Synthesis and crystal structure of bis[1-(4-Methoxyphenyl)- 3 -(1H-1,2,4-Triazol-1-yl)-1-propanone-N4] dichorocobalt (II) complex

Ke Guang Cao; Cheng Hui Sun; Tao Fang; Xin Qi Zhao

Synthesis and crystal structure of bis[1-(4-Methoxyphenyl)- 3 -(1H-1,2,4-Triazol-1-yl)-1-propanone-N⁴] dichorocobalt (II) complex

Ke Guang Cao^*
, Cheng Hui Sun
, Tao Fang
, Xin Qi Zhao

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology
Chengde Petroleum College

Research output: Contribution to journal › Article › peer-review

Abstract

Bis [1-(4-methoxyphenyl)- 3-(1H-1,2,4-triazol-1-yl)-1-propanone-N⁴] dichorocobalt (II) complex was synthesized and the crystal structure determined by X-ray crystallography. It crystallizes in the monoclinic system, space group C2/c group, with lattice parameters a=2.1008(4) nm, b=0.48888(10) nm, c=2.6274(5) nm, β=98.10(3)°, V=2.6715(9) nm³, Z=4, D_c=1.473 g/cm³. It has C₂ symmetry with its axis through the Co atom, and the Co atom was coordinated by two N atoms of the 1-(4-methoxyphenyl)-3-(1H-1,2,4-triazol-1-yl)-1-propanone ligands and two Cl^- atoms, forming a slightly distorted tetrahedron. IR and electronic spectra study of the target complex were carried out.

Original language	English
Pages (from-to)	835-838
Number of pages	4
Journal	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
Volume	25
Issue number	9
Publication status	Published - Sept 2005

Keywords

1H-1,2,4-triazol-1-yl complex
Crystal structure
Electronic spectra
Synthesis

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title = "Synthesis and crystal structure of bis[1-(4-Methoxyphenyl)- 3 -(1H-1,2,4-Triazol-1-yl)-1-propanone-N4] dichorocobalt (II) complex",

abstract = "Bis [1-(4-methoxyphenyl)- 3-(1H-1,2,4-triazol-1-yl)-1-propanone-N4] dichorocobalt (II) complex was synthesized and the crystal structure determined by X-ray crystallography. It crystallizes in the monoclinic system, space group C2/c group, with lattice parameters a=2.1008(4) nm, b=0.48888(10) nm, c=2.6274(5) nm, β=98.10(3)°, V=2.6715(9) nm3, Z=4, Dc=1.473 g/cm3. It has C2 symmetry with its axis through the Co atom, and the Co atom was coordinated by two N atoms of the 1-(4-methoxyphenyl)-3-(1H-1,2,4-triazol-1-yl)-1-propanone ligands and two Cl- atoms, forming a slightly distorted tetrahedron. IR and electronic spectra study of the target complex were carried out.",

keywords = "1H-1,2,4-triazol-1-yl complex, Crystal structure, Electronic spectra, Synthesis",

author = "Cao, \{Ke Guang\} and Sun, \{Cheng Hui\} and Tao Fang and Zhao, \{Xin Qi\}",

year = "2005",

month = sep,

language = "English",

volume = "25",

pages = "835--838",

journal = "Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology",

issn = "1001-0645",

publisher = "Beijing Institute of Technology",

number = "9",

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TY - JOUR

T1 - Synthesis and crystal structure of bis[1-(4-Methoxyphenyl)- 3 -(1H-1,2,4-Triazol-1-yl)-1-propanone-N4] dichorocobalt (II) complex

AU - Cao, Ke Guang

AU - Sun, Cheng Hui

AU - Fang, Tao

AU - Zhao, Xin Qi

PY - 2005/9

Y1 - 2005/9

N2 - Bis [1-(4-methoxyphenyl)- 3-(1H-1,2,4-triazol-1-yl)-1-propanone-N4] dichorocobalt (II) complex was synthesized and the crystal structure determined by X-ray crystallography. It crystallizes in the monoclinic system, space group C2/c group, with lattice parameters a=2.1008(4) nm, b=0.48888(10) nm, c=2.6274(5) nm, β=98.10(3)°, V=2.6715(9) nm3, Z=4, Dc=1.473 g/cm3. It has C2 symmetry with its axis through the Co atom, and the Co atom was coordinated by two N atoms of the 1-(4-methoxyphenyl)-3-(1H-1,2,4-triazol-1-yl)-1-propanone ligands and two Cl- atoms, forming a slightly distorted tetrahedron. IR and electronic spectra study of the target complex were carried out.

AB - Bis [1-(4-methoxyphenyl)- 3-(1H-1,2,4-triazol-1-yl)-1-propanone-N4] dichorocobalt (II) complex was synthesized and the crystal structure determined by X-ray crystallography. It crystallizes in the monoclinic system, space group C2/c group, with lattice parameters a=2.1008(4) nm, b=0.48888(10) nm, c=2.6274(5) nm, β=98.10(3)°, V=2.6715(9) nm3, Z=4, Dc=1.473 g/cm3. It has C2 symmetry with its axis through the Co atom, and the Co atom was coordinated by two N atoms of the 1-(4-methoxyphenyl)-3-(1H-1,2,4-triazol-1-yl)-1-propanone ligands and two Cl- atoms, forming a slightly distorted tetrahedron. IR and electronic spectra study of the target complex were carried out.

KW - 1H-1,2,4-triazol-1-yl complex

KW - Crystal structure

KW - Electronic spectra

KW - Synthesis

UR - https://www.scopus.com/pages/publications/27244448596

M3 - Article

AN - SCOPUS:27244448596

SN - 1001-0645

VL - 25

SP - 835

EP - 838

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - 9

ER -

Synthesis and crystal structure of bis[1-(4-Methoxyphenyl)- 3 -(1H-1,2,4-Triazol-1-yl)-1-propanone-N⁴] dichorocobalt (II) complex

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