	Journal of Molecular Structure
Volume	837
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2006.10.013
Publication status	Published - 30 Jun 2007
Externally published	Yes

Keywords

Coordination polymer
Crystal structure
Luminescence
Rare-earth metal complexes

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10.1016/j.molstruc.2006.10.013

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Shi, Q., Zhang, S., Wang, Q., Ma, H., Yang, G., & Sun, W. H. (2007). Synthesis and crystal structure of metal-organic frameworks [Ln₂(pydc-3,5)₃(H₂O)₉]_n3nH₂O (Ln = Sm, Eu, Gd, Dy; pydc-3,5 = pyridine-3,5-dicarboxylate) along with the photoluminescent property of its europium one. Journal of Molecular Structure, 837(1-3), 185-189. https://doi.org/10.1016/j.molstruc.2006.10.013

@article{48533a5693be4a5ca5604999cf235fc9,

title = "Synthesis and crystal structure of metal-organic frameworks [Ln2(pydc-3,5)3(H2O)9]n 3nH2O (Ln = Sm, Eu, Gd, Dy; pydc-3,5 = pyridine-3,5-dicarboxylate) along with the photoluminescent property of its europium one",

abstract = "Rare-earth metal-organic frameworks, [Ln2(pydc)3(H2O)9] n3nH2O (Ln = Sm, Eu, Gd, Dy; pydc = pyridine-3,5-dicarboxylate), were synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The solid-state photoluminescence measurements exhibited red light-emitting characteristic of europium (III) coordination polymer. The title compounds consist of one-dimensional dual chains, in which each metal atom is nine-coordinated with oxygen atoms.",

keywords = "Coordination polymer, Crystal structure, Luminescence, Rare-earth metal complexes",

author = "Qisong Shi and Shu Zhang and Qian Wang and Hongwei Ma and Guoqiang Yang and Sun, \{Wen Hua\}",

year = "2007",

month = jun,

day = "30",

doi = "10.1016/j.molstruc.2006.10.013",

language = "English",

volume = "837",

pages = "185--189",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "1-3",

}

Shi, Q, Zhang, S, Wang, Q, Ma, H, Yang, G & Sun, WH 2007, 'Synthesis and crystal structure of metal-organic frameworks [Ln₂(pydc-3,5)₃(H₂O)₉]_n3nH₂O (Ln = Sm, Eu, Gd, Dy; pydc-3,5 = pyridine-3,5-dicarboxylate) along with the photoluminescent property of its europium one', Journal of Molecular Structure, vol. 837, no. 1-3, pp. 185-189. https://doi.org/10.1016/j.molstruc.2006.10.013

Synthesis and crystal structure of metal-organic frameworks [Ln₂(pydc-3,5)₃(H₂O)₉]_n3nH₂O (Ln = Sm, Eu, Gd, Dy; pydc-3,5 = pyridine-3,5-dicarboxylate) along with the photoluminescent property of its europium one. / Shi, Qisong; Zhang, Shu; Wang, Qian et al.
In: Journal of Molecular Structure, Vol. 837, No. 1-3, 30.06.2007, p. 185-189.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and crystal structure of metal-organic frameworks [Ln2(pydc-3,5)3(H2O)9]n 3nH2O (Ln = Sm, Eu, Gd, Dy; pydc-3,5 = pyridine-3,5-dicarboxylate) along with the photoluminescent property of its europium one

AU - Shi, Qisong

AU - Zhang, Shu

AU - Wang, Qian

AU - Ma, Hongwei

AU - Yang, Guoqiang

AU - Sun, Wen Hua

PY - 2007/6/30

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N2 - Rare-earth metal-organic frameworks, [Ln2(pydc)3(H2O)9] n3nH2O (Ln = Sm, Eu, Gd, Dy; pydc = pyridine-3,5-dicarboxylate), were synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The solid-state photoluminescence measurements exhibited red light-emitting characteristic of europium (III) coordination polymer. The title compounds consist of one-dimensional dual chains, in which each metal atom is nine-coordinated with oxygen atoms.

AB - Rare-earth metal-organic frameworks, [Ln2(pydc)3(H2O)9] n3nH2O (Ln = Sm, Eu, Gd, Dy; pydc = pyridine-3,5-dicarboxylate), were synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The solid-state photoluminescence measurements exhibited red light-emitting characteristic of europium (III) coordination polymer. The title compounds consist of one-dimensional dual chains, in which each metal atom is nine-coordinated with oxygen atoms.

KW - Coordination polymer

KW - Crystal structure

KW - Luminescence

KW - Rare-earth metal complexes

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