Synthesis and characterization of a new organic-inorganic hybrid zinc borate: [Zn(dab) 0.5(dab′) 0.5(B 4O 6(OH) 2)]·H 2O

Pei Zhao; Lin Cheng; Guo Yu Yang

doi:10.1016/j.inoche.2012.02.036

Synthesis and characterization of a new organic-inorganic hybrid zinc borate: [Zn(dab) _0.5(dab′) _0.5(B ₄O ₆(OH) ₂)]·H ₂O

Pei Zhao
, Lin Cheng
, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

A new organic-inorganic hybrid zinc borate [Zn(dab) _0.5(dab′) _0.5(B ₄O ₆(OH) ₂)]·H ₂O has been hydrothermally synthesized by using 1,4-diaminobutane (dab) as the linkers and characterized by means of elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction, respectively. This compound crystallizes in the monoclinic space group P2 ₁/c, a = 9.997(3) Å, b = 8.371(3) Å, c = 16.321(4) Å, β = 111.7(1)°, V = 1268.8(7) Å ³, Z = 4. The structure contains ZnO ₂N ₂ tetrahedra, 1,4-dab and B ₄O ₇(OH) ₂ clusters, which interconnect to form a new three-dimensional framework.

Original language	English
Pages (from-to)	138-141
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	20
DOIs	https://doi.org/10.1016/j.inoche.2012.02.036
Publication status	Published - Jun 2012

Keywords

Hydrothermal synthesis
Open-framework
Template
Zinc borate

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10.1016/j.inoche.2012.02.036

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@article{c15a0fbd3e7942928196f69221bc6e60,

title = "Synthesis and characterization of a new organic-inorganic hybrid zinc borate: [Zn(dab) 0.5(dab′) 0.5(B 4O 6(OH) 2)]·H 2O",

abstract = "A new organic-inorganic hybrid zinc borate [Zn(dab) 0.5(dab′) 0.5(B 4O 6(OH) 2)]·H 2O has been hydrothermally synthesized by using 1,4-diaminobutane (dab) as the linkers and characterized by means of elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction, respectively. This compound crystallizes in the monoclinic space group P2 1/c, a = 9.997(3) {\AA}, b = 8.371(3) {\AA}, c = 16.321(4) {\AA}, β = 111.7(1)°, V = 1268.8(7) {\AA} 3, Z = 4. The structure contains ZnO 2N 2 tetrahedra, 1,4-dab and B 4O 7(OH) 2 clusters, which interconnect to form a new three-dimensional framework.",

keywords = "Hydrothermal synthesis, Open-framework, Template, Zinc borate",

author = "Pei Zhao and Lin Cheng and Yang, \{Guo Yu\}",

year = "2012",

month = jun,

doi = "10.1016/j.inoche.2012.02.036",

language = "English",

volume = "20",

pages = "138--141",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Synthesis and characterization of a new organic-inorganic hybrid zinc borate

T2 - [Zn(dab) 0.5(dab′) 0.5(B 4O 6(OH) 2)]·H 2O

AU - Zhao, Pei

AU - Cheng, Lin

AU - Yang, Guo Yu

PY - 2012/6

Y1 - 2012/6

N2 - A new organic-inorganic hybrid zinc borate [Zn(dab) 0.5(dab′) 0.5(B 4O 6(OH) 2)]·H 2O has been hydrothermally synthesized by using 1,4-diaminobutane (dab) as the linkers and characterized by means of elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction, respectively. This compound crystallizes in the monoclinic space group P2 1/c, a = 9.997(3) Å, b = 8.371(3) Å, c = 16.321(4) Å, β = 111.7(1)°, V = 1268.8(7) Å 3, Z = 4. The structure contains ZnO 2N 2 tetrahedra, 1,4-dab and B 4O 7(OH) 2 clusters, which interconnect to form a new three-dimensional framework.

AB - A new organic-inorganic hybrid zinc borate [Zn(dab) 0.5(dab′) 0.5(B 4O 6(OH) 2)]·H 2O has been hydrothermally synthesized by using 1,4-diaminobutane (dab) as the linkers and characterized by means of elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction, respectively. This compound crystallizes in the monoclinic space group P2 1/c, a = 9.997(3) Å, b = 8.371(3) Å, c = 16.321(4) Å, β = 111.7(1)°, V = 1268.8(7) Å 3, Z = 4. The structure contains ZnO 2N 2 tetrahedra, 1,4-dab and B 4O 7(OH) 2 clusters, which interconnect to form a new three-dimensional framework.

KW - Hydrothermal synthesis

KW - Open-framework

KW - Template

KW - Zinc borate

UR - https://www.scopus.com/pages/publications/84861527617

U2 - 10.1016/j.inoche.2012.02.036

DO - 10.1016/j.inoche.2012.02.036

M3 - Article

AN - SCOPUS:84861527617

SN - 1387-7003

VL - 20

SP - 138

EP - 141

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Synthesis and characterization of a new organic-inorganic hybrid zinc borate: [Zn(dab) _0.5(dab′) _0.5(B ₄O ₆(OH) ₂)]·H ₂O

Abstract

Keywords

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