Synthesis and characterization of a new inorganic-organic hybrid open-framework zinc phosphite: (C6N3H12) 2 · Zn5(HPO3)6

Jian Xin Pan; Shou Tian Zheng; Guo Yu Yang

doi:10.1016/j.micromeso.2004.07.022

Synthesis and characterization of a new inorganic-organic hybrid open-framework zinc phosphite: (C₆N₃H₁₂) ₂ · Zn₅(HPO₃)₆

Jian Xin Pan
, Shou Tian Zheng
, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

A new inorganic-organic hybrid open-framework zinc phosphite, (C ₆N₃H₁₂)·₂ Zn ₅(HPO₃)₆, has been hydrothermally synthesized in the presence of l-(3-aminopropyl)imidazole amine as a structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (PXRD), IR spectroscopy, ICP, elemental, and TG analyses. This compound crystallizes in the orthorhombic system, space group C222₁ (no. 20), a = 9.9512(4), b = 14.7129(6), c = 22.50660(10) Å, V = 3295.21(19) Å³, Z = 4. The connectivity of the strictly alternating Zn-centered tetrahedra and HPO ₃ pseudopyramids results in a 3D framework with intersecting 8- and 12-membered ring channels, where organic amines reside. It is worth noting that the title compound is the first metal phosphite to be prepared with a metal: phosphorus ratio of 5:6.

Original language	English
Pages (from-to)	129-133
Number of pages	5
Journal	Microporous and Mesoporous Materials
Volume	75
Issue number	1-2
DOIs	https://doi.org/10.1016/j.micromeso.2004.07.022
Publication status	Published - 12 Oct 2004
Externally published	Yes

Keywords

Crystal structure
Hybrid solid
Hydrothermal synthesis
Open-framework
Zinc phosphite

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10.1016/j.micromeso.2004.07.022

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@article{4e270ad52fd14168a4177b89150ce9fd,

title = "Synthesis and characterization of a new inorganic-organic hybrid open-framework zinc phosphite: (C6N3H12) 2 · Zn5(HPO3)6",

abstract = "A new inorganic-organic hybrid open-framework zinc phosphite, (C 6N3H12)·2 Zn 5(HPO3)6, has been hydrothermally synthesized in the presence of l-(3-aminopropyl)imidazole amine as a structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (PXRD), IR spectroscopy, ICP, elemental, and TG analyses. This compound crystallizes in the orthorhombic system, space group C2221 (no. 20), a = 9.9512(4), b = 14.7129(6), c = 22.50660(10) {\AA}, V = 3295.21(19) {\AA}3, Z = 4. The connectivity of the strictly alternating Zn-centered tetrahedra and HPO 3 pseudopyramids results in a 3D framework with intersecting 8- and 12-membered ring channels, where organic amines reside. It is worth noting that the title compound is the first metal phosphite to be prepared with a metal: phosphorus ratio of 5:6.",

keywords = "Crystal structure, Hybrid solid, Hydrothermal synthesis, Open-framework, Zinc phosphite",

author = "Pan, \{Jian Xin\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2004",

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day = "12",

doi = "10.1016/j.micromeso.2004.07.022",

language = "English",

volume = "75",

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journal = "Microporous and Mesoporous Materials",

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T1 - Synthesis and characterization of a new inorganic-organic hybrid open-framework zinc phosphite

T2 - (C6N3H12) 2 · Zn5(HPO3)6

AU - Pan, Jian Xin

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004/10/12

Y1 - 2004/10/12

N2 - A new inorganic-organic hybrid open-framework zinc phosphite, (C 6N3H12)·2 Zn 5(HPO3)6, has been hydrothermally synthesized in the presence of l-(3-aminopropyl)imidazole amine as a structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (PXRD), IR spectroscopy, ICP, elemental, and TG analyses. This compound crystallizes in the orthorhombic system, space group C2221 (no. 20), a = 9.9512(4), b = 14.7129(6), c = 22.50660(10) Å, V = 3295.21(19) Å3, Z = 4. The connectivity of the strictly alternating Zn-centered tetrahedra and HPO 3 pseudopyramids results in a 3D framework with intersecting 8- and 12-membered ring channels, where organic amines reside. It is worth noting that the title compound is the first metal phosphite to be prepared with a metal: phosphorus ratio of 5:6.

AB - A new inorganic-organic hybrid open-framework zinc phosphite, (C 6N3H12)·2 Zn 5(HPO3)6, has been hydrothermally synthesized in the presence of l-(3-aminopropyl)imidazole amine as a structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (PXRD), IR spectroscopy, ICP, elemental, and TG analyses. This compound crystallizes in the orthorhombic system, space group C2221 (no. 20), a = 9.9512(4), b = 14.7129(6), c = 22.50660(10) Å, V = 3295.21(19) Å3, Z = 4. The connectivity of the strictly alternating Zn-centered tetrahedra and HPO 3 pseudopyramids results in a 3D framework with intersecting 8- and 12-membered ring channels, where organic amines reside. It is worth noting that the title compound is the first metal phosphite to be prepared with a metal: phosphorus ratio of 5:6.

KW - Crystal structure

KW - Hybrid solid

KW - Hydrothermal synthesis

KW - Open-framework

KW - Zinc phosphite

UR - https://www.scopus.com/pages/publications/5044241978

U2 - 10.1016/j.micromeso.2004.07.022

DO - 10.1016/j.micromeso.2004.07.022

M3 - Article

AN - SCOPUS:5044241978

SN - 1387-1811

VL - 75

SP - 129

EP - 133

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 1-2

ER -

Synthesis and characterization of a new inorganic-organic hybrid open-framework zinc phosphite: (C₆N₃H₁₂) ₂ · Zn₅(HPO₃)₆

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Keywords

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