Synthesis and crystal structure of complex [Ni(en)3] 4[HVIV12VV6O 42(PO4)]

Shou Tian Zheng; Qing Xin Zeng; Zhi En Lin; Guo Yu Yang

Synthesis and crystal structure of complex [Ni(en)₃] ₄[HV^IV₁₂V^V₆O ₄₂(PO₄)]

Shou Tian Zheng
, Qing Xin Zeng
, Zhi En Lin
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A new complex [Ni(en)₃]₄[HV^IV ₁₂V^V₆O₄₂(PO₄)] has been hydrothermally synthesized and characterized by X-Ray diffraction, IR and Elemental analysis. Single crystal X-ray analysis indicates that this compoud crystallizes in cubic system, space group Im 3m with a = 17.4081(2) Å, V = 5275.38(10) Å³, R = 0.0420, wR = 0.1055, Z = 2, D_c = 1.663g · cm^-3, μ = 2.297mm^-1, F(000) = 2636. The crystal structure consists of [Ni(en)₃]²⁺ cations and {HV₁₈O₄₂(PO₄)}^8- cluster anion which construct from 18 {VO₅} square pyramids. The VO₅ pyramids joined each other to form a {V₁₈O₄₂} cage hosting a tetrahedral {PO₄}^3- moiety with disordered oxygen atoms. CCDC: 185574.

Original language	English
Pages (from-to)	1233-1236
Number of pages	4
Journal	Chinese Journal of Inorganic Chemistry
Volume	18
Issue number	12
Publication status	Published - 2002
Externally published	Yes

Keywords

Crystal structure
Hydrothermal synthesis
Polyoxovanadate

Cite this

@article{d7e4861dda824dd2b4a4af5d8e05c186,

title = "Synthesis and crystal structure of complex [Ni(en)3] 4[HVIV12VV6O 42(PO4)]",

abstract = "A new complex [Ni(en)3]4[HVIV 12VV6O42(PO4)] has been hydrothermally synthesized and characterized by X-Ray diffraction, IR and Elemental analysis. Single crystal X-ray analysis indicates that this compoud crystallizes in cubic system, space group Im 3m with a = 17.4081(2) {\AA}, V = 5275.38(10) {\AA}3, R = 0.0420, wR = 0.1055, Z = 2, Dc = 1.663g · cm-3, μ = 2.297mm-1, F(000) = 2636. The crystal structure consists of [Ni(en)3]2+ cations and \{HV18O42(PO4)\}8- cluster anion which construct from 18 \{VO5\} square pyramids. The VO5 pyramids joined each other to form a \{V18O42\} cage hosting a tetrahedral \{PO4\}3- moiety with disordered oxygen atoms. CCDC: 185574.",

keywords = "Crystal structure, Hydrothermal synthesis, Polyoxovanadate",

author = "Zheng, \{Shou Tian\} and Zeng, \{Qing Xin\} and Lin, \{Zhi En\} and Yang, \{Guo Yu\}",

year = "2002",

language = "English",

volume = "18",

pages = "1233--1236",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "12",

}

TY - JOUR

T1 - Synthesis and crystal structure of complex [Ni(en)3] 4[HVIV12VV6O 42(PO4)]

AU - Zheng, Shou Tian

AU - Zeng, Qing Xin

AU - Lin, Zhi En

AU - Yang, Guo Yu

PY - 2002

Y1 - 2002

N2 - A new complex [Ni(en)3]4[HVIV 12VV6O42(PO4)] has been hydrothermally synthesized and characterized by X-Ray diffraction, IR and Elemental analysis. Single crystal X-ray analysis indicates that this compoud crystallizes in cubic system, space group Im 3m with a = 17.4081(2) Å, V = 5275.38(10) Å3, R = 0.0420, wR = 0.1055, Z = 2, Dc = 1.663g · cm-3, μ = 2.297mm-1, F(000) = 2636. The crystal structure consists of [Ni(en)3]2+ cations and {HV18O42(PO4)}8- cluster anion which construct from 18 {VO5} square pyramids. The VO5 pyramids joined each other to form a {V18O42} cage hosting a tetrahedral {PO4}3- moiety with disordered oxygen atoms. CCDC: 185574.

AB - A new complex [Ni(en)3]4[HVIV 12VV6O42(PO4)] has been hydrothermally synthesized and characterized by X-Ray diffraction, IR and Elemental analysis. Single crystal X-ray analysis indicates that this compoud crystallizes in cubic system, space group Im 3m with a = 17.4081(2) Å, V = 5275.38(10) Å3, R = 0.0420, wR = 0.1055, Z = 2, Dc = 1.663g · cm-3, μ = 2.297mm-1, F(000) = 2636. The crystal structure consists of [Ni(en)3]2+ cations and {HV18O42(PO4)}8- cluster anion which construct from 18 {VO5} square pyramids. The VO5 pyramids joined each other to form a {V18O42} cage hosting a tetrahedral {PO4}3- moiety with disordered oxygen atoms. CCDC: 185574.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Polyoxovanadate

UR - https://www.scopus.com/pages/publications/20444378160

M3 - Article

AN - SCOPUS:20444378160

SN - 1001-4861

VL - 18

SP - 1233

EP - 1236

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 12

ER -

Synthesis and crystal structure of complex [Ni(en)₃] ₄[HV^IV₁₂V^V₆O ₄₂(PO₄)]

Abstract

Keywords

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