Synthesis and crystal structure of 3-(1,1,1,3,3,3-hexamethyl-disuazan-2-yl) -1-phenyl-1H-indene-2-carbonitrile

Yong Jun Liu; Hua Zhong; Yan Qi; Shu Sheng Zhang

Synthesis and crystal structure of 3-(1,1,1,3,3,3-hexamethyl-disuazan-2-yl) -1-phenyl-1H-indene-2-carbonitrile

Yong Jun Liu
, Hua Zhong
, Yan Qi
, Shu Sheng Zhang^*

^*Corresponding author for this work

Qingdao University of Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal structure of 3-(1,1,1,3,3,3-hexamethyl-disilazan-2-yl)-1- phenyl-1H-indene-2-carbonitrile has been determined by X-ray diffraction method. The crystal is orthorhombic with space group P2₁2₁2 ₁, a = 8.6317(2) Å, b = 14.8822(3) Å, c = 17.5719(3) Å, V= 2257.26(8) Å³, Z = 4, and R₁ = 0.047. wR2 = 0.129 for 2016 observed reflections (I > 2.00σ(I)). The mean plane of indene is almost perpendicular to the phenyl ring attached at chloro atom, the dihedral angling being 84.4(1)°. In the crystal packing, the molecules are stabilized by C-H⋯π and C-H⋯N interactions.

Original language	English
Pages (from-to)	1983-1987
Number of pages	5
Journal	Asian Journal of Chemistry
Volume	19
Issue number	3
Publication status	Published - 2007
Externally published	Yes

Keywords

Crystal structure
Disilylation
Indene
Samarium

Cite this

@article{cd387602bfac4e0287f9831d54407a1e,

title = "Synthesis and crystal structure of 3-(1,1,1,3,3,3-hexamethyl-disuazan-2-yl) -1-phenyl-1H-indene-2-carbonitrile",

abstract = "The crystal structure of 3-(1,1,1,3,3,3-hexamethyl-disilazan-2-yl)-1- phenyl-1H-indene-2-carbonitrile has been determined by X-ray diffraction method. The crystal is orthorhombic with space group P21212 1, a = 8.6317(2) {\AA}, b = 14.8822(3) {\AA}, c = 17.5719(3) {\AA}, V= 2257.26(8) {\AA}3, Z = 4, and R1 = 0.047. wR2 = 0.129 for 2016 observed reflections (I > 2.00σ(I)). The mean plane of indene is almost perpendicular to the phenyl ring attached at chloro atom, the dihedral angling being 84.4(1)°. In the crystal packing, the molecules are stabilized by C-H⋯π and C-H⋯N interactions.",

keywords = "Crystal structure, Disilylation, Indene, Samarium",

author = "Liu, \{Yong Jun\} and Hua Zhong and Yan Qi and Zhang, \{Shu Sheng\}",

year = "2007",

language = "English",

volume = "19",

pages = "1983--1987",

journal = "Asian Journal of Chemistry",

issn = "0970-7077",

publisher = "Asian Publication Corporation",

number = "3",

}

TY - JOUR

T1 - Synthesis and crystal structure of 3-(1,1,1,3,3,3-hexamethyl-disuazan-2-yl) -1-phenyl-1H-indene-2-carbonitrile

AU - Liu, Yong Jun

AU - Zhong, Hua

AU - Qi, Yan

AU - Zhang, Shu Sheng

PY - 2007

Y1 - 2007

N2 - The crystal structure of 3-(1,1,1,3,3,3-hexamethyl-disilazan-2-yl)-1- phenyl-1H-indene-2-carbonitrile has been determined by X-ray diffraction method. The crystal is orthorhombic with space group P21212 1, a = 8.6317(2) Å, b = 14.8822(3) Å, c = 17.5719(3) Å, V= 2257.26(8) Å3, Z = 4, and R1 = 0.047. wR2 = 0.129 for 2016 observed reflections (I > 2.00σ(I)). The mean plane of indene is almost perpendicular to the phenyl ring attached at chloro atom, the dihedral angling being 84.4(1)°. In the crystal packing, the molecules are stabilized by C-H⋯π and C-H⋯N interactions.

AB - The crystal structure of 3-(1,1,1,3,3,3-hexamethyl-disilazan-2-yl)-1- phenyl-1H-indene-2-carbonitrile has been determined by X-ray diffraction method. The crystal is orthorhombic with space group P21212 1, a = 8.6317(2) Å, b = 14.8822(3) Å, c = 17.5719(3) Å, V= 2257.26(8) Å3, Z = 4, and R1 = 0.047. wR2 = 0.129 for 2016 observed reflections (I > 2.00σ(I)). The mean plane of indene is almost perpendicular to the phenyl ring attached at chloro atom, the dihedral angling being 84.4(1)°. In the crystal packing, the molecules are stabilized by C-H⋯π and C-H⋯N interactions.

KW - Crystal structure

KW - Disilylation

KW - Indene

KW - Samarium

UR - https://www.scopus.com/pages/publications/33947395636

M3 - Article

AN - SCOPUS:33947395636

SN - 0970-7077

VL - 19

SP - 1983

EP - 1987

JO - Asian Journal of Chemistry

JF - Asian Journal of Chemistry

IS - 3

ER -

Synthesis and crystal structure of 3-(1,1,1,3,3,3-hexamethyl-disuazan-2-yl) -1-phenyl-1H-indene-2-carbonitrile

Abstract

Keywords

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