Synthesis and characterization of a novel energetic complex [Cd(DAT) 6](NO3)2 (DAT = 1,5-diamino-tetrazole) with high nitrogen content

Jian Guo Zhang; Jing Yu Li; Yan Zang; Yuan Jie Shu; Tong Lai Zhang; Li Yang; Philip P. Power

doi:10.1002/zaac.200900502

Synthesis and characterization of a novel energetic complex [Cd(DAT) ₆](NO₃)₂ (DAT = 1,5-diamino-tetrazole) with high nitrogen content

Jian Guo Zhang^*
, Jing Yu Li
, Yan Zang
, Yuan Jie Shu
, Tong Lai Zhang
, Li Yang
, Philip P. Power

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The novel high nitrogen-containing energetic complex [Cd(DAT) ₆](NO₃)₂was synthesized by reaction of Cd(NO₃)₂·6H₂O with 1,5-diamino-tetrazole (DAT). It was characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction, analysis. The central Cd²⁺ ion is coordinated by six nitrogen atoms from six DAT ligand molecules to form a hexacoordinate distorted octahedral compound. The [Cd(DAT)₆](NO ₃)₂ molecules are linked together through two types of hydrogen bonds thus forming a stable three-dimensional net structure. The thermal decomposition mechanism of [Cd(DAT)₆](NO₃) ₂ was investigated by DSC and TG/DTG analyses and FT-IR spectroscopy. The kinetic parameters of the exothermic process were studied by using Kissinger's and Ozawa-Doyle's methods.

Original language	English
Pages (from-to)	1147-1151
Number of pages	5
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	636
Issue number	6
DOIs	https://doi.org/10.1002/zaac.200900502
Publication status	Published - May 2010

Keywords

1-5-diamino-tetrazole (DAT)
Cadmium
Nitrogen
Structure elucidation
Thermochemistry

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10.1002/zaac.200900502

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title = "Synthesis and characterization of a novel energetic complex [Cd(DAT) 6](NO3)2 (DAT = 1,5-diamino-tetrazole) with high nitrogen content",

abstract = "The novel high nitrogen-containing energetic complex [Cd(DAT) 6](NO3)2was synthesized by reaction of Cd(NO3)2·6H2O with 1,5-diamino-tetrazole (DAT). It was characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction, analysis. The central Cd2+ ion is coordinated by six nitrogen atoms from six DAT ligand molecules to form a hexacoordinate distorted octahedral compound. The [Cd(DAT)6](NO 3)2 molecules are linked together through two types of hydrogen bonds thus forming a stable three-dimensional net structure. The thermal decomposition mechanism of [Cd(DAT)6](NO3) 2 was investigated by DSC and TG/DTG analyses and FT-IR spectroscopy. The kinetic parameters of the exothermic process were studied by using Kissinger's and Ozawa-Doyle's methods.",

keywords = "1-5-diamino-tetrazole (DAT), Cadmium, Nitrogen, Structure elucidation, Thermochemistry",

author = "Zhang, \{Jian Guo\} and Li, \{Jing Yu\} and Yan Zang and Shu, \{Yuan Jie\} and Zhang, \{Tong Lai\} and Li Yang and Power, \{Philip P.\}",

year = "2010",

month = may,

doi = "10.1002/zaac.200900502",

language = "English",

volume = "636",

pages = "1147--1151",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

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T1 - Synthesis and characterization of a novel energetic complex [Cd(DAT) 6](NO3)2 (DAT = 1,5-diamino-tetrazole) with high nitrogen content

AU - Zhang, Jian Guo

AU - Li, Jing Yu

AU - Zang, Yan

AU - Shu, Yuan Jie

AU - Zhang, Tong Lai

AU - Yang, Li

AU - Power, Philip P.

PY - 2010/5

Y1 - 2010/5

N2 - The novel high nitrogen-containing energetic complex [Cd(DAT) 6](NO3)2was synthesized by reaction of Cd(NO3)2·6H2O with 1,5-diamino-tetrazole (DAT). It was characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction, analysis. The central Cd2+ ion is coordinated by six nitrogen atoms from six DAT ligand molecules to form a hexacoordinate distorted octahedral compound. The [Cd(DAT)6](NO 3)2 molecules are linked together through two types of hydrogen bonds thus forming a stable three-dimensional net structure. The thermal decomposition mechanism of [Cd(DAT)6](NO3) 2 was investigated by DSC and TG/DTG analyses and FT-IR spectroscopy. The kinetic parameters of the exothermic process were studied by using Kissinger's and Ozawa-Doyle's methods.

AB - The novel high nitrogen-containing energetic complex [Cd(DAT) 6](NO3)2was synthesized by reaction of Cd(NO3)2·6H2O with 1,5-diamino-tetrazole (DAT). It was characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction, analysis. The central Cd2+ ion is coordinated by six nitrogen atoms from six DAT ligand molecules to form a hexacoordinate distorted octahedral compound. The [Cd(DAT)6](NO 3)2 molecules are linked together through two types of hydrogen bonds thus forming a stable three-dimensional net structure. The thermal decomposition mechanism of [Cd(DAT)6](NO3) 2 was investigated by DSC and TG/DTG analyses and FT-IR spectroscopy. The kinetic parameters of the exothermic process were studied by using Kissinger's and Ozawa-Doyle's methods.

KW - 1-5-diamino-tetrazole (DAT)

KW - Cadmium

KW - Nitrogen

KW - Structure elucidation

KW - Thermochemistry

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U2 - 10.1002/zaac.200900502

DO - 10.1002/zaac.200900502

M3 - Article

AN - SCOPUS:77952604988

SN - 0044-2313

VL - 636

SP - 1147

EP - 1151

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 6

ER -

Synthesis and characterization of a novel energetic complex [Cd(DAT) ₆](NO₃)₂ (DAT = 1,5-diamino-tetrazole) with high nitrogen content

Abstract

Keywords

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