Synthesis and characterization of task-specific acidic ionic liquids

Jing Xian Wang; Qin Wu; Han Sheng Li

Synthesis and characterization of task-specific acidic ionic liquids

Jing Xian Wang^*
, Qin Wu
, Han Sheng Li

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

Several water-stable and task-specific Bronsted-acidic ionic liquids were synthesized, each system consisting of the methyl pyridinium ion ([MPy]⁺), or quaternary ammonium ion ([Et₃NH]⁺), or sultone pyridinium ion ([SPy]⁺) as the cation, and either dihydric phosphate (H₂PO₄^-), or bisulfate ion (HSO₄^-), or nitrate ion (NO₃^-) as the anion. They were characterized by nuclear magnetic resonance (NMR), infrared spectrum (IR), and electrospray ionization mass spectrum (ESI-MS). It was confirmed that their structures were consistent with the designed structure and their purities were more than 95%. So the method of synthesis and purification is proved to be proper.

Original language	English
Pages (from-to)	55-58
Number of pages	4
Journal	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
Volume	27
Issue number	SUPPL. 2
Publication status	Published - Dec 2007

Keywords

Electrospray ionization mass spectrum
Infrared spectrum
Ionic liquids
Nuclear magnetic resonance

Cite this

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title = "Synthesis and characterization of task-specific acidic ionic liquids",

abstract = "Several water-stable and task-specific Bronsted-acidic ionic liquids were synthesized, each system consisting of the methyl pyridinium ion ([MPy]+), or quaternary ammonium ion ([Et3NH]+), or sultone pyridinium ion ([SPy]+) as the cation, and either dihydric phosphate (H2PO4-), or bisulfate ion (HSO4-), or nitrate ion (NO3-) as the anion. They were characterized by nuclear magnetic resonance (NMR), infrared spectrum (IR), and electrospray ionization mass spectrum (ESI-MS). It was confirmed that their structures were consistent with the designed structure and their purities were more than 95\%. So the method of synthesis and purification is proved to be proper.",

keywords = "Electrospray ionization mass spectrum, Infrared spectrum, Ionic liquids, Nuclear magnetic resonance",

author = "Wang, \{Jing Xian\} and Qin Wu and Li, \{Han Sheng\}",

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T1 - Synthesis and characterization of task-specific acidic ionic liquids

AU - Wang, Jing Xian

AU - Wu, Qin

AU - Li, Han Sheng

PY - 2007/12

Y1 - 2007/12

N2 - Several water-stable and task-specific Bronsted-acidic ionic liquids were synthesized, each system consisting of the methyl pyridinium ion ([MPy]+), or quaternary ammonium ion ([Et3NH]+), or sultone pyridinium ion ([SPy]+) as the cation, and either dihydric phosphate (H2PO4-), or bisulfate ion (HSO4-), or nitrate ion (NO3-) as the anion. They were characterized by nuclear magnetic resonance (NMR), infrared spectrum (IR), and electrospray ionization mass spectrum (ESI-MS). It was confirmed that their structures were consistent with the designed structure and their purities were more than 95%. So the method of synthesis and purification is proved to be proper.

AB - Several water-stable and task-specific Bronsted-acidic ionic liquids were synthesized, each system consisting of the methyl pyridinium ion ([MPy]+), or quaternary ammonium ion ([Et3NH]+), or sultone pyridinium ion ([SPy]+) as the cation, and either dihydric phosphate (H2PO4-), or bisulfate ion (HSO4-), or nitrate ion (NO3-) as the anion. They were characterized by nuclear magnetic resonance (NMR), infrared spectrum (IR), and electrospray ionization mass spectrum (ESI-MS). It was confirmed that their structures were consistent with the designed structure and their purities were more than 95%. So the method of synthesis and purification is proved to be proper.

KW - Electrospray ionization mass spectrum

KW - Infrared spectrum

KW - Ionic liquids

KW - Nuclear magnetic resonance

UR - https://www.scopus.com/pages/publications/40749095982

M3 - Article

AN - SCOPUS:40749095982

SN - 1001-0645

VL - 27

SP - 55

EP - 58

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - SUPPL. 2

ER -

Synthesis and characterization of task-specific acidic ionic liquids

Abstract

Keywords

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