Synthesis and characterization of a molecular zinc phosphate Ni(2,2′-bipy)3·[ZnCl(H2PO4) 3]

Zhi En Lin; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/zaac.200400200

Synthesis and characterization of a molecular zinc phosphate Ni(2,2′-bipy)₃·[ZnCl(H₂PO₄) ₃]

Zhi En Lin, Jie Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A new zinc phosphate cluster Ni(2,2′-bipy)₃·[ZnCl- (H₂PO₄)₃] (1) was obtained by the hydrothermal reaction of ZnO, H₃PO₄, NiCl₂·6H ₂O, 2,2′-bipyridine(2,2′-bipy) and H₂O in a molar ration of 1:1.9:0.5:1.5:126. The structure of 1 is made of [ZnCl(H ₂PO₄)₃] clusters that are separated by nickel complexes. The compound is novel in the sense that it is the first zinc phosphate cluster with metal complexes acting as structure-directing agents. Crystal data: trigonal, space group = R3c (no. 167), a = 13.2407(3), c = 74.034(3) Å, V = 11240.5(6) Å³, Z =12.

Original language	English
Pages (from-to)	148-151
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	631
Issue number	1
DOIs	https://doi.org/10.1002/zaac.200400200
Publication status	Published - 2005
Externally published	Yes

Keywords

Cluster
Crystal elucidation
Nickel complex
Phosphate
Zinc

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@article{12ae5169aa4a4832ac12a103c8b5d439,

title = "Synthesis and characterization of a molecular zinc phosphate Ni(2,2′-bipy)3·[ZnCl(H2PO4) 3]",

abstract = "A new zinc phosphate cluster Ni(2,2′-bipy)3·[ZnCl- (H2PO4)3] (1) was obtained by the hydrothermal reaction of ZnO, H3PO4, NiCl2·6H 2O, 2,2′-bipyridine(2,2′-bipy) and H2O in a molar ration of 1:1.9:0.5:1.5:126. The structure of 1 is made of [ZnCl(H 2PO4)3] clusters that are separated by nickel complexes. The compound is novel in the sense that it is the first zinc phosphate cluster with metal complexes acting as structure-directing agents. Crystal data: trigonal, space group = R3c (no. 167), a = 13.2407(3), c = 74.034(3) {\AA}, V = 11240.5(6) {\AA}3, Z =12.",

keywords = "Cluster, Crystal elucidation, Nickel complex, Phosphate, Zinc",

author = "Lin, {Zhi En} and Jie Zhang and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2005",

doi = "10.1002/zaac.200400200",

language = "English",

volume = "631",

pages = "148--151",

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T1 - Synthesis and characterization of a molecular zinc phosphate Ni(2,2′-bipy)3·[ZnCl(H2PO4) 3]

AU - Lin, Zhi En

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2005

Y1 - 2005

N2 - A new zinc phosphate cluster Ni(2,2′-bipy)3·[ZnCl- (H2PO4)3] (1) was obtained by the hydrothermal reaction of ZnO, H3PO4, NiCl2·6H 2O, 2,2′-bipyridine(2,2′-bipy) and H2O in a molar ration of 1:1.9:0.5:1.5:126. The structure of 1 is made of [ZnCl(H 2PO4)3] clusters that are separated by nickel complexes. The compound is novel in the sense that it is the first zinc phosphate cluster with metal complexes acting as structure-directing agents. Crystal data: trigonal, space group = R3c (no. 167), a = 13.2407(3), c = 74.034(3) Å, V = 11240.5(6) Å3, Z =12.

AB - A new zinc phosphate cluster Ni(2,2′-bipy)3·[ZnCl- (H2PO4)3] (1) was obtained by the hydrothermal reaction of ZnO, H3PO4, NiCl2·6H 2O, 2,2′-bipyridine(2,2′-bipy) and H2O in a molar ration of 1:1.9:0.5:1.5:126. The structure of 1 is made of [ZnCl(H 2PO4)3] clusters that are separated by nickel complexes. The compound is novel in the sense that it is the first zinc phosphate cluster with metal complexes acting as structure-directing agents. Crystal data: trigonal, space group = R3c (no. 167), a = 13.2407(3), c = 74.034(3) Å, V = 11240.5(6) Å3, Z =12.

KW - Cluster

KW - Crystal elucidation

KW - Nickel complex

KW - Phosphate

KW - Zinc

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DO - 10.1002/zaac.200400200

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VL - 631

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IS - 1

ER -

Synthesis and characterization of a molecular zinc phosphate Ni(2,2′-bipy)₃·[ZnCl(H₂PO₄) ₃]

Abstract

Keywords

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