Synthesis and characterization of a new hybrid zinc phosphite (4,4′-bipy)[Zn(HPO3)]2 with a pillared layer structure

Zhi En Lin; Jie Zhang; Shou Tian Zheng; G. Y.Guo Yu Yang

doi:10.1016/j.micromeso.2003.11.015

Synthesis and characterization of a new hybrid zinc phosphite (4,4′-bipy)[Zn(HPO₃)]₂ with a pillared layer structure

Zhi En Lin
, Jie Zhang
, Shou Tian Zheng
, G. Y.Guo Yu Yang

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

A new inorganic-organic hybrid solid, (4,4^′-bipy) [Zn(HPO₃)]₂ (4,4^′-bipy= 4,4^′-bipyridine), has been hydrothermally synthesized in the presence of 4,4^′-bipy ligand. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, ICP analysis, powder X-ray diffraction, thermogravimetric analysis and fluorescent spectrum. It crystallized in the monoclinic space group, P2₁/c, with a=9.741(2), b=7.4423(16), c=10.271(2) Å, β=100.038(4)°, V=733.3(3) Å³, Z=2. The structure consists of neutral sheets of zinc phosphite which is pillared through 4,4^′-bipy ligands to generate a 3D framework. The compound shows relatively high thermal stability and exhibits intense photoluminescence upon photo-excitation at 362 nm.

Original language	English
Pages (from-to)	65-70
Number of pages	6
Journal	Microporous and Mesoporous Materials
Volume	68
Issue number	1-3
DOIs	https://doi.org/10.1016/j.micromeso.2003.11.015
Publication status	Published - 8 Mar 2004
Externally published	Yes

Keywords

Crystal structure
Fluorescent emission
Hybrid solid
Open-framework
Zinc phosphite

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10.1016/j.micromeso.2003.11.015

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title = "Synthesis and characterization of a new hybrid zinc phosphite (4,4′-bipy)[Zn(HPO3)]2 with a pillared layer structure",

abstract = "A new inorganic-organic hybrid solid, (4,4′-bipy) [Zn(HPO3)]2 (4,4′-bipy= 4,4′-bipyridine), has been hydrothermally synthesized in the presence of 4,4′-bipy ligand. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, ICP analysis, powder X-ray diffraction, thermogravimetric analysis and fluorescent spectrum. It crystallized in the monoclinic space group, P21/c, with a=9.741(2), b=7.4423(16), c=10.271(2) {\AA}, β=100.038(4)°, V=733.3(3) {\AA}3, Z=2. The structure consists of neutral sheets of zinc phosphite which is pillared through 4,4′-bipy ligands to generate a 3D framework. The compound shows relatively high thermal stability and exhibits intense photoluminescence upon photo-excitation at 362 nm.",

keywords = "Crystal structure, Fluorescent emission, Hybrid solid, Open-framework, Zinc phosphite",

author = "Lin, \{Zhi En\} and Jie Zhang and Zheng, \{Shou Tian\} and Yang, \{G. Y.Guo Yu\}",

year = "2004",

month = mar,

day = "8",

doi = "10.1016/j.micromeso.2003.11.015",

language = "English",

volume = "68",

pages = "65--70",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

publisher = "Elsevier B.V.",

number = "1-3",

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TY - JOUR

T1 - Synthesis and characterization of a new hybrid zinc phosphite (4,4′-bipy)[Zn(HPO3)]2 with a pillared layer structure

AU - Lin, Zhi En

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, G. Y.Guo Yu

PY - 2004/3/8

Y1 - 2004/3/8

N2 - A new inorganic-organic hybrid solid, (4,4′-bipy) [Zn(HPO3)]2 (4,4′-bipy= 4,4′-bipyridine), has been hydrothermally synthesized in the presence of 4,4′-bipy ligand. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, ICP analysis, powder X-ray diffraction, thermogravimetric analysis and fluorescent spectrum. It crystallized in the monoclinic space group, P21/c, with a=9.741(2), b=7.4423(16), c=10.271(2) Å, β=100.038(4)°, V=733.3(3) Å3, Z=2. The structure consists of neutral sheets of zinc phosphite which is pillared through 4,4′-bipy ligands to generate a 3D framework. The compound shows relatively high thermal stability and exhibits intense photoluminescence upon photo-excitation at 362 nm.

AB - A new inorganic-organic hybrid solid, (4,4′-bipy) [Zn(HPO3)]2 (4,4′-bipy= 4,4′-bipyridine), has been hydrothermally synthesized in the presence of 4,4′-bipy ligand. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, ICP analysis, powder X-ray diffraction, thermogravimetric analysis and fluorescent spectrum. It crystallized in the monoclinic space group, P21/c, with a=9.741(2), b=7.4423(16), c=10.271(2) Å, β=100.038(4)°, V=733.3(3) Å3, Z=2. The structure consists of neutral sheets of zinc phosphite which is pillared through 4,4′-bipy ligands to generate a 3D framework. The compound shows relatively high thermal stability and exhibits intense photoluminescence upon photo-excitation at 362 nm.

KW - Crystal structure

KW - Fluorescent emission

KW - Hybrid solid

KW - Open-framework

KW - Zinc phosphite

UR - https://www.scopus.com/pages/publications/1442359025

U2 - 10.1016/j.micromeso.2003.11.015

DO - 10.1016/j.micromeso.2003.11.015

M3 - Article

AN - SCOPUS:1442359025

SN - 1387-1811

VL - 68

SP - 65

EP - 70

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 1-3

ER -

Synthesis and characterization of a new hybrid zinc phosphite (4,4′-bipy)[Zn(HPO₃)]₂ with a pillared layer structure

Abstract

Keywords

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