Synthesis and characterization of a new zinc phosphate with 16-ring channels: Zn3PO4(HPO4)3 · C6N3H18

Zhi En Lin; Qing Xin Zeng; Jie Zhang; Guo Yu Yang

doi:10.1016/S1387-1811(03)00475-X

Synthesis and characterization of a new zinc phosphate with 16-ring channels: Zn₃PO₄(HPO₄)₃ · C₆N₃H₁₈

Zhi En Lin, Qing Xin Zeng, Jie Zhang, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A new open-framework zinc phosphate, Zn₃PO₄ (HPO₄)₃ · C₆N₃ H₁₈ (denoted FJ-11), was synthesized under solvothermal conditions in the presence of 1-(2-aminoethyl)piperazine as structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, ICP analysis, powder X-ray diffraction and thermogravimetric analysis. The compound crystallized in the triclinic space group, P-1, with a = 8.2807(2) Å, b = 9.13750(10) Å, c = 13.3463(2) Å, α = 83.7700(10)°, β = 84.4460(10)°, γ = 78.0250(10)°, V = 979.17(3) Å³, Z = 2. The structure consists of ZnO₄, PO₄ and HPO₄ tetrahedra with shared corners, forming intersecting three-dimensional channels. The triply protonated 1-(2-aminoethyl)piperazine molecules reside in the large 16-ring channels and interact with the inorganic framework by extensive hydrogen bonds.

Original language	English
Pages (from-to)	119-125
Number of pages	7
Journal	Microporous and Mesoporous Materials
Volume	64
Issue number	1-3
DOIs	https://doi.org/10.1016/S1387-1811(03)00475-X
Publication status	Published - 3 Oct 2003
Externally published	Yes

Keywords

16-Ring channels
Crystal structure
Open-framework
Solvothermal synthesis
Zeolites
Zinc phosphate

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10.1016/S1387-1811(03)00475-X

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@article{8a4f99a6b4354d14aeb43de9f61e80ca,

title = "Synthesis and characterization of a new zinc phosphate with 16-ring channels: Zn3PO4(HPO4)3 · C6N3H18",

abstract = "A new open-framework zinc phosphate, Zn3PO4 (HPO4)3 · C6N3 H18 (denoted FJ-11), was synthesized under solvothermal conditions in the presence of 1-(2-aminoethyl)piperazine as structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, ICP analysis, powder X-ray diffraction and thermogravimetric analysis. The compound crystallized in the triclinic space group, P-1, with a = 8.2807(2) {\AA}, b = 9.13750(10) {\AA}, c = 13.3463(2) {\AA}, α = 83.7700(10)°, β = 84.4460(10)°, γ = 78.0250(10)°, V = 979.17(3) {\AA}3, Z = 2. The structure consists of ZnO4, PO4 and HPO4 tetrahedra with shared corners, forming intersecting three-dimensional channels. The triply protonated 1-(2-aminoethyl)piperazine molecules reside in the large 16-ring channels and interact with the inorganic framework by extensive hydrogen bonds.",

keywords = "16-Ring channels, Crystal structure, Open-framework, Solvothermal synthesis, Zeolites, Zinc phosphate",

author = "Lin, \{Zhi En\} and Zeng, \{Qing Xin\} and Jie Zhang and Yang, \{Guo Yu\}",

year = "2003",

month = oct,

day = "3",

doi = "10.1016/S1387-1811(03)00475-X",

language = "English",

volume = "64",

pages = "119--125",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

publisher = "Elsevier B.V.",

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}

TY - JOUR

T1 - Synthesis and characterization of a new zinc phosphate with 16-ring channels

T2 - Zn3PO4(HPO4)3 · C6N3H18

AU - Lin, Zhi En

AU - Zeng, Qing Xin

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2003/10/3

Y1 - 2003/10/3

N2 - A new open-framework zinc phosphate, Zn3PO4 (HPO4)3 · C6N3 H18 (denoted FJ-11), was synthesized under solvothermal conditions in the presence of 1-(2-aminoethyl)piperazine as structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, ICP analysis, powder X-ray diffraction and thermogravimetric analysis. The compound crystallized in the triclinic space group, P-1, with a = 8.2807(2) Å, b = 9.13750(10) Å, c = 13.3463(2) Å, α = 83.7700(10)°, β = 84.4460(10)°, γ = 78.0250(10)°, V = 979.17(3) Å3, Z = 2. The structure consists of ZnO4, PO4 and HPO4 tetrahedra with shared corners, forming intersecting three-dimensional channels. The triply protonated 1-(2-aminoethyl)piperazine molecules reside in the large 16-ring channels and interact with the inorganic framework by extensive hydrogen bonds.

AB - A new open-framework zinc phosphate, Zn3PO4 (HPO4)3 · C6N3 H18 (denoted FJ-11), was synthesized under solvothermal conditions in the presence of 1-(2-aminoethyl)piperazine as structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, ICP analysis, powder X-ray diffraction and thermogravimetric analysis. The compound crystallized in the triclinic space group, P-1, with a = 8.2807(2) Å, b = 9.13750(10) Å, c = 13.3463(2) Å, α = 83.7700(10)°, β = 84.4460(10)°, γ = 78.0250(10)°, V = 979.17(3) Å3, Z = 2. The structure consists of ZnO4, PO4 and HPO4 tetrahedra with shared corners, forming intersecting three-dimensional channels. The triply protonated 1-(2-aminoethyl)piperazine molecules reside in the large 16-ring channels and interact with the inorganic framework by extensive hydrogen bonds.

KW - 16-Ring channels

KW - Crystal structure

KW - Open-framework

KW - Solvothermal synthesis

KW - Zeolites

KW - Zinc phosphate

UR - https://www.scopus.com/pages/publications/0141889716

U2 - 10.1016/S1387-1811(03)00475-X

DO - 10.1016/S1387-1811(03)00475-X

M3 - Article

AN - SCOPUS:0141889716

SN - 1387-1811

VL - 64

SP - 119

EP - 125

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 1-3

ER -

Synthesis and characterization of a new zinc phosphate with 16-ring channels: Zn₃PO₄(HPO₄)₃ · C₆N₃H₁₈

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Keywords

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