Synthesis and crystal structure of bis[1-(4-Methoxyphenyl)- 3 -(1H-1,2,4-Triazol-1-yl)-1-propanone-N4] dichorocobalt (II) complex

Ke Guang Cao*, Cheng Hui Sun, Tao Fang, Xin Qi Zhao

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Bis [1-(4-methoxyphenyl)- 3-(1H-1,2,4-triazol-1-yl)-1-propanone-N4] dichorocobalt (II) complex was synthesized and the crystal structure determined by X-ray crystallography. It crystallizes in the monoclinic system, space group C2/c group, with lattice parameters a=2.1008(4) nm, b=0.48888(10) nm, c=2.6274(5) nm, β=98.10(3)°, V=2.6715(9) nm3, Z=4, Dc=1.473 g/cm3. It has C2 symmetry with its axis through the Co atom, and the Co atom was coordinated by two N atoms of the 1-(4-methoxyphenyl)-3-(1H-1,2,4-triazol-1-yl)-1-propanone ligands and two Cl- atoms, forming a slightly distorted tetrahedron. IR and electronic spectra study of the target complex were carried out.

Original languageEnglish
Pages (from-to)835-838
Number of pages4
JournalBeijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
Volume25
Issue number9
Publication statusPublished - Sept 2005

Keywords

  • 1H-1,2,4-triazol-1-yl complex
  • Crystal structure
  • Electronic spectra
  • Synthesis

Fingerprint

Dive into the research topics of 'Synthesis and crystal structure of bis[1-(4-Methoxyphenyl)- 3 -(1H-1,2,4-Triazol-1-yl)-1-propanone-N4] dichorocobalt (II) complex'. Together they form a unique fingerprint.

Cite this