Synthesis and characterization of a two-dimensional zinc phosphite, Zn 3(tren)(HPO3)3·xH2O (x ≈ 0.5; tren = tris(2-aminoethyl)amine)

You Ju Zhong; Yong Mei Chen; Yan Qiong Sun; Guo Yu Yang

doi:10.1002/zaac.200500034

Synthesis and characterization of a two-dimensional zinc phosphite, Zn ₃(tren)(HPO₃)₃·xH₂O (x ≈ 0.5; tren = tris(2-aminoethyl)amine)

You Ju Zhong^*
, Yong Mei Chen
, Yan Qiong Sun
, Guo Yu Yang

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter
Beijing University of Chemical Technology

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A new zinc phosphite with the formula Zn₃(tren)-(HPO ₃)₃·xH₂O (x≈0.5) has been synthesized under hydrothermal conditions and characterized by FTIR, elemental analysis, powder X-ray diffraction, single-crystal X-ray diffraction, thermogravimetric analysis and its fluorescent spectrum. The compound crystallizes in the triclinic system, space group P1 (No.2), a = 10.1188(9) Å, b = 10.4194(9) Å, c = 10.5176(9) Å, α = 60.763(2)°, β = 70.6150(10)°, γ = 80.725(2)°, V = 912.77(14) Å³, Z = 2. The structure consists of double crankshaft chains, which are linked by Zn-O-P bonds to form 8- and 12-membered channels along the [100] direction. The claw-like Zn-centered complexes of Zn(N₄C₆H₁₈) as the supported templates, hang into the 12-MR channels through Zn-O-P linkages with framework.

Original language	English
Pages (from-to)	1957-1960
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	631
Issue number	10
DOIs	https://doi.org/10.1002/zaac.200500034
Publication status	Published - 2005
Externally published	Yes

Keywords

Crystal structure
Hybrid
Hydrothermal synthesis
Zinc phosphite

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title = "Synthesis and characterization of a two-dimensional zinc phosphite, Zn 3(tren)(HPO3)3·xH2O (x ≈ 0.5; tren = tris(2-aminoethyl)amine)",

abstract = "A new zinc phosphite with the formula Zn3(tren)-(HPO 3)3·xH2O (x≈0.5) has been synthesized under hydrothermal conditions and characterized by FTIR, elemental analysis, powder X-ray diffraction, single-crystal X-ray diffraction, thermogravimetric analysis and its fluorescent spectrum. The compound crystallizes in the triclinic system, space group P1 (No.2), a = 10.1188(9) {\AA}, b = 10.4194(9) {\AA}, c = 10.5176(9) {\AA}, α = 60.763(2)°, β = 70.6150(10)°, γ = 80.725(2)°, V = 912.77(14) {\AA}3, Z = 2. The structure consists of double crankshaft chains, which are linked by Zn-O-P bonds to form 8- and 12-membered channels along the [100] direction. The claw-like Zn-centered complexes of Zn(N4C6H18) as the supported templates, hang into the 12-MR channels through Zn-O-P linkages with framework.",

keywords = "Crystal structure, Hybrid, Hydrothermal synthesis, Zinc phosphite",

author = "Zhong, \{You Ju\} and Chen, \{Yong Mei\} and Sun, \{Yan Qiong\} and Yang, \{Guo Yu\}",

year = "2005",

doi = "10.1002/zaac.200500034",

language = "English",

volume = "631",

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T1 - Synthesis and characterization of a two-dimensional zinc phosphite, Zn 3(tren)(HPO3)3·xH2O (x ≈ 0.5; tren = tris(2-aminoethyl)amine)

AU - Zhong, You Ju

AU - Chen, Yong Mei

AU - Sun, Yan Qiong

AU - Yang, Guo Yu

PY - 2005

Y1 - 2005

N2 - A new zinc phosphite with the formula Zn3(tren)-(HPO 3)3·xH2O (x≈0.5) has been synthesized under hydrothermal conditions and characterized by FTIR, elemental analysis, powder X-ray diffraction, single-crystal X-ray diffraction, thermogravimetric analysis and its fluorescent spectrum. The compound crystallizes in the triclinic system, space group P1 (No.2), a = 10.1188(9) Å, b = 10.4194(9) Å, c = 10.5176(9) Å, α = 60.763(2)°, β = 70.6150(10)°, γ = 80.725(2)°, V = 912.77(14) Å3, Z = 2. The structure consists of double crankshaft chains, which are linked by Zn-O-P bonds to form 8- and 12-membered channels along the [100] direction. The claw-like Zn-centered complexes of Zn(N4C6H18) as the supported templates, hang into the 12-MR channels through Zn-O-P linkages with framework.

AB - A new zinc phosphite with the formula Zn3(tren)-(HPO 3)3·xH2O (x≈0.5) has been synthesized under hydrothermal conditions and characterized by FTIR, elemental analysis, powder X-ray diffraction, single-crystal X-ray diffraction, thermogravimetric analysis and its fluorescent spectrum. The compound crystallizes in the triclinic system, space group P1 (No.2), a = 10.1188(9) Å, b = 10.4194(9) Å, c = 10.5176(9) Å, α = 60.763(2)°, β = 70.6150(10)°, γ = 80.725(2)°, V = 912.77(14) Å3, Z = 2. The structure consists of double crankshaft chains, which are linked by Zn-O-P bonds to form 8- and 12-membered channels along the [100] direction. The claw-like Zn-centered complexes of Zn(N4C6H18) as the supported templates, hang into the 12-MR channels through Zn-O-P linkages with framework.

KW - Crystal structure

KW - Hybrid

KW - Hydrothermal synthesis

KW - Zinc phosphite

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DO - 10.1002/zaac.200500034

M3 - Article

AN - SCOPUS:23344445055

SN - 0044-2313

VL - 631

SP - 1957

EP - 1960

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

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ER -

Synthesis and characterization of a two-dimensional zinc phosphite, Zn ₃(tren)(HPO₃)₃·xH₂O (x ≈ 0.5; tren = tris(2-aminoethyl)amine)

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