Synthesis and characterization of organically templated zinc phosphites with two- and three-dimensional structures, (C2N2H 10)Zn2(HPO3)3 and (C 4N2H12)Zn3(HPO3) 4

Zhi En Lin; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1016/j.solidstatesciences.2004.01.007

Synthesis and characterization of organically templated zinc phosphites with two- and three-dimensional structures, (C₂N₂H ₁₀)Zn₂(HPO₃)₃ and (C ₄N₂H₁₂)Zn₃(HPO₃) ₄

Zhi En Lin
, Jie Zhang
, Shou Tian Zheng
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Two organically templated zinc phosphites, (C₂N ₂H₁₀)Zn₂(HPO₃)₃ (1) and (C₄N₂H₁₂)Zn₃(HPO₃) ₄ (2), were hydrothermally synthesized and structurally characterized. Compound 1 crystallized in the triclinic system, space group P-1 (No. 2), a=8.6357(14) Å, b=8.8197(14) Å, c=9.9665(16) Å, α=64.645(2), β=65.922(2), γ=81.049(2)°, V=626.12(17) Å³, Z=2. The connectivity of the strictly alternating ZnO ₄ and HPO₃ polyhedra results in infinite macroanionic layers with 4.8-net. The organic cations locate in the interlayer region and hold the macroanionic sheets together by strong H-bonds. Compound 2 crystallized in the monoclinic system, space group P2₁/c (No. 14), a=9.9352(14) Å, b=10.1487(14) Å, c=17.8257(13) Å, β=95.701(7), V=1788.5(4) Å³, Z=4. The structure of 2 consists of ZnO₄ tetrahedra and HPO₃ pseudo-pyramids with shared vertices, forming a 3D framework with 8-ring channels. Both compounds were characterized by FTIR, elemental analysis, ICP analysis and thermogravimetric analysis.

Original language	English
Pages (from-to)	371-376
Number of pages	6
Journal	Solid State Sciences
Volume	6
Issue number	4
DOIs	https://doi.org/10.1016/j.solidstatesciences.2004.01.007
Publication status	Published - Apr 2004
Externally published	Yes

Keywords

Crystal structure
Hydrothermal synthesis
Open framework
Zinc phosphite

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10.1016/j.solidstatesciences.2004.01.007

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@article{e16a0575233d482ba29c496033d66258,

title = "Synthesis and characterization of organically templated zinc phosphites with two- and three-dimensional structures, (C2N2H 10)Zn2(HPO3)3 and (C 4N2H12)Zn3(HPO3) 4",

abstract = "Two organically templated zinc phosphites, (C2N 2H10)Zn2(HPO3)3 (1) and (C4N2H12)Zn3(HPO3) 4 (2), were hydrothermally synthesized and structurally characterized. Compound 1 crystallized in the triclinic system, space group P-1 (No. 2), a=8.6357(14) {\AA}, b=8.8197(14) {\AA}, c=9.9665(16) {\AA}, α=64.645(2), β=65.922(2), γ=81.049(2)°, V=626.12(17) {\AA}3, Z=2. The connectivity of the strictly alternating ZnO 4 and HPO3 polyhedra results in infinite macroanionic layers with 4.8-net. The organic cations locate in the interlayer region and hold the macroanionic sheets together by strong H-bonds. Compound 2 crystallized in the monoclinic system, space group P21/c (No. 14), a=9.9352(14) {\AA}, b=10.1487(14) {\AA}, c=17.8257(13) {\AA}, β=95.701(7), V=1788.5(4) {\AA}3, Z=4. The structure of 2 consists of ZnO4 tetrahedra and HPO3 pseudo-pyramids with shared vertices, forming a 3D framework with 8-ring channels. Both compounds were characterized by FTIR, elemental analysis, ICP analysis and thermogravimetric analysis.",

keywords = "Crystal structure, Hydrothermal synthesis, Open framework, Zinc phosphite",

author = "Lin, \{Zhi En\} and Jie Zhang and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2004",

month = apr,

doi = "10.1016/j.solidstatesciences.2004.01.007",

language = "English",

volume = "6",

pages = "371--376",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier Masson s.r.l.",

number = "4",

}

TY - JOUR

T1 - Synthesis and characterization of organically templated zinc phosphites with two- and three-dimensional structures, (C2N2H 10)Zn2(HPO3)3 and (C 4N2H12)Zn3(HPO3) 4

AU - Lin, Zhi En

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004/4

Y1 - 2004/4

N2 - Two organically templated zinc phosphites, (C2N 2H10)Zn2(HPO3)3 (1) and (C4N2H12)Zn3(HPO3) 4 (2), were hydrothermally synthesized and structurally characterized. Compound 1 crystallized in the triclinic system, space group P-1 (No. 2), a=8.6357(14) Å, b=8.8197(14) Å, c=9.9665(16) Å, α=64.645(2), β=65.922(2), γ=81.049(2)°, V=626.12(17) Å3, Z=2. The connectivity of the strictly alternating ZnO 4 and HPO3 polyhedra results in infinite macroanionic layers with 4.8-net. The organic cations locate in the interlayer region and hold the macroanionic sheets together by strong H-bonds. Compound 2 crystallized in the monoclinic system, space group P21/c (No. 14), a=9.9352(14) Å, b=10.1487(14) Å, c=17.8257(13) Å, β=95.701(7), V=1788.5(4) Å3, Z=4. The structure of 2 consists of ZnO4 tetrahedra and HPO3 pseudo-pyramids with shared vertices, forming a 3D framework with 8-ring channels. Both compounds were characterized by FTIR, elemental analysis, ICP analysis and thermogravimetric analysis.

AB - Two organically templated zinc phosphites, (C2N 2H10)Zn2(HPO3)3 (1) and (C4N2H12)Zn3(HPO3) 4 (2), were hydrothermally synthesized and structurally characterized. Compound 1 crystallized in the triclinic system, space group P-1 (No. 2), a=8.6357(14) Å, b=8.8197(14) Å, c=9.9665(16) Å, α=64.645(2), β=65.922(2), γ=81.049(2)°, V=626.12(17) Å3, Z=2. The connectivity of the strictly alternating ZnO 4 and HPO3 polyhedra results in infinite macroanionic layers with 4.8-net. The organic cations locate in the interlayer region and hold the macroanionic sheets together by strong H-bonds. Compound 2 crystallized in the monoclinic system, space group P21/c (No. 14), a=9.9352(14) Å, b=10.1487(14) Å, c=17.8257(13) Å, β=95.701(7), V=1788.5(4) Å3, Z=4. The structure of 2 consists of ZnO4 tetrahedra and HPO3 pseudo-pyramids with shared vertices, forming a 3D framework with 8-ring channels. Both compounds were characterized by FTIR, elemental analysis, ICP analysis and thermogravimetric analysis.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Open framework

KW - Zinc phosphite

UR - https://www.scopus.com/pages/publications/1842507606

U2 - 10.1016/j.solidstatesciences.2004.01.007

DO - 10.1016/j.solidstatesciences.2004.01.007

M3 - Article

AN - SCOPUS:1842507606

SN - 1293-2558

VL - 6

SP - 371

EP - 376

JO - Solid State Sciences

JF - Solid State Sciences

IS - 4

ER -

Synthesis and characterization of organically templated zinc phosphites with two- and three-dimensional structures, (C₂N₂H ₁₀)Zn₂(HPO₃)₃ and (C ₄N₂H₁₂)Zn₃(HPO₃) ₄

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